全文获取类型
收费全文 | 337篇 |
免费 | 7篇 |
国内免费 | 3篇 |
专业分类
化学 | 183篇 |
晶体学 | 14篇 |
力学 | 28篇 |
数学 | 58篇 |
物理学 | 64篇 |
出版年
2022年 | 7篇 |
2021年 | 4篇 |
2020年 | 9篇 |
2019年 | 2篇 |
2018年 | 8篇 |
2017年 | 10篇 |
2016年 | 7篇 |
2015年 | 10篇 |
2014年 | 13篇 |
2013年 | 20篇 |
2012年 | 25篇 |
2011年 | 39篇 |
2010年 | 20篇 |
2009年 | 9篇 |
2008年 | 14篇 |
2007年 | 12篇 |
2006年 | 9篇 |
2005年 | 7篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 12篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 4篇 |
1995年 | 9篇 |
1994年 | 9篇 |
1993年 | 4篇 |
1992年 | 8篇 |
1991年 | 2篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1984年 | 2篇 |
1982年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1975年 | 3篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1966年 | 1篇 |
1964年 | 1篇 |
1961年 | 2篇 |
排序方式: 共有347条查询结果,搜索用时 0 毫秒
1.
Heavy ion irradiation in the electronic stopping power region induces macroscopic dimensional change in metallic glasses and introduces magnetic anisotropy in some magnetic materials. The present work is on the irradiation study of ferromagnetic metallic glasses, where both dimensional change and modification of magnetic anisotropy are expected. Magnetic anisotropy was measured using Mössbauer spectroscopy of virgin and irradiated Fe40Ni40B20 and Fe40Ni38Mo4B18 metallic glass ribbons. 90 MeV 127I beam was used for the irradiations. Irradiation doses were 5×1013 and 7.5×1013 ions/cm2. The relative intensity ratios D 23 of the second and third lines of the Mössbauer spectra were measured to determine the magnetic anisotropy. The virgin samples of both the materials display in-plane magnetic anisotropy, i.e., the spins are oriented parallel to the ribbon plane. Irradiation is found to cause reduction in magnetic anisotropy. Near-complete randomization of magnetic moments is observed at high irradiation doses. Correlation is found between the residual stresses introduced by ion irradiation and the change in magnetic anisotropy. 相似文献
2.
The N-benzoyl-l-tyrosine ethyl ester (BTEE) anchored in cyclodextrin (β and β-methyl CD) serves as an excellent substrate for subtilisin
Carlsberg catalysis. The rate of hydrolysis was found to be approximately twofold higher than that of the methanolic substrate.
The Kmapp and Vmax values for the CD anchored substrates were significantly higher than the methanol-solubilized BTEE. 相似文献
3.
D. R. Prabhu G. R. Mahajan G. M. Nair 《Journal of Radioanalytical and Nuclear Chemistry》1997,224(1-2):113-117
The extraction of uranium(VI) and plutonium(IV) from nitric acid into n-dodecane was studied using two isomeric branched alkyl amides, di(2-ethyl hexyl) butyramide (DEHBA) and di(2-ethyl hexyl) isobutyramide (DEHIBA). The extraction ratios of Pu(IV) at relatively high acidities were higher than the corresponding values for U(VI) in the case of DEHBA. However, with DEHIBA the values for Pu(IV) were negligibly small. Pu(IV) was found to be extracted as trisolvate by DEHBA and as disolvate by DEHIBA. U(VI) was extracted by both the amides. From the study of the extraction reactions at different temperatures, it was shown that all the reactions in the present investigation were enthalpy favoured and entropy disfavoured. Separation of Pu(IV) from bulk of U(VI) was feasible. However, the purity of the separated plutonium was not satisfactory in batch extraction studies. 相似文献
4.
5.
6.
Recently much attention has been paid to the application of metal hybrid nanoparticles in industrial catalytic fields because of their super-efficient catalytic activity and attractive properties. We explored a novel strategy to prepare GSH-capped Pt–Au–Ag-hybrid nanoclusters through the synergistic effect between ascorbic acid(VC) and glutathione(GSH) with chloroplatinic acid, chloroauric acid, and silver nitrate as precursors. The potential utilization of as-prepared GSH-capped Pt–Au–Aghybrid nanoclusters for catalytic applications has been evaluated through the reduction of 4-nitrophenol(4-NP) with NaBH4; we obtained the kinetic data by monitoring with UV-Vis spectroscopy. Our results illustrate that GSH-capped Pt–Au– Ag-hybrid nanoclusters could facilitate the process of reduction of 4-NP in a way that is unprecedented. This approach may offer a novel, non-cytotoxicity, efficient catalyst for industry. 相似文献
7.
8.
D. R. Prabhu Neelam Kumari A. S. Kanekar P. N. Pathak 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(1):691-698
The relative stability of different oxidation states of actinide elements is influenced by the nature of complexes formed and redox equilibria in aqueous/non-aqueous solutions. The reduction/stripping studies on Pu(IV) ions from loaded organic phases of 1.1 M tributyl phosphate and of 1.1 M N,N-dihexyl octanamide in n-dodecane were studied using organic soluble tert-butyl hydroquinone (TBH) and aqueous soluble reductants like acetaldoxime (AX) and hydroxyurea (HU). These studies were carried out as a function of reductant and nitric acid concentration (0.5–4 M HNO3) and of time. The changes in Pu oxidation states were followed by spectrophotometry for TBH and by distribution ratio values for AX and HU as reductants. Spectrophotometric investigations using TBH as reductant showed that it was desirable to strip Pu(III) formed after reduction of Pu(IV) in the organic phase, which may otherwise be reconverted to extractable Pu(IV) by in situ generated HNO2 from oxidative degradation of TBH to tert-butyl quinone. Similarly, the biphasic reduction/stripping of Pu(IV) using AX and HU as reductant rate was affected adversely with increased aqueous phase acidity. This data will help in the accurate simulation of Pu separation processes using these reductants in mixer-settlers/pulsed columns or centrifugal contactors. 相似文献
9.
Raja K. Raja Pugalenthi M. Ramesh Prabhu M. 《Journal of Solid State Electrochemistry》2020,24(1):35-44
Journal of Solid State Electrochemistry - The sulfonated poly(ether ether ketone) (SPEEK) is one of the most promising aromatic proton exchange polymer membranes concerning fluorinated aliphatic... 相似文献
10.
T. V. Beatriceveena A. Sree Rama Murthy S. Murugesan E. Prabhu K. I. Gnanasekar 《Angewandte Chemie (International ed. in English)》2020,59(6):2241-2245
Owing to a wide range of industrial applications and fundamental importance, delafossite compounds have gathered tremendous interest in research community. In this study, the formation of hexagonal nanoplates of AgInO2 mainly dominated by (00l) facets with no metallic Ag impurity, reported using a facile hydrothermal route at 180 °C using KOH as mineralizer by adopting a factorial design approach. Rietveld analysis of the powder XRD pattern and SAED confirms the rhombohedral system of AgInO2. FE‐SEM image shows a uniform hexagonal plate‐like morphology with an average width of about 300 nm and thickness of 70 nm. XPS and EDX analysis confirm potassium ion free AgInO2. A specific surface area of about 48.5 m2 g?1 is arrived from N2 adsorption studies. Temperature‐dependent AC impedance measurements revealed an activation energy of 0.24 eV/f.u. Further, TG‐DTA studies found that the compound is stable in air up to 595 °C. 相似文献