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1.
New organohalogermanes RGe(OCH2CH2NMe2)2X (R = Ph, X = I (5); R = Me, X = Cl (6) or I (7)) with an intramolecular N→Ge coordination bond were synthesized. According
to the 1H and 13C NMR spectroscopic data, iodides 5 and 7 exist in solution as ionic compounds with the pentacoordinated germanium atom. In
solution of compound 4 (R = Ph, X = Cl), there is an equilibrium between the ionic and covalent forms. The equilibrium shifts
toward the ionic form with increasing solvent polarity or temperature. In solution, chloride 6 is a covalent compound. The
structures and relative stabilities of different isomers of compounds 4–7 were studied by quantum chemical calculations at
the density functional level of theory.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 892–900, May, 2007. 相似文献
2.
Khrustalev VN Portnyagin IA Nechaev MS Bukalov SS Leites LA 《Dalton transactions (Cambridge, England : 2003)》2007,(32):3489-3492
Equatorial-axial isomerism of the tin(II)-iron(0) complex (Me2NCH2CH2O)2Sn-Fe(CO)4 (), which indicates that the free Sn(OCH2CH2NMe2)2 () ligand can behave as a stannylene, has been revealed and studied by NMR and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid-state. 相似文献
3.
MF Miller IA Franchi AS Sexton CT Pillinger 《Rapid communications in mass spectrometry : RCM》1999,13(13):1211-1217
The use of infrared laser-assisted fluorination to release oxygen from milligram quantities of silicates or other oxide mineral grains is a well-established technique. However, relatively few studies have reported the optimisation of this procedure for oxygen-17 isotope measurements. We describe here details of an analytical system using infrared (10 μm) laser-assisted fluorination, in conjunction with a dual inlet mass spectrometer of high resolving power ( approximately 250) to provide (17)O and (18)O oxygen isotope measurements from 0.5-2 mg of silicates or other oxide mineral grains. Respective precisions (1) of typically 0.08 and 0.04 per thousand are obtained for the complete analytical procedure. Departures from the mass-dependent oxygen isotope fractionation line are quantified by Delta(17)O; our precision (1) of such measurements on individual samples is shown to be +/-0.024 per thousand. In turn, this permits the offset between parallel, mass-dependent fractionation lines to be characterised to substantially greater precision than has been possible hitherto. Application of this system to investigate the (17)O versus (18)O relationship for numerous terrestrial whole-rock and mineral samples, of diverse geological origins and age, indicates that the complete data set may be described by a single, mass-dependent fractionation line of slope 0.5244+/- 0.00038 (standard error). Copyright 1999 John Wiley & Sons, Ltd. 相似文献
4.
Egorin Andrei Sokolnitskaya Tatiana Azarova Yuliya Portnyagin Arseniy Balanov Mikhail Misko Darya Shelestyuk Evgeny Kalashnikova Anastasia Tokar Eduard Tananaev Ivan Avramenko Valentin 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(1):243-251
Sorption of micro- and microamounts of Sr from seawater has been studied using granulated Na-birnessite. Distribution coefficients of 90Sr in the natural seawater are 0.8–1.2?×?103 ml g?1, in the model seawater they are 1.6–1.8?×?103 ml g?1. Application of Na-birnessite was shown to be prospective in sorption–desorption–regeneration regime. In dynamic sorption conditions, over 150 bed volumes of seawater can be purified till 5% breakthrough occurs at feed rate 10 BV h?1. Na-birnessite can be used for 90Sr radionuclide removal from liquid radioactive wastes containing seawater.
相似文献5.
D. V. Portnyagin 《Journal of Mathematical Sciences》2010,170(5):604-611
Estimates for the L
∞-norms of weak solutions are obtained for a model nondiagonal parabolic system of nonlinear differential equations with matrix
of coefficients satisfying special structure conditions. A technique based on estimating the certain function of unknowns
is employed to this end. 相似文献
6.
D. V. Portnyagin 《Differential Equations》2010,46(6):896-900
We prove the Hölder continuity of the solutions of the Dirichlet problem for a nondiagonal parabolic system of equations in divergence form whose leading parts are modeled by the p-Laplacians. 相似文献
7.
Mikhail S. Nechaev Oleg V. Chernov Ivan A. Portnyagin Victor N. Khrustalev Valery V. Lunin 《Journal of organometallic chemistry》2010,695(3):365-369
Alkylation of Sn(OCH2CH2NMe2)2 (1) by MeI or MeOTf leads to a mixture of quaternary ammonium salts by alkylation of the NMe2 moiety. Reaction of Sn(acac)2 (2) with MeOTf gives unexpected redistribution product Sn(acac)OTf (3), which is a rare example of mono acetylacetonato tin (II) derivatives. Pentacoordinated monoorgano stannyl cation was generated by salt metathesis from PhSn(OCH2CH2NMe2)2Cl (5) and Ag[Al(OCH(CF3)2)4] or Ag[B(C6F5)4]. This cation was not isolated due to its strong electrophilic nature. It abstracts substituents from aluminate and borate weakly coordinating anions (WCAs) leading to redistribution products [Al[OCH(CF3)2]2OCH2CH2NMe2]2 (6) and [Ph(C6F5)Sn(OCH2CH2NMe2)2][H2OB(C6F5)3] (9), respectively. Structures of 3 and 6 were established by single-crystal X-ray diffraction analysis. 相似文献
8.
D. V. Portnyagin 《Siberian Mathematical Journal》2012,53(2):291-300
We propose a method of generalizing the well-known maximum and comparison principles to nondiagonal parabolic systems of second
order nonlinear differential equations. Under consideration are the cases of Dirichlet and Neumann problems. We also present
some examples of the systems that this method applies to. 相似文献
9.
Ivanova I. K. Kashirtsev V. A. Semenov M. E. Glyaznetsova Yu. S. Chalaya O. N. Zueva I. N. Portnyagin A. S. 《Russian Journal of Applied Chemistry》2020,93(4):603-610
Russian Journal of Applied Chemistry - The results of a study of melting the commercial waxes in the composition of asphaltene-resin-paraffin deposits and for comparison of petroleum waxes in... 相似文献
10.
Victor N. Khrustalev Ivan A. Portnyagin Nikolay N. Zemlyansky Irina V. Borisova Yuri A. Ustynyuk Mikhail Yu. Antipin Mikhail S. Nechaev Robert West 《应用有机金属化学》2005,19(6):774-777
Germanium(II) dipropionate (1) has been synthesized and its crystal structure, as well as that of germanium(IV) tetrapropionate (2), has been determined. By contrast to monomeric 2 with monodentate propionate ligands, compound 1 is associated, forming a cyclotetramer [Ge(O2CEt)2]4 (1a) via intermolecular dative C?O → Ge interactions. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献