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V. I. Terenin E. A. Sumtsova M. A. Kovalkina S. Z. Vatsadze E. V. Kabanova A. P. Pleshkova N. V. Zyk 《Chemistry of Heterocyclic Compounds》2003,39(11):1487-1491
A series of previously unreported aldehydes has been prepared by the formylation reaction of dipyrrolo[1,2-a;2':,1'-c]pyrazines and their 5,6-dihydro analogs by DMF and phosphorus oxychloride. 相似文献
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V. I. Terenin E. A. Sumtsova S. Z. Vatsadze E. V. Kabanova I. F. Leshcheva A. P. Pleshkova N. V. Zyk 《Chemistry of Heterocyclic Compounds》2003,39(7):943-952
We have studied the behavior of asymmetrically substituted dipyrrolo[1,2-a;2',1'-c]pyrazines and their 5,6-dihydro analogs under phosphorylation reaction conditions. 相似文献
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Alexandra P. Pleshkova Marina N. Uspenskaya Sergei V. Volkovitch 《Journal of mass spectrometry : JMS》1994,29(1):26-29
New examples of the ortho effect in bisphenol A derivatives including interaction of the hydrogen of the ortho-hydroxy group with the neighbouring aromatic ring have been observed. The characteristic ions [M ? PhOH]+middot; (m/z = 134) and [M ? CH3 ? PhOH]+ (m/z = 119) were shown to form through the hydrogen transfer from hydroxy and isopropyl groups, respectively. The spectra of cyclic derivatives having ortho-hydroxy functions show [M ? 43]+, [M ? C8H9O]+, m/z = 147, m/z = 135 and [M ? C9H10O]+ ions. The proposed mechanims of the corresponding transformations were supported by mass spectra of deuterated analogues, methyl and trimethyl silyl ethers. 相似文献
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E. S. Kelbysheva A. P. Pleshkova S. E. Lyubimov S. P. Dolgova N. M. Loim 《Russian Journal of Organic Chemistry》2010,46(2):260-267
Procedures were developed for preparation of optically active dendrones and dendrimers with terminal 1,2-hydroxylimino, 1,2-hydroxylamino
and oxazolidinyl groups containing ether bonds in the branches and ester bonds in the backbone of the macromolecule. The compounds
described may serve as chiral ligands for asymmetric metallocomplex catclysis. 相似文献
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G. V. Shustov N. B. Tavakalyan A. P. Pleshkova R. G. Kostyanovskii 《Chemistry of Heterocyclic Compounds》1981,17(7):662-667
The amidation and alkaline hydrolysis of diazirine-3,3-dicarboxylic acid esters, which proceed with retention of the diazirine ring, were studied. The higher stability of diazirine-3,3-dicarboxylic acid esters as compared with their spirocyclic analogs is explained by the conformational lability of the C=O groups. The UV and mass spectra of the diazirines are discussed.See [1] for our preliminary communication.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 901–906, July, 1981. 相似文献
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DC Muddiman AP Null JC Hannis 《Rapid communications in mass spectrometry : RCM》1999,13(12):1201-1204
Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS) has been used to determine the mass of a double-stranded 500 base-pair (bp) polymerase chain reaction (PCR) product with an average theoretical mass of the blunt-ended (i.e. unadenylated) species of 308 859.35 Da. The PCR product was generated from the linearized bacteriophage Lambda genome which is a double-stranded template. Utilization of ethanol precipitation in tandem with a rapid microdialysis step to purify and desalt the PCR product was crucial to obtain a precise mass measurement. The PCR product (0.8 pmol/μL) was electrosprayed from a solution containing 75% acetonitrile, 25 mM piperidine, and 25 mM imidazole and was infused at a rate of 200 nL/min. The average molecular mass and the corresponding precision were determined using the charge-states ranging from 172 to 235 net negative charges. The experimental mass and corresponding precision (reported as the 95% confidence interval of the mean) was 309 406 +/- 27 Da (87 ppm). The mass accuracy was compromised due to the fact that the PCR generates multiple products when using Taq polymerase due to the non-template directed 3'-adenylation. This results in a mixture of three PCR products with nearly identical mass (i.e. blunt-ended, mono-adenylated and di-adenylated) with unknown relative abundances that were not resolved in the spectrum. Thus, the experimental mass will be a weighted average of the three species which, under our experimental conditions, reflects a nearly equal concentration of the mono- and di-adenylated species. This report demonstrates that precise mass measurements of PCR products up to 309 kDa (500 bp) can be routinely obtained by ESI-FTICR requiring low femtomole amounts. Copyright 1999 John Wiley & Sons, Ltd. 相似文献