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1.
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The critical fields of the valence transition induced by a magnetic field in the EuNi2(Si1?x Gex)2 (x=0.5–0.75) compound in an intermediate valence state are measured. The magnetic-field-induced valence transition is observed in the low-concentration range down to x=0.5. It is demonstrated that the critical field increases linearly with a decrease in the germanium concentration. 相似文献
3.
A. Yu. Shvykin V. V. Platonov V. A. Proskuryakov K. B. Chilachava S. I. Podshibyakin 《Russian Journal of Applied Chemistry》2006,79(10):1576-1580
A method of synthesis of acetylacetonated humin-like compounds was developed. The effect of modification on the sorption capacity of humin-like compounds with respect to heavy metals was studied. 相似文献
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V. V. Platonov A. A. Khadartsev A. Yu. Shvykin D. V. Prokopchenkov V. A. Proskuryakov T. V. Chestnova 《Russian Journal of Applied Chemistry》2006,79(10):1581-1587
The organic matter of schungite rock from the Zazhogino Deposit of Karelian Transonega region was extracted in the sequential mode. The extract composition was determined by several modern physicochemical methods. 相似文献
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The reaction of perfluorinated 1- and 3-phenylpropenes with AlCl3 gives polyfluorochloroindanes as the result of an intramolecular cyclization, apparently, by an electrophilic pathway.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2854–2857, December, 1989. 相似文献
8.
Matsura V. A. Potekhin V. V. Platonov V. V. Tatsenko O. M. Ukraintsev V. B. Khokhryakov K. A. 《Russian Journal of General Chemistry》2003,73(12):1900-1903
Kinetic regularities of hydrogenation, oxidation with oxygen, and condensation of allyl alcohol in the presence of colloid palladium in situ were revealed. A mechanism of the reactions was proposed. 相似文献
9.
Platonov V. V. Kudrya A. N. Proskuryakov S. V. 《Russian Journal of Applied Chemistry》2003,76(7):1182-1184
The structure of asphaltene compounds formed by homogeneous pyrolysis of 2-naphthol was studied. 相似文献
10.
V. M. Karpov T. V. Mezhenkora V. E. Platonov G. G. Yakobson° 《Russian Chemical Bulletin》1990,39(5):1000-1004
Taking perfluoro-1,1-dialkylbenzocyclobutenes as examples, it has been shown to be possible to enlarge the four-membered ring in polyfluorobenzocyclobutenes to five-membered in the presence of SbF5, by cleavage of the four-membered ring followed by cyclization of the resulting polyfluorostyrene to the polyfluoroindane, which then undergoes further reactions. Perfluoro-1-methyl-1-ethylbenzocyclobutene isomerizes at 50°C in the presence of SbF5 to perfluoro-,-o -trimethylstyrene, which is reversibly converted at 130°C into perfluoro-1,2-dimethylindane. Perfluoro-l,l-diethylbenzocyclobutene isomerizes at 130°C in the presence of SbF5 to give perfluoro- -ethyl-,o -dimethylstyrene, which at 170°C gives perfluoro-2-methyl-3-ethylindene- and perfluoro-2-methyl-3-ethyl-4,5,6,7-tetrahydroindene. The last two compounds, together with perfluoro-o-dipropylbenzene, are obtained from per fluoro-1,2-diethylbenzocyclobutene-with SbF5 at 170°C. From perfluoro-1-methyl-2-ethylbenzocyclobutene with SbF5 at 95°C there is obtained perfluoro-1-ethylindane, while at 130°C, in addition to the latter compound, there are obtained perfluorinated 1,1-dimethylindane, 1,2-dimethylindane, ,,o-trimethylstyrene, 2,3-dimethylindene, and 2,3-dimethyl-4,5,6,7-tetrahydroindene.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1114–1120, May, 1990. 相似文献