全文获取类型
收费全文 | 73篇 |
免费 | 0篇 |
国内免费 | 1篇 |
专业分类
化学 | 11篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 8篇 |
物理学 | 52篇 |
出版年
2012年 | 1篇 |
2011年 | 1篇 |
2010年 | 4篇 |
2009年 | 3篇 |
2008年 | 1篇 |
2007年 | 5篇 |
2006年 | 4篇 |
2005年 | 2篇 |
2004年 | 2篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 6篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有74条查询结果,搜索用时 15 毫秒
1.
The conformational energies, rotational barrier heights and molecular structures in C(CH2X)4 molecules (X=F, Cl, Br) based on molecular-mechanics calculations have been obtained. The results from these calculations are compared with the experimental gas-phase results. 相似文献
2.
Analysis of the beta-blockers oxprenolol, atenolol, timolol, propranolol, metoprolol, and acebutolol in human urine by a combination of isotachophoresis (ITP) and zone electrophoresis (ZE) was investigated. Methods were developed with a conventional capillary electrophoresis (CE) apparatus and a poly(methyl methacrylate) (PMMA) microchip system. With CE the separation of oxprenolol, atenolol, timolol, and acebutolol from a standard solution containing 5 microg/mL of each compound was accomplished by performing ZE with transient ITP. The electrolyte system consisted of 10 mM sodium morpholinoethane sulfonate (pH 5.5) and 0.1% methylhydroxyethylcellulose as the leading electrolyte and 30 mM ortho-phosphoric acid (pH 2.0) as both the terminating and the ZE background electrolyte. With the microchip system the separation of oxprenolol and acebutolol from a standard solution containing 10 microg/mL of each compound was accomplished by a coupled-channel ITP-ZE device using the same leading electrolyte solution as the CE system but 5 mM glutamic acid (pH 3.4) as terminating and background electrolytes. The systems were used for analyses of patient urine samples. Water-soluble hydrophilic matrix compounds were removed from the urine samples by solid-phase extraction (SPE). Limits of quantification below 5 microg/mL could be achieved. The PMMA ITP-ZE chip has not earlier been used for analyses of any drugs from urine samples. 相似文献
3.
R.-D. Herzberg N. Amzal J.E. Bastin F. Becker P.M.T. Brew P.A. Butler A.J.C. Chewter J.F.C. Cocks O. Dorvaux K. Eskola J. Gerl P.T. Greenlees N.J. Hammond K. Hauschild K. Helariutta F. Heßberger M. Houry A. Hürstel R.D. Humphreys G.D. Jones P.M. Jones R. Julin S. Juutinen H. Kankaanpää H. Kettunen T.L. Khoo W. Korten P. Kuusiniemi Y. Le Coz M. Leino A.P. Leppänen C.J. Lister R. Lucas M. Muikku P. Nieminen R.D. Page T. Page P. Rahkila P. Reiter Ch. Schlegel C. Scholey G. Sletten O. Stezowski Ch. Theisen W.H. Trzaska J. Uusitalo H.J. Wollersheim 《The European Physical Journal A - Hadrons and Nuclei》2002,15(1-2):205-208
In-beam conversion electron spectroscopy experiments have been performed on the transfermium nuclei 253, 254No using the conversion electron spectrometer SACRED in nearly collinear geometry in conjunction with the gas-filled separator
RITU at the University of Jyv?skyl?. The experimental setup is discussed and the spectra are compared to Monte Carlo simulations.
The implications for the ground-state configuration of 253No are discussed.
Received: 21 March 2002 / Accepted: 16 May 2002 / Published online: 31 October 2002
RID="a"
ID="a"e-mail: rdh@ns.ph.liv.ac.uk
RID="b"
ID="b"Present address: GANIL, F-14021 Caen, France.
RID="c"
ID="c"Permanent address: IReS Strasbourg, IN2P3-CNRS, F-67037-Strasbourg, France.
RID="d"
ID="d"Present address: CEA/DIF DCRE/SDE/LDN F-91680 Bruyeres-le-Chatel.
RID="e"
ID="e"Present address: Daresbury Laboratory, Daresbury WA4 4AD, UK.
RID="f"
ID="f"Permanent address: IPN Lyon, IN2P3-CNRS, F-69037 Lyon, France. 相似文献
4.
D. Sohler Zs. Dombrádi J. Blomqvist J. Cederkäll J. Huijnen M. Lipoglavšek M. Palacz A. Atac C. Fahlander H. Grawe A. Johnson A. Kerek W. Klamra J. Kownacki A. Likar L.-O. Norlin J. Nyberg J. Persson D. Seweryniak G. de Angelis P. Bednarczyk D. Foltescu D. Jerrestam S. Juutinen E. Mäkelä M. de Poli H.A. Roth T. Shizuma Ö. Skeppstedt G. Sletten J. Timár S. Törmänen M. Weiszflog 《The European Physical Journal A - Hadrons and Nuclei》2003,16(2):171-175
Excited states of 99Ag were populated via the 50Cr + 58Ni (261 MeV) reaction using the NORDBALL detector array equipped with charged-particle and neutron detector systems for reaction
channel separation. On the basis of the measured γγ-coincidence relations and angular distribution ratios a significantly
extended level scheme has been constructed up to E
x ∼ 7.8 MeV and I = 35/2. The experimental results were described within the framework of the shell model. Candidates for states fully aligned
in the πg
9/2
-3ν(d
5/2, g
7/2)2 valence configuration space were found at 4109 and 6265 keV.
Received: 18 June 2002 / Accepted: 11 October 2002 / Published online: 4 February 2003
RID="a"
ID="a"e-mail: sohler@atomki.hu
Communicated by J. ?yst? 相似文献
5.
J. Cederkäll M. Lipoglavšek M. Palacz J. Persson J. Blomqvist A. Ataċ C. Fahlander H. Grawe A. Johnson W. Klamra J. Kownacki A. Likar L.–O. Norlin J. Nyberg R. Schubart D. Seweryniak G. de Angelis P. Bednarczyk Z. Dombrádi D. Foltescu M. Górska D. Jerrestam S. Juutinen E. Mäkelä B. M. G. Perez M. de Poli H. A. T. Shizuma Ö. Skeppstedt G. Sletten S. Törmänen 《The European Physical Journal A - Hadrons and Nuclei》1998,1(1):7-9
New excited states have been observed in the neutron deficient isotope 98Ag following the 58Ni+50Cr →108Te* heavy–ion reaction. One of these states may be interpreted as a maximum spin aligned state of the πg9/2
−3νg7/2 configuration. Other possible interpretations within the nuclear shell model are discussed as well.
Received: 24 October 1997 相似文献
6.
D. Sohler Zs. Dombrádi S. Brant J. Cederkäll M. Lipoglavšek M. Palacz V. Paar J. Persson A. Atac̣ C. Fahlander H. Grawe A. Johnson A. Kerek W. Klamra J. Kownacki A. Likar L. O. Norlin J. Nyberg R. Schubart D. Seweryniak G. de Angelis P. Bednarczyk D. Foltescu M. Fayez-Hassan D. Jerrestam S. Juutinen E. Mäkelä B. M. Nyakó M. de Poli H. A. Roth T. Shizuma Ö. Skeppstedt G. Sletten S. Törmänen 《Zeitschrift für Physik A Hadrons and Nuclei》1997,357(3):239-240
Excited states of 65Ge were populated via the 12C + 58Ni (261 MeV) reaction using the NORDBALL detector array equipped with charged-particle and neutron detector systems for reaction channel separation. On the basis of γγ-coincidence relations and angular distribution ratios a significantly extended level scheme was constructed up to E x = 9 MeV and J π = (33/2?). The low-energy states of the nucleus are discussed in the framework of the interacting boson-fermion model. 相似文献
7.
Pekka Kekäläinen Mikko Voutilainen Antti Poteri Pirkko Hölttä Aimo Hautojärvi Jussi Timonen 《Transport in Porous Media》2011,87(1):125-149
A model transport system is considered in which a pulse of tracer molecules is advected along a flow channel with porous walls.
The advected tracer thus undergoes diffusion, matrix-diffusion, inside the walls, which affects the breakthrough curve of
the tracer. Analytical solutions in the form of series expansions are derived for a number of situations which include a finite
depth of the porous matrix, varying aperture of the flow channel, and longitudinal diffusion and Taylor dispersion of the
tracer in the flow channel. Novel expansions for the Laplace transforms of the concentration in the channel facilitated closed-form
expressions for the solutions. A rigorous result is also derived for the asymptotic form of the breakthrough curve for a finite
depth of the porous matrix, which is very different from that for an infinite matrix. A specific experimental system was created
for validation of matrix-diffusion modeling for a matrix of finite depth. A previously reported fracture-column experiment
was also modeled. In both cases model solutions gave excellent fits to the measured breakthrough curves with very consistent
values for the diffusion coefficients used as the fitting parameters. The matrix-diffusion modeling performed could thereby
be validated. 相似文献
8.
H. C. Scraggs E. S. Paul A. J. Boston J. F. C. Cocks D. M. Cullen K. Helariutta P. M. Jones R. Julin S. Juutinen H. Kankaanp M. Muikku P. J. Nolan C. M. Parry A. Savelius R. Wadsworth A. V. Afanasjev I. Ragnarsson 《Nuclear Physics A》1998,640(3-4):337-361
High-spin states have been populated in 54119Xe via the 96Mo(27Al,p3n) reaction at 133 MeV, using the
γ-ray spectrometer to record triple γ-ray coincidences. The known level scheme has been significantly extended and several band crossings identified. In particular, the νh11/2 yrast band has been extended to Iπ = (83/2−) and shows features which are consistent with those of smooth band termination at high spin. Theoretical results for 119Xe at high spin are discussed within the framework of cranked Nilsson-Strutinsky calculations, together with results for 117Xe. 相似文献
9.
G. Lhersonneau B. Pfeiffer J. R. Persson J. Suhonen J. Toivanen P. Campbell P. Dendooven A. Honkanen M. Huhta P. M. Jones R. Julin S. Juutinen M. Oinonen H. Penttilä K. Peräjärvi A. Savelius W. Jicheng J. C. Wang J. Äystö 《Zeitschrift für Physik A Hadrons and Nuclei》1997,358(3):317-327
The decay of 99Nb to 99Mo has been investigated. The use of the ion-guide technique for on-line mass separation and of a Ge-array for γ-ray detection have allowed the observation of decay branchings lower than 10?3. Mediumspin levels, some already known from reaction studies and new ones at high energy, are populated. The β-feeding patterns of the decays of the 9/2+ states in 99Nb and in its isotones 97Y, and 101Tc are qualitatively reproduced by QRPA calculations. 相似文献
10.
D. Seweryniak B. Cederwall J. Nyberg C. Fahlander A. Johnson A. Kerek J. Kownacki L. -O. Norlin E. Adamides A. Atac J. Blomqvist H. Grawe E. Ideguchi R. Julin S. Juutinen W. Karczmarczyk S. Mitarai M. Piiparinen R. Schubart G. Sletten S. Törmänen A. Virtanen 《Zeitschrift für Physik A Hadrons and Nuclei》1993,345(2):243-244
Neutron deficient nuclei close to 100Snhave been investigated in-beam by γ-ray spectroscopic methods using the NORDBALL detector array. A beam of 270 MeV 58Niwas used to bombard a target of 54Fe.Reaction channel separation was achieved with a 4π charged particle multidetector setup together with a 1π neutron detector wall placed in the forward direction. Excited states of 102Inwere identified for the first time. The level scheme constructed from γ-γ-particle-coincidence and γ-γ-angular correlation analysis is presented. The structure of 102 In is discussed and compared to neighboring nuclei in the framework of the nuclear shell-model. 相似文献