排序方式: 共有19条查询结果,搜索用时 15 毫秒
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针对非实时成像中动态场景偏振探测产生的虚假偏振信息问题,充分利用渥拉斯顿棱镜的分光特性,设计了一种新型实时偏振成像系统.采用像方远心望远透镜系统、准直透镜系统并设计匹配的成像镜系统,在单探测器阵列上同时获取偏振态相互垂直的两幅偏振图像.通过全系统联动设计与优化,系统的调制传递函数在截止频率处不小于0.55,全系统弥散斑均方根半径小于5.3μm,即小于探测器像元尺寸,满足成像设计要求.仿真结果证明该成像系统可有效解决传统分振幅偏振成像系统的实时性差的不足,分孔径偏振成像系统的能量利用率和分辨率低的问题以及偏振焦平面方法中光路串扰的缺陷,应用前景广阔. 相似文献
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通过甲基丙烯酸与苯乙烯聚合制备了表面负电性的聚苯乙烯(PSt)纳米乳胶粒. 在乙醇与水的混合溶剂中, 用硅烷偶联剂乙烯基三甲氧基硅烷对其进行表面改性后加入钛酸四丁酯、 氯化钠和硝酸银, 以PSt乳胶粒为模板采用共沉淀法制备了PSt-AgCl-TiO2复合微球. 在180 ℃对其进行液相预处理及煅烧去除PSt模板后制备了Ag/AgCl-TiO2空心复合粒子. 对各阶段产物的形貌、 晶体结构和比表面积等进行了表征. 结果表明, 所得产物为Ag/AgCl与锐钛矿型TiO2复合的空心粒子, 其比表面远大于商品TiO2(P25). 考察了Ag/AgCl-TiO2复合粒子在紫外光与可见光下对罗丹明B(RhB)降解的催化活性. 结果表明, 在紫外光下n(Ag)/n(Ti)=0.1%的Ag/AgCl-TiO2复合粒子活性最高, 30 min时对RhB的降解率比不含Ag/AgCl的TiO2空心微球提高了13%; 虽然Ag/AgCl-TiO2在可见光下的催化活性远比紫外光下低, 但与纯TiO2空心纳米微球相比其催化活性仍明显增强. n(Ag)/n(Ti)=2.0%的Ag/AgCl-TiO2复合粒子催化活性最高, 120 min时对RhB的降解率比不含Ag/AgCl的TiO2空心微球提高了38%. 相似文献
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Ag掺杂型空心TiO2纳米微球的制备与表征及其光催化性能 总被引:1,自引:0,他引:1
通过甲基丙烯酸与苯乙烯的乳液聚合制备了表面载有阴离子的聚苯乙烯(PSt)纳米乳胶粒. 在乙醇与水的混合溶剂中, 用硅烷偶联剂乙烯基三甲氧基硅烷对其进行表面改性. 以此乳胶粒为模板, 加入钛酸四丁酯和硝酸银制备了Ag2O掺杂型聚苯乙烯/二氧化钛(PSt/TiO2)复合微球. 对该微球在180 °C进行液相预处理、干燥、500 °C煅烧等步骤制备了Ag 掺杂型Ag-TiO2复合粒子. 通过扫描电镜(SEM)、透射电镜(TEM)和X射线衍射(XRD)等手段对PSt/TiO2复合粒子及Ag-TiO2空心粒子的形貌及晶体结构等进行了表征. 考察了Ag-TiO2复合粒子在紫外光(365 nm)与紫外-可见光(370-760 nm)下对罗丹明B (RhB)降解的催化活性. 结果表明, 与不含银的TiO2空心微球相比, 在紫外光照射下, 银含量(nAg/nTi)为0.1%的Ag-TiO2复合粒子对RhB的降解率提高了11%左右; 在紫外-可见光照射下, nAg/nTi为1.0%和2.0% 的Ag-TiO2复合粒子对RhB的降解率提高了30%左右. 相似文献
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The asymmetric epoxidation of 2-cyclohexen-1-one with aqueous H(2)O(2) as oxidant, 1,2-diaminocyclohexane as catalyst, and a Br?nsted acid trifluoroacetic acid (TFA) as cocatalyst has been studied by performing density functional theory calculations. It is confirmed that the catalyzed epoxidation proceeds via sequential nucleophilic addition and ring-closure processes involving a ketiminium intermediate. Four possible pathways associated with two Z isomers and two E isomers of ketiminium have been explored in detail. Our calculation indicates that these four pathways have high barriers and a small energy gap between two more favorable R and S pathways. We have analyzed the effects of the TFA anion and H(2)O on the activity and enantioselectivity of catalytic epoxidation. It is found that the TFA anion acts as a counterion to stabilize the transition states of the catalytic epoxidation by hydrogen-bond acceptance, leading to decreases in the barriers of the nucleophilic addition and ring-closure processes. The most significant decrease occurred in the ring-closure step of the Z-R-pathway, resulting in H-bond-induced enantioselectivity. Our calculations also show that water cooperates with TFA to further increase the reaction rate significantly. 相似文献
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Ying Zhou Shu Zheng Yang Guo Ping-Li 《International Journal of Theoretical Physics》2013,52(10):3367-3375
According to the basic rules of finite difference method,we calculate massive charged scalar field quasinormal modes of Reissner-Nordström-de Sitter Black Hole with a global monopole, which shows that when electronic quantity of scalar field e is comparatively small, all the factors including angular quantum number, the mass of scalar field, the size of horizon and the breaking scale will influence the frequency spectrum of quasinormal modes. When e is more than some definite critical value, second-order transition will appear and after that the curve of frequency spectrum rises, the black hole is no longer steady, which means when e is greater than some definite critical value, the structure of black hole can be changed. While the size of angular quantum number and breaking scale will influence the happening time of second-order transition. When breaking scale is less than some definite critical value, the second-order transition can be vanished. 相似文献
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针对实时广域高分辨率成像需求,充分利用具有对称结构的多层共心球透镜视场大且各轴外视场成像效果一致性好的特点,设计基于共心球透镜的多尺度广域高分辨率计算成像系统.该系统基于计算成像原理,通过构建像差优化函数获得光学系统设计参数,结合球形分布的次级相机阵列进行全局性优化,提高系统性能的同时有效简化光学设计过程、降低系统设计难度.系统稳定性测试结果表明,该成像系统的MTF(modulation transmission function)值在截止频率处接近衍射极限,弥散斑均方根恒小于探测器像元尺寸,整机实景实时成像效果良好,无视觉可见畸变.该系统不仅有效解决了传统成像中广域和高分辨率成像矛盾的问题,而且为计算光学成像系统设计奠定了一定研究基础. 相似文献