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Andrew M. Piggott 《Tetrahedron letters》2007,48(42):7452-7455
Sulfinamides are important in enantioselective synthesis, as rare post-translational modifications of proteins and as isosteres of the amide bond. Little is known about the rates of hydrolysis for aliphatic sulfinamides or the mechanism of hydrolysis. In this Letter, we show that sulfinamides hydrolyse by predominantly a non-specific acid/base catalysis with phosphate buffer but by varying the buffer concentration, it was possible to determine the hydrolysis rates of a range of sulfinamides with water through non-linear least squares regression. 相似文献
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Garcia Ruano JL Alemparte C Martin Castro AM Adams H Rodriguez Ramos JH 《The Journal of organic chemistry》2000,65(23):7938-7943
The behavior of (Z)-3-p-tolylsulfinylacrylonitrile (1) as a chiral dienophile has been evaluated from its reactions with furan and acyclic dienes. Electrostatic interactions of the cyano group with the sulfinyl one restrict the conformational mobility around the C-S bond, thus controlling the pi-facial selectivity, which is almost complete in all cases, the approach of the diene from the less-hindered face of the dienophile (that bearing the lone electron pair) in the predominant rotamer being the favored one. The regioselectivity is also completely controlled by the cyano group. Additionally, the reactivity of compound 1 as well as its endo-selectivity are both higher than those observed for the corresponding (Z)-3-sulfinylacrylates, thus proving the potential of sulfinylnitriles as chiral dienophiles. 相似文献
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EI Rodriguez Martinez CI Barriga-Paulino MI Zapata CC Chinchilla AM López-Jiménez CM Gómez 《BMC neuroscience》2012,13(1):104-23
ABSTRACT: BACKGROUND: The peri-adolescent period is a crucial developmental moment of transition from childhood to emergent adulthood. The present report analyses the differences in Power Spectrum (PS) of the Electroencephalogram (EEG) between late childhood (24 children between 8 and 13 years old) and young adulthood (24 young adults between 18 and 23 years old). RESULTS: The narrow band analysis of the Electroencephalogram was computed in the frequency range of 0--20 Hz. The analysis of mean and variance suggested that six frequency ranges presented a different rate of maturation at these ages, namely: low delta, delta-theta, low alpha, high alpha, low beta and high beta. For most of these bands the maturation seems to occur later in anterior sites than posterior sites. Correlational analysis showed a lower pattern of correlation between different frequencies in children than in young adults, suggesting a certain asynchrony in the maturation of different rhythms. The topographical analysis revealed similar topographies of the different rhythms in children and young adults. Principal Component Analysis (PCA) demonstrated the same internal structure for the Electroencephalogram of both age groups. Principal Component Analysis allowed to separate four subcomponents in the alpha range. All these subcomponents peaked at a lower frequency in children than in young adults. CONCLUSIONS: The present approaches complement and solve some of the incertitudes when the classical brain broad rhythm analysis is applied. Children have a higher absolute power than young adults for frequency ranges between 0-20 Hz, the correlation of Power Spectrum (PS) with age and the variance age comparison showed that there are six ranges of frequencies that can distinguish the level of EEG maturation in children and adults. The establishment of maturational order of different frequencies and its possible maturational interdependence would require a complete series including all the different ages. 相似文献
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Qian Wang Assoc. Prof. Fuhang Song Dr. Xue Xiao Pei Huang Assoc. Prof. Li Li Prof. Aaron Monte Dr. Wael M. Abdel‐Mageed Dr. Jian Wang Hui Guo Dr. Wenni He Feng Xie Dr. Huanqin Dai Miaomiao Liu Dr. Caixia Chen Hao Xu Assoc. Prof. Mei Liu Dr. Andrew M. Piggott Assoc. Prof. Xueting Liu Prof. Robert J. Capon Prof. Lixin Zhang 《Angewandte Chemie (International ed. in English)》2013,52(4):1231-1234
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A method of estimating contact angles is described in which 1000 A thick layers of metals are condensed from the vapour. If condensation takes place at temperatures greater than about 0.8 Tm the film is observed to break up into drops which are approximately segments of spheres, and the contact angle may be calculated from measurements on the drop size when the average film thickness is known. The experimental method is straightforward and relatively very fast, yet gives results in good agreement with earlier measurements. Results for the following metals on sapphire are presented: Al, Ag, Au, Cu, In, Sn. In addition results for Al on quartz are discussed, and it is suggested that the method may give meaningful results even when, as in this case, chemical reaction takes place. 相似文献
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We propose a picture of Wigner function scars as a sequence of concentric rings along a two-dimensional surface inside a periodic orbit. This is verified for a two-dimensional plane that contains a classical hyperbolic orbit of a Hamiltonian system with 2 degrees of freedom. The stationary wave functions are the familiar mixture of scarred and random waves, but the spectral average of the Wigner functions in part of the plane is nearly that of a harmonic oscillator and individual states are also remarkably regular. These results are interpreted in terms of the semiclassical picture of chords and centers. 相似文献
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Sun R Colin E Ajitanand NN Alexander JM Barton MA DeYoung PA Drake KL Elmaani A Gelderloos CJ Gualtieri EE Guinet D Hannuschke S Jaasma JA Kowalski L Lacey RA Lauret J Norbeck E Pak R Peaslee GF Stern M Stone NT Sundbeck SD Vander Molen AM Westfall GD Yang LB Yee J 《Physical review letters》2000,84(1):43-46
For central collisions of (17-115)A MeV 40Ar+Cu, Ag, Au, an overall balance is determined for the average mass, energy, and longitudinal momentum. Light charged particles and fragments are separated into forward-focused and isotropic components in the frame of the heaviest fragment. Energy removal by the isotropic component reaches 1-2 GeV. For such high deposition energies, statistical multifragmentation models predict much more extensive nuclear disassembly than is observed. 相似文献