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1.
In this paper the explicit form of such systems of conservation laws, which imply an additional conservation law, is determined. It is shown that there are many classes of such systems besides the symmetric conservative ones. From the point of view of phenomenological thermodynamics, this result can be interpreted as a sort of integration of the constraints imposed by the second law of thermodynamics.  相似文献   
2.
Enthalpies of dissolution of benzo-15-crown-5 ether (B15C5) in mixtures of acetonitrile with water and in solutions of NaI and NaBPh4 (I=0.05 mol dm–3) in these mixtures were measured at 298.15 K. From the obtained results and appropriate literature data, the thermodynamic functions of B15C5/Na+ complex formation in acetonitrile-water mixtures were determined. The enthalpies of transfer of the complex B15C5/Na+ from pure acetonitrile to the examined mixtures were calculated and are discussed.  相似文献   
3.
This communication describes the synthesis of l-methyl-2,3-diformylpyrrole. This new compound is used to prepare a new heterocycle, l-methylcyclohepta[b]pyrrol-6-one and thus allows a new synthesis of l-methylpyrrolo[2,3-d]pyridazine.  相似文献   
4.
This paper is devoted to a discussion of the notion of localizability for phonons, i.e., quasiparticles arising from the harmonic vibrations of a system ofn atoms bound to one another by elastic forces. The natural tools for the analysis of localizability are the projection operatorsÊ() acting on the Hilbert space of one-phonon states, where is an arbitrary subset of the set that consists ofn vectors specifying the equilibrium positions ofn atoms. The expectation value ofÊ() is the probability that the phonon belongs to the atoms whose equilibrium positions are characterized by the elements of . For a strongly localizable phonon all of the projection operatorsÊ() commute with one another, whereas in the case of a weakly localizable phonon the operatorsÊ(1) andÊ(2) do not commute when 1 and 2 overlap. With the aid of the Jauch-Piron quantum theory of localization in space, the present paper describes the method of obtainingÊ() and also shows that if in the system ofn atoms there exist normal modes of zero frequency, then the phonon is only weakly localizable. Given the explicit expression forÊ(), one can define the number-of-phonons operator as well as the quasiparticle analogue (given in a companion paper) of the Wigner distribution function.  相似文献   
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The standard molar enthalpies of solution at infinite dilution \Updelta\textsol H\textm \Updelta_{\text{sol}} H_{\text{m}}^{\infty } of glycylglycine, dl-alanyl-dl-alanine and glycylglycylglycine in aqueous solutions of potassium chloride and ethanol as well as of glycylglycine and glycylglycylglycine in the solutions containing urea and water have been determined by calorimetry at the temperature 298.15 K. Changes of solution enthalpy, expressed in a form so-called heterotactic interaction coefficients, h\textxy h_{\text{xy}} were used for analysis of interactions occurring between the investigated solutes in water. The group contributions illustrating the interactions of KCl, urea and ethanol with selected functional groups in the peptide molecules, namely CH2, “pep,” and “ion” groups, were calculated and discussed.  相似文献   
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This article describes the synthesis of a new heterocycle, pyrido[2,3,f]phtalazine and three new diformylquinolincs.  相似文献   
10.
The synthesis of two new heterocycles is described: pyrido-[2,3-d]-.s-triazolo[ 3,4-f] pyrimidine and pyrido[3,2-d]-.s-triayzolo-[3,4-f] pyrimidine. 4-[I'-Pyrazolyl]pyrido[2,3-d]pyrimidines and 4-[1′-pyrazoly1] pyrido[ 3,2-d] pyrimidine are obtained by the action of 4-hydrazinopyrido[2,3-d]pyrimidine and 4-hydrazinopyrido-[3,2-d]pyrimidine with several β-diketones.  相似文献   
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