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1.
A self-consistent model of the development of dendrites and partial discharges in a dielectric solid under a variable voltage
is suggested. Dendrites originate at sites with the enhanced local field strength and also where the dielectric is broken
down under the action of partial discharges. The numerical simulation is used to quantitatively describe the space-time dynamics
of the dendrites and partial discharges in epoxy resin for the tip-plane electrode configuration. The simulated data are compared
with electrical measurements of partial discharges and with optical images of dendrite growth under the same conditions. 相似文献
2.
3.
P. Schwab A. Kochemasov R. Kullmer D. Bäuerle 《Applied Physics A: Materials Science & Processing》1992,54(2):166-169
Pulsed-laser deposition of YBa2Cu3O7 in N2O permits lowering of the substrate temperature with respect to deposition in O2 atmosphere. Additional photodissociation of N2O near the substrate surface deteriorates the superconducting properties of deposited films.On leave from: Institute of Applied Physics of the Academy of Sciences of the USSR, SU-603600 Nishni Nowgorod, USSR 相似文献
4.
C. Donzaud S. Czajkowski P. Armbruster M. Bernas C. Böckstiegel P. Dessagne H. Geissel E. Hanelt A. Heinz C. Kozhuharov C. Miehé G. Münzenberg M. Pfützner W. Schwab C. Stéphan K. Sümmerer L. Tassan-Got B. Voss 《The European Physical Journal A - Hadrons and Nuclei》1998,1(4):407-426
Projectile fission of 750 AMeV 238U-ions interacting with a Pb target was studied by means of the spectrometer FRS, GSI-Darmstadt. One of the two fission fragments
was detected with a transmission of few percent and identified in mass and charge. Low-energy fission (E* < 25 MeV) events were selected by their magnetic rigidity. Whereas the production of asymmetric fission events is dominated
by the GDR excitation, very asymmetric fission and symmetric fission take place after a GQR or DGDR excitation or after a
nuclear interaction. Cross sections of more than 250 isotopes were measured. Isotopic distributions of low-energy fission
were reconstructed for elements from Se to Te. The fission modes SI, SII and SL were clearly shown in these distributions
and in the mass and TKE distributions. Charge polarization and mass dispersion were deduced for each fission mode. Finally,
the characteristics of the low-energy fission process explain the production rates of neutron-rich species.
Received: 14 July 1997 / Revised version: 6 October 1997 相似文献
5.
In this paper, we investigate {1,2,3}-semiaffine planes. All such planes of order n >51 shall be classified. It turns out that they are embeddable into projective planes of the same order n in the most natural way.Work supported by National Research Project on Strutture Geometriche Combinatoria, loro applicazioni of Italian M.P.I. and G.N.S.A.G.A. of C.N.R. 相似文献
6.
We describe a convergent synthesis of eight 1,3,5- and 1,2,4,5-substituted benzene derivatives with long rigid arms containing 4-pyridyl, 2,2'-bipyridyl, and 2,2'-bipyrimidyl termini, meant to be used as trigonal or tetragonal connectors for the construction of large molecular structures. The synthesis involved copper-free Pd-mediated coupling of terminal acetylenes to aryl halides. First, one of the termini of 1,3-diethynylbicyclo[1.1.1]pentane was coupled with a brominated aza heterocycle, and second, 3 equiv of the resulting extended arm were coupled with 1,3,5-triiodobenzene or 4 with 1,2,4,5-tetraiodobenzene. An improved large-scale synthesis for 1,3-diethynylbicyclo[1.1.1]pentane is described. The structures of two of the arms were determined by single-crystal X-ray analysis. Several long molecular rods with 4-pyridyl termini were obtained as byproducts, and a single-crystal X-ray structure is reported for the shortest of these. 相似文献
7.
Preparation and physical and chemical properties of 3-ethinyl-2,4-diformyl-pentandial (3 a) and its salts are described.3 a contains 2 malonaldehyde groups. Starting from3 a, 4H-pyranes, 4H-dihydropyridines, dipyrazoles, diisoxazoles, bisdiazepines and vinamidine derivates are obtained.
Mit 1 Abbildung 相似文献
Mit 1 Abbildung 相似文献
8.
Colour Effects in Oxidic and Other Mn2+ Compounds – the Ligand Field Spectra of Mixed Crystals MgO/MnO, CaO/MnO, and of MnAl2O4 The colour intensity and the shift of the hue is examined for mixed crystals Mg1?xMnxIIO and Mn1?yIICayO in dependence of the Mn2+-concentration and interpreted in terms of Mn2+? Mn2+ pair interactions and variations of the Mn? O bond length, respectively. The experimental band positions (sextet-quartet transitions) could be fitted quantitatively – also in case of Mn2+ in tetrahedral (MnAl2O4) and dodecahedral oxygen coordination (Mn3Al2Ge3O12, MnY2Mg2Ge3O12) – by means of crystal field calculations. The obtained ligand field parameters are discussed in comparison with data for octahedral Mn2+ ions with H2O, F? and Cl? as ligands. 相似文献
9.
The complexes Ru(L1-CH3)(CO)3Cl, RuL2(CO)2Cl2, and RuL3(CO)2Cl2 (L1= 6-methoxy-5,8-quinolinedione, L2 = 7-amino-6-methoxy-5,8-quinolinedione, L3 = 6,6'-dimethoxycarbonyl-2,2'-bipyridine) were prepared by reaction of L1-L3 with the tricarbonyldichlororuthenium(II) dimer. L1-L3 act as bidentates through the ortho oxygen atoms, the pyridyl nitrogen and the adjacent quinone oxygen, and the bipyridyl nitrogens, respectively. RuL3(CO)2Cl2 is characterized by X-ray crystallography. 15N NMR correlation spectra give upfield shifts of around 60 ppm for the pyridyl nitrogens that are coordinated to the metal, while 13C NMR correlation spectra give a downfield shift of 10 ppm for the quinone carbonyl group that is coordinated to the metal. The electrochemistry of RuL2(CO)2Cl2 is examined, and the implications for the formation of metal complexes of the antitumor antibiotic streptonigrin, which cleaves DNA in the presence of metal ions, are discussed. 相似文献
10.
A tungsten neopentylidene complex has been found to decompose to yield a heterochiral dimer that contains a W=W double bond and no bridging ligands. Decompositions of related bisalkoxide complexes also yield compounds that contain an "unsupported" W=W double bond, while a sample of [Mo(NAr)(CH2-t-Bu)(OC6F5)]2 has been found to be a homochiral species related to [W(NAr)(CH2-t-Bu)(OC6F5)]2. 相似文献