全文获取类型
收费全文 | 49篇 |
免费 | 0篇 |
专业分类
化学 | 18篇 |
力学 | 3篇 |
数学 | 10篇 |
物理学 | 18篇 |
出版年
2021年 | 1篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2012年 | 1篇 |
2010年 | 1篇 |
2009年 | 2篇 |
2008年 | 3篇 |
2005年 | 2篇 |
2004年 | 2篇 |
2003年 | 1篇 |
2002年 | 2篇 |
2001年 | 3篇 |
1999年 | 1篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1993年 | 1篇 |
1990年 | 2篇 |
1988年 | 2篇 |
1984年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1966年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有49条查询结果,搜索用时 46 毫秒
1.
JOSEF MÁLEK JINDŘICH NEČAS K. R. RAJAGOPAL 《Archive for Rational Mechanics and Analysis》2002,165(3):243-269
To describe the flows of fluids over a wide range of pressures, it is necessary to take into account the fact that the viscosity
of the fluid depends on the pressure. That the viscosity depends on the pressure has been verified by numerous careful experiments.
While the existence of solutions local-in-time to the equations governing the flows of such fluids are available for small,
special data and rather unrealistic dependence of the viscosity on the pressure, no global existence results are in place.
Our interest here is to establish the existence of weak solutions for spatially periodic three-dimensional flows that are
global in time, for a large class of physically meaningful viscosity-pressure relationships.
(Accepted May 1, 2002) Published online November 15, 2002
Communicated by S. S. ANTMAN 相似文献
2.
Dr. James P. Dombrowski Dr. Micah S. Ziegler Dr. Neelay M. Phadke Erum Mansoor Dr. Daniel S. Levine Dr. Ryan J. Witzke Prof. Dr. Martin Head-Gordon Prof. Dr. Alexis T. Bell Prof. Dr. T. Don Tilley 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(1):307-315
Anionic molecular models for nonhydrolyzed and partially hydrolyzed aluminum and gallium framework sites on silica, M[OSi(OtBu)3]4− and HOM[OSi(OtBu)3]3− (where M=Al or Ga), were synthesized from anionic chlorides Li{M[OSi(OtBu)3]3Cl} in salt metathesis reactions. Sequestration of lithium cations with [12]crown-4 afforded charge-separated ion pairs composed of monomeric anions M[OSi(OtBu)3]4− with outer-sphere [([12]crown-4)2Li]+ cations, and hydroxides {HOM[OSi(OtBu)3]3} with pendant [([12]crown-4)Li]+ cations. These molecular models were characterized by single-crystal X-ray diffraction, vibrational spectroscopy, mass spectrometry and NMR spectroscopy. Upon treatment of monomeric [([12]crown-4)Li]{HOM[OSi(OtBu)3]3} complexes with benzyl alcohol, benzyloxide complexes were formed, modeling a possible pathway for the formation of active sites for Meerwin–Ponndorf–Verley (MPV) transfer hydrogenations with Al/Ga-doped silica catalysts. 相似文献
3.
Previous attempts to synthesize boracyclanes in the medium-ring range (9-, 10-, 11-, and 12-ring members) via cyclic hydroboration of α,ω-dienes have failed. However, their synthesis via the sequential one-carbon homologation of B-methoxyboracyclanes has been achieved utilizing the successive reaction of B-methoxyboracyclanes with in situ generated (chloromethyl)lithium (LiCH2Cl): MeOB(CH2)5 → MeOB(CH2)6 → MeOB(CH2)7 → MeOB(CH2)8 → MeOB(CH2)9 → MeOB(CH2)10 → MeOB(CH2)11. The yields achieved are in the range of 75–85%. In each case the products are identified by conversion via the DCME reaction into the known cycloalkanones. This development provides the first entry into boracyclanes of the strained medium ring range. 相似文献
4.
5.
6.
G. Bossi B. Dubini P. Mariani M. G. Ponzi Bossi F. Rustichelli R. S. Phadke 《Il Nuovo Cimento D》1990,12(9):1293-1308
Summary We report a thermodynamical and structural investigation on the effect of a dicarboxylic acid, the azelaic acid, on a synthetic
phosophatidylcholine in excess water condition. The results indicate that the drug interacts with the lipid headgroup region,
near to the hydrocarbon chains: in particular, at higher concentrations investigated, an interdigitated ?gel phase?, with
rigid chains, stiff and perpendicular to the lamellar planes, is induced. The experimental electron density profiles, obtained
for samples containing low and high quantity of azelaic acid, support the proposed interaction. Moreover, step electron density
models, used to confirm the selected sign combination of the observed structure factors, show the best agreement with the
experimental data when the chain terminal methyl groups are frozen in fixed position.
Work presented at the second USSR-Italy Bilateral Meeting on Liquid Crystals held in Moscow, September 15–21, 1988. 相似文献
7.
A waveguide in integrated optics is defined by its refractiveindex. The guide is assumed to be invariant in the propagationdirection while in the transverse direction it is supposed tobe a compact perturbation of an unbounded stratified medium.We are interested in the modes guided by this device, whichare waves with a transverse energy confined in a neighbourhoodof the perturbation. Our goal is to analyse the existence of such guided modes. Underthe assumptions of weak guidance the problem reduces to a two-dimensionaleigenvalue problem for a scalar field. The associated operatoris unbounded, selfadjoint, and bounded from below. Its spectrumconsists of the discrete spectrum corresponding to the guidedmodes and of the essential spectrum corresponding to the radiationmodes. We present existence results of guided modes and an asymptoticstudy at high frequencies, which shows that contrarily to thecase of optical fibers, the number of guided modes can remainbounded. The major tools are the min-max principle and comparisonof results between different eigenvalue problems. The originalityof the present study lies in the stratified character of theunbounded reference medium. 相似文献
8.
9.
Jay Jin Saranya Kittanakom Victoria Wong Beverly AS Reyes Elisabeth J Van Bockstaele Igor Stagljar Wade Berrettini Robert Levenson 《BMC neuroscience》2010,11(1):33
Background
Opioid agonist drugs produce analgesia. However, long-term exposure to opioid agonists may lead to opioid dependence. The analgesic and addictive properties of opioid agonist drugs are mediated primarily via the mu-opioid receptor (MOR). Opioid agonists appear to alter neuronal morphology in key brain regions implicated in the development of opioid dependence. However, the precise role of the MOR in the development of these neuronal alterations remains elusive. We hypothesize that identifying and characterizing novel MOR interacting proteins (MORIPs) may help to elucidate the underlying mechanisms involved in the development of opioid dependence. 相似文献10.
Manisha U. Phadke Vivek K. Jadhav Rajendra K. Jadhav Suraj S. Dave Dattatray S. Patil 《Chromatographia》2008,68(11-12):1003-1007
A simple, fast and precise reversed phase liquid chromatographic method was developed for the simultaneous determination of artesunate (AS) and amodiaquine (AD) in combined pharmaceutical dosage form. Chromatographic separation of the two drugs was performed on a BDS Hypersil C18, 100 mm × 4.6 mm, 3 μm particle size column as stationary phase with a mobile phase comprising of phosphate buffer (pH 3.0 with orthophosphoric acid) and acetonitrile in the proportion of 50:40 (v/v), at a flow rate of 0.8 mL min?1 and UV detection at wavelength 210 nm for AS and 300 nm for AD using photo diode array detection. The proposed method was validated for specificity, accuracy, linearity, range, precision and was successfully applied to the simultaneous determination of AS and AD in the combined fixed dosage form without any excipient’s interference. 相似文献