全文获取类型
收费全文 | 84篇 |
免费 | 1篇 |
专业分类
化学 | 23篇 |
数学 | 5篇 |
物理学 | 57篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2020年 | 2篇 |
2016年 | 1篇 |
2013年 | 1篇 |
2012年 | 3篇 |
2011年 | 2篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2007年 | 5篇 |
2006年 | 1篇 |
2005年 | 3篇 |
2004年 | 1篇 |
2003年 | 4篇 |
2002年 | 3篇 |
2001年 | 7篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1933年 | 1篇 |
排序方式: 共有85条查询结果,搜索用时 15 毫秒
1.
C. Donzaud S. Czajkowski P. Armbruster M. Bernas C. Böckstiegel P. Dessagne H. Geissel E. Hanelt A. Heinz C. Kozhuharov C. Miehé G. Münzenberg M. Pfützner W. Schwab C. Stéphan K. Sümmerer L. Tassan-Got B. Voss 《The European Physical Journal A - Hadrons and Nuclei》1998,1(4):407-426
Projectile fission of 750 AMeV 238U-ions interacting with a Pb target was studied by means of the spectrometer FRS, GSI-Darmstadt. One of the two fission fragments
was detected with a transmission of few percent and identified in mass and charge. Low-energy fission (E* < 25 MeV) events were selected by their magnetic rigidity. Whereas the production of asymmetric fission events is dominated
by the GDR excitation, very asymmetric fission and symmetric fission take place after a GQR or DGDR excitation or after a
nuclear interaction. Cross sections of more than 250 isotopes were measured. Isotopic distributions of low-energy fission
were reconstructed for elements from Se to Te. The fission modes SI, SII and SL were clearly shown in these distributions
and in the mass and TKE distributions. Charge polarization and mass dispersion were deduced for each fission mode. Finally,
the characteristics of the low-energy fission process explain the production rates of neutron-rich species.
Received: 14 July 1997 / Revised version: 6 October 1997 相似文献
2.
Jochum KP Stoll B Pfänder JA Seufert M Flanz M Maissenbacher P Hofmann AW Hofmann AW 《Fresenius' Journal of Analytical Chemistry》2001,370(5):647-653
Spark source mass spectrometry (SSMS) has experienced important and significant improvements in nearly all analytical features by the use of a multiple ion counting (MIC) system. Two procedures have recently been developed to further increase the analytical capabilities of MIC-SSMS in geochemistry. These are a mathematical correction of interferences, which is often necessary for the ultra trace element analysis of Nb, Ta, Zr, Hf and Y, and the development of an autospark system to hold the total ion beam constant. New analytical data for geological samples, especially international reference materials, are presented using the improved MIC-SSMS technique. The data set consists of high precision and low abundance data for Zr, Nb and Y in depleted reference materials. The MIC-SSMS results are compared with those of conventional SSMS using photoplates for ion detection. The precision of the MIC-SSMS isotope ratio measurements (about 1%) is more than a factor of 3 better than that of conventional SSMS, as demonstrated by analyses of Hawaiian samples. Total uncertainties of MIC-SSMS concentration data including all sources of error are generally between 2 and 5% for concentrations higher than about 0.3 microg/g and about 10% for trace element abundances in the ng/g range. 相似文献
3.
Kevin Becker Sebastian Pfütze Dr. Eric Kuhnert Prof. Dr. Russell J. Cox Prof. Dr. Marc Stadler Dr. Frank Surup 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(4):1438-1450
The diversity of azaphilones in stromatal extracts of the fungus Hypoxylon fragiforme was investigated and linked to their biosynthetic machineries by using bioinformatics. Nineteen azaphilone-type compounds were isolated and characterized by NMR spectroscopy and mass spectrometry, and their absolute stereoconfigurations were assigned by using Mosher ester analysis and electronic circular dichroism spectroscopy. Four unprecedented bis-azaphilones, named hybridorubrins A–D, were elucidated, in addition to new fragirubrins F and G and various known mitorubrin derivatives. Only the hybridorubrins, which are composed of mitorubrin and fragirubrin moieties, exhibited strong inhibition of Staphylococcus aureus biofilm formation. Analysis of the genome of H. fragiforme revealed the presence of two separate biosynthetic gene clusters (BGCs) hfaza1 and hfaza2 responsible for azaphilone formation. While the hfaza1 BGC likely encodes the assembly of the backbone and addition of fatty acid moieties to yield the (R)-configured series of fragirubrins, the hfaza2 BGC contains the necessary genes to synthesise the widely distributed (S)-mitorubrins. This study is the first example of two distant cross-acting fungal BGCs collaborating to produce two families of azaphilones and bis-azaphilones derived therefrom. 相似文献
4.
Dr. Bidyut B. Sarma Jonglack Kim Jonas Amsler Dr. Giovanni Agostini Dr. Claudia Weidenthaler Norbert Pfänder Dr. Raul Arenal Dr. Patricia Concepción Dr. Philipp Plessow Prof. Dr. Felix Studt Dr. Gonzalo Prieto 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(14):5855-5864
Realizing the full potential of oxide-supported single-atom metal catalysts (SACs) is key to successfully bridge the gap between the fields of homogeneous and heterogeneous catalysis. Here we show that the one-pot combination of Ru1/CeO2 and Rh1/CeO2 SACs enables a highly selective olefin isomerization-hydrosilylation tandem process, hitherto restricted to molecular catalysts in solution. Individually, monoatomic Ru and Rh sites show a remarkable reaction specificity for olefin double-bond migration and anti-Markovnikov α-olefin hydrosilylation, respectively. First-principles DFT calculations ascribe such selectivity to differences in the binding strength of the olefin substrate to the monoatomic metal centers. The single-pot cooperation of the two SACs allows the production of terminal organosilane compounds with high regio-selectivity (>95 %) even from industrially-relevant complex mixtures of terminal and internal olefins, alongside a straightforward catalyst recycling and reuse. These results demonstrate the significance of oxide-supported single-atom metal catalysts in tandem catalytic reactions, which are central for the intensification of chemical processes. 相似文献
5.
Giovinazzo J Blank B Chartier M Czajkowski S Fleury A Lopez Jimenez MJ Pravikoff MS Thomas JC De Oliveira Santos F Lewitowicz M Maslov V Stanoiu M Grzywacz R Pfützner M Borcea C Brown BA 《Physical review letters》2002,89(10):102501
In an experiment at the SISSI-LISE3 facility of GANIL, the decay of the proton drip line nucleus 45Fe has been studied. Fragment-implantation events have been correlated with radioactive decay events in a 16x16 pixel silicon-strip detector. The decay-energy spectrum of 45Fe implants shows a distinct peak at (1.14+/-0.04) MeV with a half-life of T(1/2)=(4.7(+3.4)(-1.4)) ms. None of the events in this peak is in coincidence with beta particles. For a longer correlation interval, daughter decays of the two-proton daughter 43Cr can be observed after 45Fe implantation. The decay energy for 45Fe agrees nicely with several theoretical predictions for two-proton radioactivity. 相似文献
6.
M. Sawicka I. Matea H. Grawe R. Grzywacz M. Pfützner M. Lewitowicz J. M. Daugas B. A. Brown A. Lisetskiy F. Becker G. Bélier C. Bingham R. Borcea E. Bouchez A. Buta E. Dragulescu G. de France G. Georgiev J. Giovinazzo F. Hammache F. Ibrahim P. Mayet V. Méot F. Negoita F. De Oliveira-Santos O. Perru O. Roig K. Rykaczewski M. G. Saint-Laurent J. E. Sauvestre O. Sorlin M. Stanoiu I. Stefan C. Stodel Ch. Theisen D. Verney J. Żylicz 《The European Physical Journal A - Hadrons and Nuclei》2004,22(3):455-459
A decay spectroscopy study of the neutron-rich cobalt isotopes has been performed using fragmentation of a 86Kr36+ beam and the new LISE2000 spectrometer at GANIL. For 71Co and 73Co, the -delayed radiation has been observed for the first time, and the half-lives were found to be 79(5) ms and 41(4) ms, respectively. Features of the decay are discussed qualitatively in terms of nuclear models. 相似文献
7.
S. Pietri P. H. Rega Zs. Podolyák A. Jungclaus M. Pfützner D. Rudolph A. B. Garnsworthy S. J. Steer R. Hoischen M. Górska J. Gerl H. J. Wollersheim I. Kojouharov H. Schaffner J. Grębosz F. Becker P. Bednarczyk L. Caceres P. Doornenbal H. Geissel A. Kelic N. Kurz F. Montes W. Prokopowicz T. Saito S. Tashenov E. Werner-Malento W. Gelletly 《The European physical journal. Special topics》2007,150(1):319-320
The RISING (Rare ISotope INvestigations at GSI) project constitutes a major
pan-european initiative to study nuclear structure in exotic nuclei.
A brief outline of the technical details specific to studies of isomeric decays
following relativistic projectile fragmentation reactions is presented. 相似文献
8.
9.
10.
Frank?Pf?ffle Christoph?A.?StephanEmail author 《Communications in Mathematical Physics》2011,307(1):261-273
We investigate the Holst action for closed Riemannian 4-manifolds with orthogonal connections. For connections whose torsion
has zero Cartan type component we show that the Holst action can be recovered from the heat asymptotics for the natural Dirac
operator acting on left-handed spinor fields. 相似文献