排序方式: 共有57条查询结果,搜索用时 15 毫秒
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Pengbo Jiang Tiexin Cheng Yan Liu Xianghao Cui Yingli Bi Kaiji Zhen 《Reaction Kinetics and Catalysis Letters》2004,82(1):49-56
The novel phase transfer catalysts S-8 [4-(dimethyloctylammonium) propansultan] and DB-X [1,4-bis(triethylmethylammonium)benzene dibromide] were synthesized and employed for high conversion synthesis of dichlorocyclopropane from various olefins.This revised version was published online in December 2005 with corrections to the Cover Date. 相似文献
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以 YBCO(YBa2Cu3 O7 -δ ) 为代表的二代高温超导带材因具有高临界转变温度、 高临界磁场和强载流能力,受到了国际学界高度关注, 在各个领域具有广泛的应用前景. 二代高温超导带材在绕制、 冷却和运行过程中会受到不同来源的外力作用, 且超导带材的韧性、 延展性较差, 因此其机械性能是影响安全性与设备运行可靠性的关键.本文基于二代超导带材各向异性的特点, 对超导带材轴向、 横向、 弯曲三个方向的静态机械性能及疲劳性能进行了介绍. 同时, 也对超导带材各方向机械性能的测试方法、 影响因素及机理进行了总结 相似文献
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Pengbo Su Bin Han Zhongnan Zhao Qiancheng Zhang Tian Jian Lu 《Acta Mechanica Sinica》2018,34(4):667-675
A novel square honeycomb-cored sandwich beam with perforated bottom facesheet is investigated under threepoint bending,both analytically and numerically.Perforated square holes in the bottom facesheet are characterized by the area ratio of the hole to intact facesheet(perforation ratio).While for large-scale engineering applications like the decks of cargo vehicles and transportation ships,the perforations are needed to facilitate the fabrication process(e.g.,laser welding)as well as service maintenance,it is demonstrated that these perforations,when properly designed,can also enhance the resistance of the sandwich to bending.For illustration,fair comparisons among competing sandwich designs having different perforation ratios but equal mass is achieved by systematically thickening the core webs.Further,the perforated sandwich beam is designed with a relatively thick facesheet to avoid local indention failure so that it mainly fails in two competing modes:(1)bending failure,i.e.,yielding of beam cross-section and buckling of top facesheet caused by bending moment;(2)shear failure,i.e.,yielding and buckling of core webs due to shear forcing.The sensitivity of the failure loads to the ratio of core height to beam span is also discussed for varying perforation ratios.As the perfo-ration ratio is increased,the load of shear failure increases due to thickening core webs,while that of bending failure decreases due to the weakening bottom facesheet.Design of a sandwich beam with optimal perforation ratio is realized when the two failure loads are equal,leading to significantly enhanced failure load(up to 60%increase)relative to that of a non-perforated sandwich beam with equal mass. 相似文献
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Wei Liu Pengbo Zhai Shengjian Qin Jing Xiao Yi Wei Weiwei Yang Shiqiang Cui Qian Chen Chunqiao Jin Shubin Yang Yongji Gong 《Journal of Energy Chemistry》2021,(5):463-469
Li metal,possessing advantages of high theoretical specific capacity and low electrochemical potential,is regarded as the most promising anode material for next-generation batteries.However,despite decades of intensive research,its practical application is still hindered by safety hazard and low Coulombic efficiency,which is primarily caused by dendritic Li deposition.To address this issue,restraining dendrite growth at the nucleation stage is deemed as the most effective method.By utilizing the difference of electronegativity between boron atoms and carbon atoms,carbon atoms around boron atoms in boron-doped graphene(BG)turn into lithiophilic sites,which can enhance the adsorption capacity to Li+at the nucleation stage.Consequently,an ultralow overpotential of 10 mV at a current density of 0.5 mA/cm2 and a high average Coulombic efficiency of 98.54%over more than 140 cycles with an areal capacity of 2 mAh/cm2 at a current density of 1 m A/cm2 were achieved.BG-Li|LiFePO4 full cells delivered a long lifespan of480 cycles at 0.5 C and excellent rate capability.This work provides a novel method for rational design of dendrite-free Li metal batteries by regulating nucleation process. 相似文献
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FM信号受单音干扰时,有时无法获取干扰信号信息,但易获取输入信号和输出信号信息。提出将均方误差公式进行改进,并与干信比这一指标相关联,间接对FM信号进行单音干扰效果评估的方法。首先,建立了FM信号仿真模型,分析了不同信噪比下FM解调信号的波形失真情况;其次,分析了FM调制信号受到单音干扰时,在不同干信比下FM解调信号的波形失真情况;然后,用均方误差公式来表示模拟信号失真度,分析其与干信比的变化曲线,并对均方误差公式进行改进,仿真研究后得到新的评估指标;最后,分析了新评估指标与干信比和占空比的关系。 相似文献
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以过硫酸钾(KPS)为引发剂, 采用双丙酮丙烯酰胺(DAA)对海藻酸钠(SA)进行改性, 制备了海藻酸钠-聚双丙酮丙烯酰胺两亲性共聚物(SA-PDAA). 将SA-PDAA与聚乙烯醇(PVA)复配, 并进行静电纺丝, 制得SA-PDAA/PVA电纺纳米纤维. 通过红外光谱、 差示扫描量热和荧光光谱表征了SA-PDAA的结构和性能, 通过黏度仪、 表面张力仪和电导率仪测试了SA-PDAA纺丝液的物理性能, 用扫描电子显微镜表征了SA-PDAA/PVA电纺纳米纤维的形貌, 考察了SA-PDAA/PVA电纺纳米纤维的释药性能. 结果表明, DAA接枝到SA分子链上, SA-PDAA的临界聚集浓度为0.072 g/L, SA-PDAA具有良好的两亲性, SA-PDAA/PVA电纺纳米纤维具有均一的形貌. 改性后的SA可以有效地减缓药物释放速度, 提高SA-PDAA/PVA电纺纳米纤维的缓释性能. 相似文献
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Pengbo Li Yiru Wang Shufang Zhang Liang Xu Gongchen Wang Jingnan Cui 《Tetrahedron letters》2018,59(14):1390-1393
A fluorescent probe HCAB based on twisted intramolecular charge transfer (TICT) mechanism has been designed and synthesized by introducing benzoyl moiety to 4-dimethylamino-2′-hydroxychalcone. HCAB showed excellent selectivity towards human serum albumin (HSA) among different proteins with a remarkable 160-fold fluorescence enhancement and a wider linear range 0–100?mg/L of HSA. Job’s Plot analysis suggested that the formation of HCAB-HSA complex followed a 1:1 stoichiometry. Molecular docking and the displacement assay demonstrated the binding site of HCAB was subdomain IIA and IB of HSA. We also tested HSA levels in human plasma for practical application, the results obtained from HCAB method were similar to those obtained from the standard clinical method. 相似文献
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Pengbo Cui Linjie Zhao Dr. Yongde Long Prof. Liming Dai Prof. Chuangang Hu 《Angewandte Chemie (International ed. in English)》2023,62(14):e202218269
Oxygen reduction reaction (ORR) is vital for clean and renewable energy technologies, which require no fossil fuel but catalysts. Platinum (Pt) is the best-known catalyst for ORR. However, its high cost and scarcity have severely hindered renewable energy devices (e.g., fuel cells) for large-scale applications. Recent breakthroughs in carbon-based metal-free electrochemical catalysts (C-MFECs) show great potential for earth-abundant carbon materials as low-cost metal-free electrocatalysts towards ORR in acidic media. This article provides a focused, but critical review on C-MFECs for ORR in acidic media with an emphasis on advances in the structure design and synthesis, fundamental understanding of the structure-property relationship and electrocatalytic mechanisms, and their applications in proton exchange membrane fuel cells. Current challenges and future perspectives in this emerging field are also discussed. 相似文献