全文获取类型
收费全文 | 4407篇 |
免费 | 178篇 |
国内免费 | 35篇 |
专业分类
化学 | 2993篇 |
晶体学 | 18篇 |
力学 | 120篇 |
综合类 | 1篇 |
数学 | 781篇 |
物理学 | 707篇 |
出版年
2023年 | 31篇 |
2022年 | 134篇 |
2021年 | 137篇 |
2020年 | 110篇 |
2019年 | 96篇 |
2018年 | 111篇 |
2017年 | 85篇 |
2016年 | 174篇 |
2015年 | 147篇 |
2014年 | 182篇 |
2013年 | 278篇 |
2012年 | 325篇 |
2011年 | 354篇 |
2010年 | 243篇 |
2009年 | 228篇 |
2008年 | 323篇 |
2007年 | 283篇 |
2006年 | 267篇 |
2005年 | 188篇 |
2004年 | 166篇 |
2003年 | 135篇 |
2002年 | 122篇 |
2001年 | 58篇 |
2000年 | 36篇 |
1999年 | 51篇 |
1998年 | 33篇 |
1997年 | 23篇 |
1996年 | 34篇 |
1995年 | 32篇 |
1994年 | 23篇 |
1993年 | 25篇 |
1992年 | 18篇 |
1991年 | 10篇 |
1990年 | 19篇 |
1989年 | 11篇 |
1988年 | 12篇 |
1987年 | 6篇 |
1986年 | 11篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 9篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 7篇 |
1978年 | 6篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1974年 | 8篇 |
1970年 | 4篇 |
排序方式: 共有4620条查询结果,搜索用时 15 毫秒
1.
Cardin Pedro Toniol Teixeira Marco Antonio 《Journal of Dynamics and Differential Equations》2022,34(2):775-787
Journal of Dynamics and Differential Equations - In this paper we focus on a class of symmetric vector fields in the context of singularly perturbed fast-slow dynamical systems. Our main question... 相似文献
2.
Nonlinear Dynamics - Nonlinear flutter of variable stiffness composite plates—using a reduced-order model benefiting from a large-enough number of modes or degrees of freedom—is the... 相似文献
3.
4.
The influence of different referencing methods on the accuracy of δ13C value measurement of ethanol fuel by gas chromatography/combustion/isotope ratio mass spectrometry 下载免费PDF全文
5.
João Marcos G. Barbosa Milenna K. Fernandes Rodrigues Lurian C. David Taynara C. e Silva Danielly A. Fortuna Lima Naiara Z. Pereira Emmanuel B. D'Alessandro Anselmo E. de Oliveira Paulo H. Jorge da Cunha Maria Clorinda S. Fioravanti Nelson R. Antoniosi Filho 《Biomedical chromatography : BMC》2020,34(11):e4935
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication. 相似文献
6.
Probing the Catalytic Activity of Reduced Graphene Oxide Decorated with Au Nanoparticles Triggered by Visible Light 下载免费PDF全文
Dr. Jiale Wang Dr. Fabiane J. Trindade Caroline B. de Aquino Joana C. Pieretti Prof. Dr. Sergio H. Domingues Prof. Dr. Romulo A. Ando Prof. Dr. Pedro H. C. Camargo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(27):9889-9894
Hybrid materials in which reduced graphene oxide (rGO) is decorated with Au nanoparticles (rGO–Au NPs) were obtained by the in situ reduction of GO and AuCl4?(aq) by ascorbic acid. On laser excitation, rGO could be oxidized as a result of the surface plasmon resonance (SPR) excitation in the Au NPs, which generates activated O2 through the transfer of SPR‐excited hot electrons to O2 molecules adsorbed from air. The SPR‐mediated catalytic oxidation of p‐aminothiophenol (PATP) to p,p′‐dimercaptoazobenzene (DMAB) was then employed as a model reaction to probe the effect of rGO as a support for Au NPs on their SPR‐mediated catalytic activities. The increased conversion of PATP to DMAB relative to individual Au NPs indicated that charge‐transfer processes from rGO to Au took place and contributed to improved SPR‐mediated activity. Since the transfer of electrons from Au to adsorbed O2 molecules is the crucial step for PATP oxidation, in addition to the SPR‐excited hot electrons of Au NPs, the transfer of electrons from rGO to Au contributed to increasing the electron density of Au above the Fermi level and thus the Au‐to‐O2 charge‐transfer process. 相似文献
7.
Brandão Pedro Francisco Ramos Rui Miguel Rodrigues José António 《Analytical and bioanalytical chemistry》2018,410(26):6873-6880
Analytical and Bioanalytical Chemistry - Formaldehyde is often applied in the industrial production of different products, such as textiles, insulation materials, or cosmetics, due to its... 相似文献
8.
Lígia M. Rodrigues 《Tetrahedron》2004,60(40):8929-8936
Tetrapeptides containing one of a set of four different α,α-dialkyl glycines at the C-terminus were synthesized by conventional methods in solution and their conformational behavior investigated by 1H NMR spectroscopy in connection with molecular mechanics calculations. The results were consistent with conformations stabilized by a γ-turn in the case of compounds with alkyl groups larger than methyl, while the corresponding Aib derivative did not exhibit intramolecular hydrogen bonding. 相似文献
9.
José Francisco Rodrigues 《Monatshefte für Mathematik》2004,29(2):157-177
This paper presents further developments in the study of strong solutions and their coincidence sets to the obstacle problem for linear transport operators. Under natural mild assumptions, the strong convergence of the solutions and the characteristic functions of their coincidence sets is obtained in the passage of second order to first order problems. An application to a steady-state chemotaxis problem is given. The extension to the two obstacles problem of first order is also presented, having in view an application to a porous media model in presence of saturation arising in petroleum engineering. 相似文献
10.
A Geometric Characterization of Automatic Monoids 总被引:1,自引:0,他引:1