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1.
Spyridon Koutsoukos Frederik Philippi Francisco Malaret Tom Welton 《Chemical science》2021,12(20):6820
There are thousands of papers published every year investigating the properties and possible applications of ionic liquids. Industrial use of these exceptional fluids requires adequate understanding of their physical properties, in order to create the ionic liquid that will optimally suit the application. Computational property prediction arose from the urgent need to minimise the time and cost that would be required to experimentally test different combinations of ions. This review discusses the use of machine learning algorithms as property prediction tools for ionic liquids (either as standalone methods or in conjunction with molecular dynamics simulations), presents common problems of training datasets and proposes ways that could lead to more accurate and efficient models.In this review article, the authors discuss the use of machine learning algorithms as tools for the prediction of physical and chemical properties of ionic liquids. 相似文献
2.
Probing the Catalytic Activity of Reduced Graphene Oxide Decorated with Au Nanoparticles Triggered by Visible Light 下载免费PDF全文
Dr. Jiale Wang Dr. Fabiane J. Trindade Caroline B. de Aquino Joana C. Pieretti Prof. Dr. Sergio H. Domingues Prof. Dr. Romulo A. Ando Prof. Dr. Pedro H. C. Camargo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(27):9889-9894
Hybrid materials in which reduced graphene oxide (rGO) is decorated with Au nanoparticles (rGO–Au NPs) were obtained by the in situ reduction of GO and AuCl4?(aq) by ascorbic acid. On laser excitation, rGO could be oxidized as a result of the surface plasmon resonance (SPR) excitation in the Au NPs, which generates activated O2 through the transfer of SPR‐excited hot electrons to O2 molecules adsorbed from air. The SPR‐mediated catalytic oxidation of p‐aminothiophenol (PATP) to p,p′‐dimercaptoazobenzene (DMAB) was then employed as a model reaction to probe the effect of rGO as a support for Au NPs on their SPR‐mediated catalytic activities. The increased conversion of PATP to DMAB relative to individual Au NPs indicated that charge‐transfer processes from rGO to Au took place and contributed to improved SPR‐mediated activity. Since the transfer of electrons from Au to adsorbed O2 molecules is the crucial step for PATP oxidation, in addition to the SPR‐excited hot electrons of Au NPs, the transfer of electrons from rGO to Au contributed to increasing the electron density of Au above the Fermi level and thus the Au‐to‐O2 charge‐transfer process. 相似文献
3.
Brandão Pedro Francisco Ramos Rui Miguel Rodrigues José António 《Analytical and bioanalytical chemistry》2018,410(26):6873-6880
Analytical and Bioanalytical Chemistry - Formaldehyde is often applied in the industrial production of different products, such as textiles, insulation materials, or cosmetics, due to its... 相似文献
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A Geometric Characterization of Automatic Monoids 总被引:1,自引:0,他引:1
7.
In this paper, a generalized anti–maximum principle for the second order differential operator with potentials is proved. As an application, we will give a monotone iterative scheme for periodic solutions of nonlinear second order equations. Such a scheme involves the Lp norms of the growth, 1 ≤ p ≤ ∞, while the usual one is just the case p = ∞. 相似文献
8.
Generally, in homotopy theory a cylinder object (or, its dual, a path object) is used to define homotopy between morphisms,
and a cone object is used to build exact sequences of homotopy groups. Here, an axiomatic theory based on a cone functor is
given. Suspension objects are associated to based objects and cofibrations, obtaining homotopy groups referred to an object
and relative to a cofibration, respectively. Exact sequences of these groups are built. Algebraic and particular examples
are given. We point out that the main results of this paper were already stated in [3], and the purpose of this article is
to give full details of the foregoing. 相似文献
9.
The big trip is a cosmological process thought to occur in the future by which the entire universe would be engulfed inside a gigantic wormhole and might travel through it along space and time. In this Letter we discuss different arguments that have been raised against the viability of that process, reaching the conclusions that the process can actually occur by accretion of phantom energy onto the wormholes and that it is stable and might occur in the global context of a multiverse model. We finally argue that the big trip does not contradict any holographic bounds on entropy and information. 相似文献
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