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1.
2.
Mutual precipitates of poly (N, N-dimethyl acrylamide) and poly (4-hydroxystyrene) were collected from dioxane, methanol, or acetone. The glass transition (Tg) temperatures of the precipitates are higher than the weight-average values. Clear films cast from dimethylformamide solutions have lower Tg values. Complexation also occurred between poly (ethyl oxazoline) and poly (4-hydroxystyrene) in dioxane and between poly (vinyl pyrrolidone) and poly (4-hydroxystyrene) in methanol. Again, the glass transition temperatures of the precipitates are higher than the values for the blend films. The ΔCp values associated with the glass transitions of the complexes are smaller than those of the blends having the same compositions. Negative excess heat capacities of mixing have been observed for several precipitates. 相似文献
3.
A. Raith W. T. Perkins N. J. G. Pearce T. E. Jeffries 《Fresenius' Journal of Analytical Chemistry》1996,355(7-8):789-792
Laser ablation inductive coupled plasma – mass spectrometry (LA-ICP-MS) was used to analyse minor and trace elements in the hard parts of a shellfish, representing the environmental changes. A large, long-lived bivalve such as Arctica islandica can produce historical records of trace element fluctuations in seawater. Analytical traverses using LA-ICP-MS were performed from the inner to the outer wall of the shell at different locations. The development of the UV laser system now offers spatial resolution of craters of 10 m diameter, enabling several analyses between the various growthbands. The elemental changes between growthbands of the shell are discussed, showing the potential for precise determination of heavy-metal pollution over the years. 相似文献
4.
C. H. Do E. M. Pearce B. J. Bulkin H. K. Reimschuessel 《Journal of polymer science. Part A, Polymer chemistry》1987,25(9):2409-2424
The effects of heat and oxygen on nylon films were studied by FT–IR spectroscopy. Nylons 6, 66 and nylons containing carbonyl groups in either the diamine or the diacid moiety were prepared. Nylon films cast on aluminum were studied in an environmental chamber under controlled conditions. The progress of chemical and physical changes was monitored by FT–IR spectroscopy. Thermal energy caused largely an increase in crystallinity due to annealing and also an increase of nonhydrogen-bonded amide groups, which seemed to entail mainly amide groups from the amorphous region. The intensities of IR absorption bands related to the folded structure reduced as soon as heating began. The IR spectra of the carbonyl groups formed by thermal oxidation showed band shapes that indicated that the formed carbonyl groups were of many different origins. The presence of keto groups purposely inserted into the backbone chains increased the rate of oxidation. Pyrolysis of the nylons was also studied to supplement data obtained at lower temperatures. 相似文献
5.
In this paper we study queueing networks which allow multiple changes at a given time. The model has a natural application
to discrete-time queueing networks but describes also queueing networks in continuous time.
It is shown that product-form results which are known to hold when there are single changes at a given instant remain valid
when multiple changes are allowed. 相似文献
6.
The finite-size corrections, central chargesc, and scaling dimensionsx of tricritical hard squares and critical hard hexagons are calculated analytically. This is achieved by solving the special functional equation or inversion identity satisfied by the commuting row transfer matrices of these lattice models at criticality. The results are expressed in terms of Rogers dilogarithms. For tricritical hard squares we obtainc=7/10,x=3/40, 1/5, 7/8, 6/5 and for hard hexagons we obtainc=4/5,x=2/15, 4/5, 17/15, 4/3, 9/5, in accord with the predictions of conformal and modular invariance. 相似文献
7.
利用含时波包方法对D+HS交换和抽取通道进行量子动力学研究,动力学计算中所采用的势能面由高精度从头算能量点构建.在平动能0.0~2.0 eV区间内计算了反应物初始振转基态时的总反应几率和积分反应截面,并且计算了初始振动激发态对积分反应截面的影响.所有动力学计算均考虑了科里奥利耦合效应.在低平动能时抽取通道在反应中占主导地位,而交换通道在高平动能时占主导地位.在整个所研究的平能能区间内,反应物HS的振动激发对抽取和交换通道反应都有增强作用. 相似文献
8.
采用含时密度泛函(Time-dependent density functional theory)TDDFT/6-311++g(d,p)方法研究了一氧化硅分子能量最低的10个单重激发态的激发波长和跃迁振子强度等激发光谱参数.同时利用原子与分子物理相关理论分析了外电场对一氧化硅分子激发光谱的影响规律.得到的结论是,随外电场强度增强,一氧化硅分子激发态跃迁光谱向可见光区域发生红移.该结果为通过外电场调制材料发光特性提供了理论支持. 相似文献
9.
通过高温固相法合成了一系列Ba3La1-x(PO4)3∶xDy3+荧光粉材料。利用XRD测量样品的物相,结果显示样品为纯相Ba3La(PO4)3晶体。样品的激发光谱由一系列宽谱组成,峰值分别位于322,347,360,386,424,451 nm。在347 nm激发下,荧光粉在482 nm(4F9/2→6H15/2)和575 nm(4F9/2→6H13/2)处有很强的发射。研究了不同Dy3+掺杂浓度对样品发射光谱的影响,当Dy3+摩尔分数x=0.10时出现猝灭现象,浓度猝灭机理为电偶极-电偶极相互作用。确定了不同Dy3+掺杂浓度的Ba3La(PO4)3∶Dy3+的荧光寿命。Ba3La(PO4)3∶Dy3+荧光粉发射光谱的色坐标位于白光区域。 相似文献
10.
The HCl(v' = 0, J') rotational state distributions produced in the photoinitiated reactions of ground spin-orbit state Cl(2P3/2) atoms with the organic heterocycles oxirane (c-C2H4O), thiirane (c-C2H4S) and oxetane (c-C3H6O) have been measured using the technique of 2 + 1 resonance-enhanced multiphoton ionization in a time-of-flight mass spectrometer. In contrast to previous studies of H-atom abstraction dynamics by Cl atoms with linear functionalized molecules, the nascent HCl(v' = 0, J') products of the reactions of the three-membered heterocycles oxirane and thiirane are formed rotationally cold, with mean rotational energies <Erot> of (0.28 ± 0.02) kcal mol-1 and (0.31 ± 0.02) kcal mol-1, respectively. The reaction of Cl atoms with the four-membered heterocycle oxetane, however, results in more rotationally excited HCl(v' = 0, J') products for which <Erot> = (0.78 ± 0.03) kcal mol-1. Ab initio calculations were performed at the G2//MP2/6-311G(d,p) level to characterize molecular complexes and transition states on the reactive pathways. In all cases, the reactions were calculated to be barrierless, and weakly bound pre- and post-reaction complexes were located on the potential energy surfaces. The observed distributions and calculated reaction profiles are compared with previous studies of the reactions of Cl atoms with linear functionalized organic molecules and the consequences of the constrained molecular geometry on the HCl(v' = 0, J') rotational distribution discussed in terms of the dipole-dipole interaction model proposed previously. 相似文献