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Soliev S. B. Astakhov A. V. Pasyukov D. V. Chernyshev V. M. 《Russian Chemical Bulletin》2020,69(4):683-690
Russian Chemical Bulletin - Catalytic activity of nickel(ii) and palladium(ii) N-heterocyclic carbene (NHC) complexes derived from imidazole, benzimidazole, and 1,2,4-triazole was comparatively... 相似文献
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Pasyukov D. V. Chernenko A. Yu. Lavrentev I. V. Baydikova V. A. Minyaev M. E. Starovoytova O. A. Chernyshev V. M. 《Russian Chemical Bulletin》2022,71(5):993-1008
Russian Chemical Bulletin - The reaction of 1,4-disubstituted thiosemicarbazides with N,N-dimethylformamide dimethyl acetal afforded 1,4-disubstituted 1,2,4-triazolium-3-thiolates. Heating of the... 相似文献
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Dmitry V. Pasyukov Andrey Yu. Chernenko Konstantin E. Shepelenko Vadim V. Kutyrev Victor N. Khrustalev Victor M. Chernyshev 《Mendeleev Communications》2021,31(2):176-178
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A.?Yu.?ChernenkoEmail author A.?V.?Astakhov D.?V.?Pasyukov P.?V.?Dorovatovskii Ya.?V.?Zubavichus V.?N.?Khrustalev V.?M.?Chernyshev 《Russian Chemical Bulletin》2018,67(1):79-84
The palladium complexes of the Pd-PEPPSI type with N-heterocyclic carbenes of the 1,2,4-triazole series were synthesized in 76—99% yields by the reactions of PdCl2 with 1,4-di- alkyl-1,2,4-triazolium salts in pyridine in the presence of KBr or KI as sources of halide ions and tetrabutylammonium salts as phase-transfer catalysts. The obtained complexes can be used as efficient catalysts for the Suzuki—Miyaura cross-coupling and are not inferior to the commercially available Pd-PEPPSI catalysts in activity. 相似文献
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Shevchenko M. A. Tkachenko Y. N. Astakhov A. V. Khazipov O. V. Tyurin R. V. Pasyukov D. V. Tafeenko V. A. Kravchenko O. A. Chernyshev V. M. 《Russian Chemical Bulletin》2018,67(9):1684-1694
Representatives of the new heterocyclic system, pyrimido[5’,4’:3,4]pyrrolo[1,2-f]phenanthridine, were obtained via the intramolecular C–H-arylation of 6-aryl-5-(2-bromophenyl) pyrrolo[3,4-d]pyrimidine-2,4-diones catalyzed by palladium complexes with N-heterocyclic carbene ligands (Pd/NHC).
相似文献6.
A. Yu. Chernenko D. V. Pasyukov A. V. Astakhov V. A. Tafeenko V. M. Chernyshev 《Russian Chemical Bulletin》2018,67(7):1196-1201
The Pd-PEPPSI complexes widely used to catalyze numerous reactions eliminate the pyridine ligand on treatment with protic acids to give binuclear complexes [Pd(NHC)X2]2 with the Pd–X–Pd (X = Cl, Br, I) bridging bonds. The reaction proceeds with high yields (78–98%) and can be regarded as a preparative approach to binuclear complexes. A prolonged heat treatment of either Pd-PEPPSI complexes or binuclear [Pd(NHC)X2]2 complexes in the presence of strong protic acids results in the Pd–NHC bond cleavage to give azolium salts (proligands) and palladium salts. 相似文献
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