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1.
D. M. Bhardwaj D. C. Jain S. Dalela Ravi Kumar N. L. Saini K. B. Garg 《Physica B: Condensed Matter》2004,350(4):366-374
We have made the XAFS measurements at the Cr–K-edge on natural Indian ruby single crystals (corundum) and its two irradiated samples with fluence 1×1012 Ni6+ and 5×1012 Ni6+ ions/cm2. Irradiated samples show interesting changes in their physical appearance. XANES measurements show progressive decrease in Δoct value on increase of Ni fluence in irradiated samples. EXAFS measurements on these samples show decrease in Cr–O distance on increase of Ni fluence. Lowering of Δoct value is correlated with the increase of Cr–O distance. 相似文献
2.
Ajay K. Saini Clifford M. Carlin Howard H. Patterson 《Journal of polymer science. Part A, Polymer chemistry》1992,30(3):419-427
New model compounds for poly[N,N′-bis(phenoxyphenyl)pyromellitimide] have been synthesized in order to investigate the formation of imine bonds which are proposed to form during the curing process and lead to crosslinking in the bulk polymer. Raman studies show that terminal amines can react with imide carbonyls during curing to form C?N bonds. The Raman band due to C?N appears at 1656 cm?1 and the band due to C?O closest to the imine bond is observed at 1742 cm?1. These results are in agreement with previously published results on vapor deposited polyimide films. 相似文献
3.
J. S. Saini A. K. Singh V. K. Garg S. K. Jaireth K. Chandra 《Hyperfine Interactions》1987,35(1-4):907-911
Powdered samples of Indian Natural Wolframites, (FexMn1?x) WO4 with x=0.95 to 0.41, obtained from seven different locations of two quartz-wolframite deposits of Degana and Sirohi in Rajasthan, have been investigated by Mössbauer spectroscopy down to 20K and magnetic susceptibility down to 77K. The Mössbauer spectra from 300K to 30K clearly indicate multiple sites which is at variance with the reported work. Below 50K a weak magnetic interaction with Hint~45Koe is observed. The spectra above transition temperature are resolved in three doublets and explained on the basis of reported crystal structure. The values of isomer shift, quadrupole splitting and magnetic hyperfine field have been attributed to high spin ferrous ions with octahedral symmetry. Relatively small value of Q.S. (~1.5 mm/sec. at 300K) indicate a strong contribution of the lattice term to the electric field gradient. 相似文献
4.
A. K. Shukla S. Saini P. Kumar J. S. P. Rai A. K. Srivastava 《Journal of polymer science. Part A, Polymer chemistry》1989,27(3):807-815
Polymerization of vinyl acetate initiated by β-picolinium p-chlorophenacylide was carried out at 30, 35, and 40°C, using conventional dilatometric technique. The initiator and the monomer exponent values were 0.80 ± 0.15 and unity, respectively. The polymerization was inhibited in the presence of hydroquinone, but was favored by nonpolar solvent and polymerization temperature. The energy of activation was 90.3 KJ mol?1. An average value of k/kt for the present system was found to be 0.37 × 10?2. The results are explained in terms of a radical mode of polymerization with degradative initiator transfer; the principal mode of termination, however, was bimolecular. 相似文献
5.
T. C. Awes C. Barlag F. Berger M. A. Bloomer C. Blume D. Bock R. Bock E. -M. Bohne D. Bucher A. Claussen G. Clewing L. Dragon A. Eklund S. Garpman R. Glasow H. Gustafsson H. H. Gutbrod G. Hölker J. Idh P. Jacobs K. H. Kampert B. W. Kolb H. Löhner I. Lund F. E. Obenshain A. Oskarsson I. Otterlund T. Peitzmann F. Plasil A. M. Poskanzer M. Purschke B. Roters S. Saini R. Santo H. R. Schmidt S. P. Sørensen K. Steffens P. Steinhaeuser E. Stenlund D. Stüken G. R. Young 《Zeitschrift fur Physik C Particles and Fields》1995,65(2):207-213
Correlations between protons are studied in the target fragmentation region of reactions of protons and16O with C, Cu, Ag, Au and of32S with Al and Au at 200A GeV. The emitted protons were measured with the Plastic Ball detector in the WA80 experiment at the CERN SPS. The comparison of the correlation function with calculations, assuming a spherical, gaussian shaped source with a lifetime τ=0 fm/c, allows the extraction of radius parameters. The values are very close to those expected from the geometry of the target nuclei and increase with the target mass as αA Target 1/3 . Even in proton induced reactions the whole target nucleus is involved. The dependence of the radii on centrality, polar angleθ lab, and energy, and their relation to measured proton yields are presented. 相似文献
6.
Billups WE Saini RK Litosh VA Alemany LB Wilson WK Wiberg KB 《The Journal of organic chemistry》2002,67(13):4436-4440
Thermolysis of spiro[2.4]hepta-1,4,6-triene (1a) at 50 degrees C yielded bicyclo[3.2.0]hepta-1,3,6-triene (5), which dimerized in two different fashions to form cyclobutanes. The 1,2-dimethyl and 1-propyl derivatives of 1a also rearranged at 50 degrees C, but at a faster rate, each yielding a pair of cyclobutane dimers. The structures of these symmetrical dimers were investigated by 1D and 2D NMR and NOE difference spectroscopy. Ab initio calculations indicated that the two strained olefins 1a and 5 had comparable energies about 50 kcal/mol lower than norborna-1(7),2,5-triene, which was thus excluded as a reaction intermediate. 相似文献
7.
The formation and composition of highly fluorescent zinc phosphates in the presence of traces of uranium were investigated and a direct fluorimetric determination of uranium in aqueous media was developed, based on the formation of finely dispersed and stabilized fluorescent precipitates. The standard deviation for 20 μg of uranium, in 25 ml is 5% ; with the fluorimeter described, 10-2 μg of uranium per ml can be determined with an error of 50%. The method is very selective and can be employed for analysis of uranium in ores; it is less sensitive than conventional fluorimetry of fused alkali fluorides but is much simpler and faster. Interferences can often be eliminated by suitable masking reactions. 相似文献
8.
Summary Gradient elution RP-HPLC has been applied to the separation of the constituents of synthetic tanning agents. Information obtained from the chromatographic results was used to assess the possibility of optimizing the conditions of synthesis, to find out the number of species formed and to make a start at correlating the composition of the tanning agents and their properties. 相似文献
9.
Dž. Belkić S. Saini H. S. Taylor 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1986,3(1):59-67
Whenever a collision takes place between charged particles, the first Born approximation for electron capture from hydrogenlike ions (Z T ,e) by a bare nucleusZ P , must be modified in order to account for the long-range Coulomb effects. One of the simplest ways to fulfill this requirement is provided by theT-matrix of the following form: $$T_{if}^{(1)} = \left\langle {\Phi _f exp\left\{ { - i\frac{{Z_T (Z_p - 1)}}{\upsilon } ln (\upsilon R + v \cdot R)} \right\}\left| {\frac{{Z_P }}{R} - \frac{{Z_P }}{{r_P }}} \right| exp\left\{ {i\frac{{Z_P (Z_T - 1)}}{\upsilon } ln (\upsilon R + v \cdot R)} \right\}\Phi _i } \right\rangle $$ where Φ's are the usual unperturbed channel states andZ's are the nuclear charges. In this transition amplitude, both initial and final scattering states satisfy the correct asymptotic boundary conditions in their respective channels. In the present paper, detailed computation of theK-shell cross sections is carried out for charge exchange in H+-H and H+-Ar collisions. The results are in good agreement with experimental data. 相似文献
10.
In flash photolysis of an oxygenated aqueous potassium persulphate solution at pH 12.5 the decay of the ozonide radical has been found to follow order kinetics which has been explained by reactions O?3 + O? ? 2 O?2 and O?3 + HO2 → 2 O2 + OH? 相似文献