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1.
I. Hadzistelios C. Papadopoulou 《Journal of Radioanalytical and Nuclear Chemistry》1977,36(2):427-434
A simple neutron activation method has been developed for the determination of europium in biological tissues and applied
in the analysis of marine organism samples with ±9% precision at the nanogram level. The method is based on the separation,
by ion-exchange, of the rare earth group from dry or ashed irradiated tissues and subsequent determination of152mEu, by γ-spectrometry using a lithium drifted germanium detector.152mEu, separated almost completely from other than rare earth elements, with better than 98% chemical yield, is counted on the
121.8 keV photopeak which then is practically free from any other γ-ray energy interfering in this counting. 相似文献
2.
DNA sequences attached to Au nanoparticles via thiol linkers stand up from the surface, giving preferential enhancement of the adenine ring breathing SERS band. Non-specific binding via the nucleobases reorients the DNA, reducing this effect. This change in intensity on reorientation was utilised for label-free detection of hybridization of a molecular beacon. 相似文献
3.
T. Kouris C. Papadopoulou G. D. Kanias E. Bairaktari-Kouri G. Theodossiadis 《Journal of Radioanalytical and Nuclear Chemistry》1989,130(1):121-128
Cataract is a very common disease of the eye lens known since ancient times. Different mechanisms are responsible for the biogenesis of cataract but most scientists agree with the theory that cataract formation can be attributed to metabolism disorders in the lens. Instrumental neutron activation analysis has been applied in this work for the determination of the following trace elements: antimony, cobalt, iron, rubidium, selenium and zinc in human lenses with mature cataract. The results are statistically treated and correlated with age and sex of patients. Based on these findings, the concentration of elements studied does not have any correlation with the age and/or sex of the patients, i.e. when the lens becomes totally opaque. 相似文献
4.
E. Kontonasaki T. Zorba L. Papadopoulou E. Pavlidou X. Chatzistavrou K. Paraskevopoulos P. Koidis 《Crystal Research and Technology》2002,37(11):1165-1171
The mechanism of bonding of bioactive glasses with living tissues has been reported to be associated with the development of a layer consisting of carbonate‐containing hydroxyapatite similar to that of bone on the surface of the materials. This layer is also formed in vitro, in solutions with ion concentrations similar to those of human blood plasma, like SBF (Simulated Body Fluid). The development of HCAp (Hydroxy carbonate apatite) layer on the surface of a commercially available Bioglass® Synthetic Bone Graft Particulate (Perioglas®) after immersion in SBF solution using Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) with associated Energy Dispersive Spectroscopy (EDS). PerioGlas® powder with particle size 20‐63μm, pressed in a vacuum press in order to produce pellets. The pellets were soaked in SBF for 12, 18, 24 and 48 hours at 37°C. Results revealed the formation of an amorphous CaO‐P2O5‐ rich layer on the surface of the specimens after 12 hours in the solution and a well crystalline HCAp layer after 24 hours immersion time. 相似文献
5.
Stella K. Papadopoulou Ioannis Karapanagiotis Ioannis Zuburtikudis Costas Panayiotou 《Journal of Polymer Science.Polymer Physics》2010,48(16):1826-1833
The thermodynamic characterization of a fluorinated methacrylic homopolymer was conducted by means of inverse gas chromatography (IGC), at infinite dilution. The homopolymer under study, poly(2,2,3,3,3‐pentafluoropropyl methacrylate) (PPFPMA), was synthesized via a free radical polymerization reaction and was characterized by the employment of Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and size exclusion chromatography (SEC) techniques. The specific retention volume of 15 solvents, used as probes, was used for the assessment of the Flory–Huggins interaction parameter, the weight fraction activity coefficient, the molar heat, energy and entropy of sorption, the partial heat of mixing of the probes, as well as the solubility parameter of the polymer. The results demonstrate that PPFPMA is insoluble in most organic solvents even at increased temperatures, with the exception of solvents like 2‐Butanone. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1826–1833, 2010 相似文献
6.
Virginie Papadopoulou Meng-Xing Tang Costantino Balestra Robert J. Eckersley Thodoris D. Karapantsios 《Advances in colloid and interface science》2014
Bubbles can form in the body during or after decompression from pressure exposures such as those undergone by scuba divers, astronauts, caisson and tunnel workers. Bubble growth and detachment physics then becomes significant in predicting and controlling the probability of these bubbles causing mechanical problems by blocking vessels, displacing tissues, or inducing an inflammatory cascade if they persist for too long in the body before being dissolved. By contrast to decompression induced bubbles whose site of initial formation and exact composition are debated, there are other instances of bubbles in the bloodstream which are well-defined. Gas emboli unwillingly introduced during surgical procedures and ultrasound microbubbles injected for use as contrast or drug delivery agents are therefore also discussed. After presenting the different ways that bubbles can end up in the human bloodstream, the general mathematical formalism related to the physics of bubble growth and detachment from decompression is reviewed. Bubble behavior in the bloodstream is then discussed, including bubble dissolution in blood, bubble rheology and biological interactions for the different cases of bubble and blood composition considered. 相似文献
7.
Stella K. Papadopoulou Ioannis Karapanagiotis Costas Panayiotou 《European Polymer Journal》2010,46(2):202-78
A fluorinated methacrylic homopolymer, poly(2,2,3,3,3-pentafluoropropyl methacrylate) (PPFPMA) was synthesized by a free radical polymerization reaction. The dispersive component of the surface energy () of PPFPMA was determined by contact angle measurements and inverse gas chromatography (IGC). An extensive surface characterization was conducted by means of IGC. Surface characterization demonstrated that PPFPMA has low value, even at 35 °C and is a Lewis amphoteric polymer with predominantly basic character, as confirmed by the Lewis acidity and basicity constants KA and KB, respectively. The values of obtained by IGC are slightly higher than those obtained by the contact angle method. This trend can be attributed to the fact that IGC evaluates, primarily, high energy sites of a surface. 相似文献
8.
Alexandros Katranidis Diaa Atta Ramona Schlesinger Knud H. Nierhaus Theodora Choli‐Papadopoulou Ingo Gregor Michael Gerrits Georg Büldt Jörg Fitter 《Angewandte Chemie (International ed. in English)》2009,48(10):1758-1761
It's not easy being green : Real‐time visualization of labeled ribosomes and de novo synthesized green fluorescent protein molecules using single‐molecule‐sensitive fluorescence microscopy demonstrates that the mutant GFPem is produced with a characteristic time of five minutes. Fluorescence of the fastest GFP molecules appears within one minute (see picture).
9.
Papadopoulou DN Zachariadis GA Anthemidis AN Tsirliganis NC Stratis JA 《Talanta》2006,68(5):1692-1699
Non-destructive analysis of cultural objects by micro-XRF spectrometry is an advantageous multi-element technique that has rapidly developed during the past few years. Portable instruments contribute significantly to the in situ analysis of valuable cultural objects, which cannot be transported to the laboratory. Ancient ceramics are the most common archaeological findings and they carry a significant historical content. Their analysis often presents certain particularities due to surface irregularities and heterogeneity problems. In the present work, the analytical characteristics (beam spot size, geometry effect and detection limits) of a compact and portable micro-XRF instrument with a monocapillary lens are presented in details. The standard reference materials SARM 69, SRM 620, NCS DC 73332 and the reference materials AWI-1 and PRI-1 were analysed for the determination of the detection limits (DL's) and the evaluation of the accuracy of the micro-XRF. Emphasis is given on the critical parameters, which should be monitored during measurements and influence the final results in the analysis of ancient ceramics. A quantitative analysis of ancient ceramic samples from Abdera (North Greece) is also presented. 相似文献
10.
Inductively coupled plasma atomic emission spectrometry (ICP-AES) is a powerful, sensitive analytical technique with numerous applications in chemical characterization including that of ancient pottery, mainly due to its multi-element character, and the relatively short time required for the analysis. A critical step in characterization studies of ancient pottery is the selection of a suitable decomposition procedure for the ceramic matrix. The current work presents the results of a comparative study of six decomposition procedures applied on a standard ceramic potsherd reference material, SARM 69. The investigated decomposition procedures included three microwave-assisted decomposition procedures, one wet decomposition (WD) procedure by conventional heating, one combined microwave-assisted and conventional heating WD procedure, and one fusion procedure. Chemical analysis was carried out by ICP-AES. Five major (Si, Al, Fe, Ca, Mg), three minor (Mn, Ba, Ti) and two trace (Cu, Co) elements were determined and compared with their certified values. Quantitation was performed at two different spectral lines for each element and multi-element matrix-matched calibration standards were used. The recovery values for the six decomposition procedures ranged between 75 and 110% with a few notable exceptions. Data were processed statistically in order to evaluate the investigated decomposition procedures in terms of recovery, accuracy and precision, and eventually select the most appropriate one for ancient pottery analysis. 相似文献