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1.
The Constraint Molecular Dynamics approach is illustrated together with calculation on different heavy ion collisions. In particular the charge-mass distribution produced in the collision 124Sn + 64Ni and 112Sn + 58Ni at 35 MeV/nucleon is discussed. By comparing the Y = (N ? Z)/A distributions for fragments produced in central collisions it results that this observable can be sensitive to the dynamic effects induced on the two systems by the different charge/mass ratio. 相似文献
2.
The composting of organic solid waste, the mixture of fruit and vegetable leftovers enriched with night soil, was investigated
in a closed thermally insulated reactor. It was found that 80.9 % of the original substrate biodegraded after 14 days. A mathematical
model of the column reactor was proposed where the biodegradation rate of the organic solid waste was described using simple
n-thorder kinetics. A good prediction of process performance was obtained using the proposed kinetics and experimentally obtained
reaction heat.
Presented at the 33rd International Conference of the Slovak Society of Chemical Engineering, Tatranské Matliare, 22–26 May
2006. 相似文献
3.
An antiviral nucleoside or virazole was synthesized efficiently and regioselectively starting with benzyl cyanoformate. 相似文献
4.
5.
A new method for silylation of allyl ethers with chlorosilanes has been developed by the use of Cp2TiCl2 as a catalyst. This reaction proceeds efficiently at −20 °C in THF using nBuMgCl. A plausible reaction pathway via allyltitanocene intermediate was proposed. 相似文献
6.
Tomoko Nii Akira Takamura Kiminori Mohri Fumiyoshi Ishii 《Colloids and surfaces. B, Biointerfaces》2003,27(4):436-332
We examined hydrogenated purified egg yolk lecithins, having practical advantages over non-hydrogenated ones, as liposomal membrane materials. Liposomes were prepared by the microencapsulation vesicle (MCV) method in which liposomes are formed through two-step emulsification and dispersion. Three types of purified egg yolk lecithins with different iodine values were examined after being dissolved in one of three lipid solvents. The liposome size increased as the temperature during the second emulsification increased, being closer to the boiling temperature of the solvent. The preparation temperature in relation to the transition temperature of each lecithin was also a factor affecting liposome sizes. As for the encapsulation efficiencies of the model compound calcein in liposomes, they differed mainly depending on the solubility of each lecithin in a lipid solvent and it was more obvious in hydrogenated lecithins. A high preparation temperature resulted in lower encapsulation efficiencies, suggesting that leakage of encapsulated calcein was facilitated at high temperature in the MCV methods. There was a significant correlation between liposome sizes and encapsulation efficiencies in non-hydrogenated purified egg yolk lecithin but not in hydrogenated ones. When using hydrogenated purified egg yolk lecithins as liposomal membrane materials, it was suggested that a lipid solvent should be chosen so that a lecithin completely dissolves under the preparation condition in order to achieve a higher encapsulation efficiency. Smaller liposome particles were obtained when the second emulsification was performed at a lower temperature compared with the boiling point of the lipid solvent. These findings can be applied to control encapsulation efficiencies and particle sizes in each particular liposome preparation enclosing therapeutic agents. 相似文献
7.
The preparation of CuI + Ag2S and Cu2[HgI4] + Ag2S membranes hydrophobised by PTFE is described. The pressed membranes mounted in a multi-purpose all-solid-state electrode body have been examined as electrochemical sensors for Cu2+ and I– ions. For the electrode with (CuI + Ag2S + PTFE)-membrane experimental slopes of 29 mV(pCu)–1 and 62 mV(pI)–1 were obtained, in good agreement with the theoretical values. For practical measurement in solutions where both Cu2+ and I– can be present, the investigated electrode offers certain advantages in comparison with a commercial Cu-ISE. 相似文献
8.
Baltrusaitis RM Becker JJ Blaylock GT Brown JS Bunnell KO Burnett TH Cassell RE Coffman D Cook V Coward DH Cui H Del Papa C Dorfan DE Duncan AL Einsweiler KF Eisenstein BI Fabrizio R Gladding G Grancagnolo F Hamilton RP Hauser J Heusch CA Hitlin DG Köpke L Mockett PM Moss L Mozley RF Nappi A Odian A Partridge R Perrier J Plaetzer SA Richman JD Roehrig JR Russell JJ Sadrozinski HF Scarlatella M Schalk TL Schindler RH Seiden A Sleeman JC Spadafora AL Thaler JJ Toki W Unno Y Villa F Wattenberg A 《Physical review letters》1985,55(17):1723-1726
9.
D. Berger C. Matei F. Papa G. Voicu V. Fruth 《Progress in Solid State Chemistry》2007,35(2-4):183-191
We report the synthesis of La1−xSrxCoO3 nanopowders by solution combustion method using metal nitrates and -alanine (alanine method) or urea (urea method) as fuel. The influence of metal nitrates/organic substance molar ratio and the type of fuel was investigated. The isolated complex precursors were characterized by atomic absorption spectroscopy (AAS), FT-IR spectra and DTA–TG analysis. The La1−xSrxCoO3 (x = 0–0.3) powders were characterized by X-ray diffraction (XRD), scanning electron microscopy–energy-dispersive X-ray analysis (SEM–EDX), as well as by specific surface area measurements. XRD patterns indicate the formation of single-phase LaCoO3 (rhombohedral) when as-synthesized powders were calcined at 873 K, 3 h in the case of the alanine method and at 1073 K, 3 h for urea-based system. Also, strontium doped lanthanum cobaltites obtained by both methods at 1273 K are single phase with rhombohedral perovskite-like structure as XRD data have proved. SEM investigation of pure and doped lanthanum cobaltites reveal that the samples prepared by both methods have fine particles with tendency of agglomerates formation with different shapes, spongy aspect and high porosity. La1−xSrxCoO3 nanopowders obtained by alanine method have larger specific surface area values than those prepared by urea method. 相似文献
10.
The preparation of CuI + Ag2S and Cu2[HgI4] + Ag2S membranes hydrophobised by PTFE is described. The pressed membranes mounted in a multi-purpose “all-solid-state” electrode body have been examined as electrochemical sensors for Cu2+ and I? ions. For the electrode with (CuI + Ag2S + PTFE)-membrane experimental slopes of 29 mV(pCu)?1 and 62 mV(pI)?1 were obtained, in good agreement with the theoretical values. For practical measurement in solutions where both Cu2+ and I? can be present, the investigated electrode offers certain advantages in comparison with a commercial Cu-ISE. 相似文献