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1.
S. P. Mukherjee A. K. Chattopadhyay 《The Journal of the Operational Research Society》1989,40(5):489-494
Consider an organization with several categories of staff, each having a specified number of members. The age of entry into service and the age of retirement are both specified. Withdrawals occur at time-independent rates. Under this set-up, the authors have computed the maximum ages at which promotions should take place, assuming that the staff members continuing at various ages are random. Some illustrative calculations have been carried out. 相似文献
2.
N. Ponpandian A. Narayanasamy D. Prabhu K. Ganesan M. Manivel Raja K. Chattopadhyay 《Journal of magnetism and magnetic materials》2006
The Fe73.5Cu1Nb3Si13.5B9 FINEMET alloy has been prepared by the rapid solidification technique. The critical behaviour of this alloy in the amorphous as well as in its nanocrystalline states has been studied near their respective Curie temperatures. From the values of the critical exponents one can conclude that the alloy behaves like a 3D Heisenberg ferromagnet in the amorphous and nanocrystalline states. But there exists a slight increase in the value of β for the alloy annealed at 823 K (the nanocrystalline state) as observed in most of the amorphous alloys. 相似文献
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A convenient and enantioselective synthesis of ethyl (8RS, 15R)-8-acetoxy-15-hydroxyhexadecanoate15 via a chemoenzymatic approach has been described. The salient features of the synthesis were operational simplicity, use of easily accessible materials, and excellent enantiocontrol via lipase catalyzed acetylation of 2-alkanol. 相似文献
5.
J. Mohanty H. Pal S. K. Nayak S. Chattopadhyay A. V. Sapre 《Chemical physics letters》2003,370(5-6):641-646
Fluorescence quenching of methoxycalixarenes (MOCX) by chloroalkanes (CA) has been investigated in acetonitrile solutions. Observed quenching is attributed to photoinduced dissociative electron transfer (DET) interaction, which is supported by the characterization of the Cl− ions and by the radical scavenging experiments. Comparing the Cl− yields with different DET systems, it is inferred that both concerted and stepwise DET mechanisms operate simultaneously in MOCX–CA systems. A correlation of the quenching constants with the free-energy changes following a suitable DET theory supports the above inference. 相似文献
6.
J.M. Chatterjee S. Basu-Roy S.S. Ghugre S. Chattopadhyay R.P. Singh G.O. Rodrigues R.K. Chattopadhyay R.K. Bhowmik 《The European Physical Journal A - Hadrons and Nuclei》1998,1(1):55-59
A search for new isomers of nanosecond lifetimes were carried out in 153Eu via the 150Nd(7Li,xnγ) reaction. The single particle angular momentum alignment and dynamical moment of inertia estimated from the experimental
data indicate a configuration change at rotational energy ħω∼ 0.30 MeV. A decrease of B(E2) values is also observed at the
same frequency. An isomeric level is identified at an excitation energy of 3100 keV (Jπ=35/2−) which corresponds to this frequency. The lifetime of the level is found to be 8.6 ± 1.3 nanosecond.
Received: 22 April 1997 / Revised version: 26 September 1997 相似文献
7.
Photocatalytic polypyrrole-TiO2-nanoparticles composite thin film generated at the air-water interface 总被引:1,自引:0,他引:1
Chowdhury D Paul A Chattopadhyay A 《Langmuir : the ACS journal of surfaces and colloids》2005,21(9):4123-4128
Herein, we report a new method of generation of TiO(2) nanoparticles (NPs) incorporated thin films of polypyrrole (PPy) at the air-water interface. Aqueous TiO(2) NPs when treated with H(2)O(2) and left in a chamber of pyrrole vapor resulted in the formation of a film at the interface, in addition to bulk precipitate. Spectroscopic, X-ray diffraction, and electron microscopic measurements establish the formation of a thin film of PPy with the incorporation of TiO(2) NPs. The TiO(2)-containing PPy films when transferred onto glass substrates were able to photo catalyze the decomposition of aqueous organic dyes: methyl orange and methylene blue. Further, these films could also photo catalyze the oxidation of iodide to triiodide ions in aqueous potassium iodide solution. We find that the PPy-TiO(2) composite films catalyze the reactions in the presence of light more efficiently than a suspension of TiO(2) NPs. 相似文献
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Dhar S Senapati D Das PK Chattopadhyay P Nethaji M Chakravarty AR 《Journal of the American Chemical Society》2003,125(40):12118-12124
A new class of ternary copper(II) complexes of formulation [Cu(L(n)B](ClO(4)) (1-4), where HL(n) is a NSO-donor Schiff base (HL(1), HL(2)) and B is a NN-donor heterocyclic base viz. 1,10-phenanthroline (phen) and 2,9-dimethyl-1,10-phenanthroline (dmp), are prepared, structurally characterized, and their DNA binding and photocleavage activities studied in the presence of red light. Ternary complex [Cu(L(3))(phen)](ClO(4)) (5) containing an ONO-donor Schiff base and a binary complex [Cu(L(2))(2)] (6) are also prepared and structurally characterized for mechanistic investigations of the DNA cleavage reactions. While 1-4 have a square pyramidal (4 + 1) CuN(3)OS coordination geometry with the Schiff base bonded at the equatorial sites, 5 has a square pyramidal (4 + 1) geometry with CuN(3)O(2) coordination with the alcoholic oxygen at the axial site, and 6 has a square planar trans-CuN(2)O(2) geometry. Binding of the complexes 1-4 to calf thymus DNA shows the relative order: phen > dmp. Mechanistic investigations using distamycin reveal minor groove binding for the complexes. The phen complexes containing the Schiff base with a thiomethyl or thiophenyl moiety show red light induced photocleavage. The dmp complexes are essentially photonuclease inactive. Complexes 5 and 6 are cleavage inactive under similar photolytic conditions. A 10 microM solution of 1 displays a 72% cleavage of SC DNA (0.5 microg) on an exposure of 30 min using a 603 nm Nd:YAG pulsed laser (60 mJ/P) in Tris-HCl buffer (pH 7.2). Significant cleavage of 1 is also observed at 694 nm using a Ruby laser. Complex 1 is cleavage inactive under argon or nitrogen atmosphere. It shows a more enhanced cleavage in pure oxygen than in air. Enhancement of cleavage in D(2)O and inhibition with sodium azide addition indicate the possibility of the formation of singlet oxygen as a reactive intermediate leading to DNA cleavage. The d-d band excitation with red light shows significant enhancement of cleavage yield. The results indicate that the phen ligand is necessary for DNA binding of the complex. Both the sulfur-to-copper charge transfer band and copper d-d band excitations helped the DNA cleavage. While the absorption of a red photon induces a metal d-d transition, excitation at shorter visible wavelengths leads to the sulfur-to-copper charge transfer band excitation at the initial step of photocleavage. The excitation energy is subsequently transferred to ground state oxygen molecules to produce singlet oxygen that cleaves the DNA. 相似文献