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1.
Godfrey Gumbs 《Solid State Communications》2003,128(12):443-448
A model calculation is reported for the tunneling probability of one as well as two interacting electrons from a quantum well within a narrow channel. We discuss the cases when the two electrons are spin polarized or unpolarized by transforming the system to a noninteracting one with the use of quantal density functional theory to obtain an effective single-particle confining potential. A semiclassical approach is used to obtain the tunneling probability from this effective potential. The calculation is motivated by recent measurements of the conductance of an electron gas in a narrow channel but is not meant to explain the anomalous behavior that has been reported since, for example, we deal with a simplified two-level system. Numerical results for the tunneling probability are presented. 相似文献
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Kayser V Turton DA Aggeli A Beevers A Reid GD Beddard GS 《Journal of the American Chemical Society》2004,126(1):336-343
Energy migration between tryptophan residues has been experimentally demonstrated in self-assembled peptide tapes. Each peptide contains 11 amino acids with a Trp at position 6. The peptide self-assembly is pH-sensitive and forms amphiphilic tapes, which further stack in ribbons (double tapes) and fibrils in water depending on the concentration. Fluorescence spectra, quenching, and anisotropy experiments showed that when the pH is lowered from 9 to 2, the peptide self-assembly buries the tryptophan in a hydrophobic and restricted environment in the interior of stable ribbons as expected on the basis of the peptide design. These fluorescence data support directly and for the first time the presence of such ribbons which are characterized by a highly packed and stable hydrophobic interior. In common with Trp in many proteins, fluorescence lifetimes are nonexponential, but the average lifetime is shorter at low pH, possibly due to quenching with neighboring Phe residues. Unexpectedly, time-resolved fluorescence anisotropy does not change significantly with self-assembly when in water. In highly viscous sucrose-water mixtures, the anisotropy decay at low pH was largely unchanged compared to that in water, whereas at high pH, the anisotropy decay increased significantly. We concluded that depolarization at low pH was not due to rotational diffusion but mainly due to energy migration between adjacent tryptophan residues. This was supported by a master equation kinetic model of Trp-Trp energy migration, which showed that the simulated and experimental results are in good agreement, although on average only three Trp residues were visited before emission. 相似文献
4.
A detailed study of the Raman and infrared spectral line shapes and line parameters of aqueous solutions (both H2O and D2O) of AgNO3 is interpreted in terms of an equilibrium between “free” ions and the ion pair Ag+NO 3 ? . An association constant of 0.1M ?1 was obtained from both the 717 cm?1 and 1047 cm?1 line intensities. Spectral features suggest a significant degree of covalence in the interaction. A Cs(σV) model with Ag+ above the plane of NO 3 ? is consistent with the data. 相似文献
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The dipole strengths of the 4A2 → 4T1(F), 4T1(P), d-electron transitions of the cobalt(II) tetrahalides are found to decrease with an increase in temperature, in agreement with a dynamic ligand-polarisation model for the absorption mechanism. The reduction in dipole strength is accounted for by a decrease in the coulombic coupling between the quadrupole moment of the d-electron transition of the metal ion and the transient electric dipole moment induced in the ligands, due to the anharmonic increase in the mean bond length and the progressively larger mean-square amplitudes of the bending modes of the complex ion in its ground electronic state as the temperature is raised. 相似文献
7.
Milanesi L Reid GD Beddard GS Hunter CA Waltho JP 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(7):1705-1710
A new series of photocleavable protein cross-linking reagents based on bis(maleimide) derivatives of diaryl disulfides have been synthesised. They have been functionalised with cysteine and transient absorption spectra for the photolysis reaction have been recorded by using the pump-probe technique with a time resolution of 100 femtoseconds. Photolysis of the disulfide bond yields the corresponding thiyl radicals in less than a picosecond. There is a significant amount of geminate recombination, but some of the radicals escape the solvent cage and the quantum yield for photocleavage is 30 % in water. 相似文献
8.
The axial single-crystal magnetic circular dichroism spectra of Cs3ZnCl5/Co2+ and Cs3ZnBr5/Co2+ have been measured over the 4000–7000 cm?1 region of the 4A2 → 4T1 (F) transition at ambient and liquid-helium temperature. The B/D and C/D terms obtained give transition moment ratios, 〈t2∥m∥t2〉/〈e∥m∥t2〉, in accord with the value required (?3/2) by a dynamic ligand-polarisation model for d-electron transition probabilities in tetrahedral metal complexes. 相似文献
9.
Sarmiento M Mooney P Bishop JM Biswas N Cason NM Dauwe L Godfrey J Kenney VP Pemper R Rojek E Ruchti RC Shephard WD Edelstein RM Forsyth CP Gamarnik K Ginther G Kreymer AE Lipton R McQuade JM Potter DM Russ JS Spiegel L Johnson DE Buchholz D Cremaldi L Delchamps SW Mao HS Rosen JL Sakumoto W Schluter RA Sontz SB Winter C 《Physical review D: Particles and fields》1992,45(7):2244-2248
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