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1.
Abdurrahmanoğlu S Ozkaya AR Bulut M Bekaroğlu O 《Dalton transactions (Cambridge, England : 2003)》2004,(23):4022-4029
A new sandwich-tpype dilutetium tetraphthalocyanine 4 has been synthesized by the reaction of dimeric lutetium(III) phthalocyanine 3 with two equiv. of dilithium octakishexylthiophthalocyanine in amyl alcohol. Compound 3 was prepared from 4',5',4",5"-tetraiminoisoindoline(1,4,7,10-tetrathia-12-crown-4) 1, 4,5-bis(hexylthio)-1,2-diiminoisoindoline and lutetium acetate in amyl alcohol. Compounds 3 and 4 were characterized by elemental analysis, UV/visible, IR, (1)H NMR and ESR spectroscopy. The electrochemical and electrochromic properties of 3 and 4 have been examined by cyclic voltammetry. Both 3 and 4 displayed well-defined electrochromic behavior. 相似文献
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In the present work, according to the concept of extended homogeneous balance method and with help of Maple, we get auto-Bäcklund transformations for a (2 + 1)-dimensional nonlinear evolution equation. Subsequently, by using these auto-Bäcklund transformation, exact explicit solutions of this equation are obtained. 相似文献
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We report the first preparation of furo- and thieno-fused 1,3-diazepine-4,6-dione derivatives starting from ethyl 2-(2-methoxy-2-oxoethyl)-3-furancarboxylate and -thiophencarboxylate. The ester functionalities connected to the hetero-ring were converted regiospecifically into the desired amides. The ester groups attached to the methylene unit were converted into isocyanates via Curtius rearrangement. The ring-closure reaction was performed in the presence of lithium bis(trimethylsilyl)amide at room temperature to give furo- and thieno-fused diazepinone derivatives. 相似文献
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The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions. 相似文献
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Ozer Atakoglu Ozge Yalcin Mustafa Gurhan Ozmen Suleyman Fatih 《Journal of Radioanalytical and Nuclear Chemistry》2021,328(2):701-706
Journal of Radioanalytical and Nuclear Chemistry - Iron phosphate glasses with melting temperatures of?~?1300 °C were developed to immobilize spent nuclear fuels. The... 相似文献
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The linear, nonlinear and improved nonlinear thermodynamic models of the voltage-dependent ion channels were proposed to deduce the exact functional form of the rate constants. In this context, we present a comparative analysis of the linear, nonlinear and improved nonlinear thermodynamic models of voltage-dependent channel kinetics based on the sodium activation experimental data of Cav3.1 channel. We also provide some insight on the assumptions used to derive the thermodynamic models of the channels and show that the improved nonlinear thermodynamic model provides a simple and physically plausible approach to describe the behavior of the voltage-dependent ion channels. 相似文献
8.
Perfluorochemicals (PFCs) are clinically and biotechnologically important species. In this work, the potentiometric titration method in nonaqueous
media is proposed for the determination of acidity constant values of six different perfluorinated compounds. The saturated
and nonsaturated perfluoroacids, perfluorocarnosine, and perfluoroalkyl-β-alanine were potentiometrically titrated in acetonitrile,
N,N-dimethylformamide, acetone, ethanol, methanol, and pyridine with tetrabutylammonium hydroxide. The half-neutralization
potentials and acidity constants of PFCs have been calculated from the titration curves by using the computerized derivative
method. Except for RF-Carnosine, all of the potentiometric titration curves of the PFCs exhibited one stoichiometric and well-defined endpoints
in all of the solvents employed. The reproducibility and sensitivity of the method were evaluated.
The text was submitted by the authors in English. 相似文献
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In the present paper, within the framework of a piecewise homogenous body model, with the use of the exact three-dimensional
equations of elasticity theory, a method proposed earlier is developed for investigating the stress distribution caused by
two neighboring out-of-plane locally cophasally curved fibers located along two parallel planes in an infinite elastic body.
The body is loaded at infinity by uniformly distributed normal forces in the direction of fiber location. The self-equilibrated
normal and shear stresses caused by the curved fibers are analyzed, and the influences of interaction between the fibers and
of the geometric nonlinearity on the distribution of these stresses are studied. Numerical results for this interaction are
obtained. 相似文献
10.
A new analytical approach based on fractionation was introduced for lead in lipstick samples. Different separation techniques including n-hexane, glycerol extraction, and activated carbon adsorption were used to characterize the lipid fraction, polar and aromatic components of the samples. Additionally, artificial saliva and food stimulant extractions were used for the risk assessment studies. Trace metal levels in fractions were determined by inductively coupled plasma-mass spectrometry. Method validation parameters in the total element determinations were defined in terms of detection limits, accuracy, and precision. The limits of detection and quantification were 0.02 and 0.07 mg kg?1 for Pb; whereas the repeatability and reproducibility of the results based on percent relative standard deviation were 3.0% and 7.2% for lead, respectively. 相似文献