Exact solution of thermal radiation on MHD flow over a stretching porous sheet

The effect of radiation on MHD steady asymmetric flow of an electrically conducting fluid past a stretching porous sheet in the presence of radiation has been analyzed. Exact solutions for the velocity and temperature fields have been derived and the effects of radiation, magnetic, Prandtl number, wall temperature and suction (or injection) parameters have been studied with the help of graphs.     

Fmoc solid-phase synthesis of peptide thioesters using an intramolecularn,S-acyl shift

[reaction: see text] We describe the Fmoc solid-phase synthesis of peptide thioesters based on the alkylation of the safety-catch sulfonamide linker with a protected 2-mercaptoethanol derivative. The thioester is generated on the solid phase after the peptide chain assembly as a consequence of an intramolecular N,S-acyl shift. Depending on the stability of the spacer separating the sulfonamide linker from the resin toward TFA, treatment of the peptidyl resin with TFA led to a soluble or supported deprotected thioester.