Optimal size-based opportunistic scheduler for wireless systems

Modern wireless cellular systems are able to utilize the opportunistic scheduling gain originating from the variability in the users’ channel conditions. By favoring users with good instantaneous channel conditions, the service capacity of the system can be increased with the number of users. On the other hand, for service systems with fixed service capacity, the system performance can be optimized by utilizing the size information. Combining the advantages of size-based scheduling with opportunistic scheduling gain has proven to be a challenging task. In this paper, we consider scheduling of data traffic (finite-size elastic flows) in wireless cellular systems. Assuming that the channel conditions for different users are independent and identically distributed, we show how to optimally combine opportunistic and size-based scheduling in the transient setting with all flows available at time 0. More specifically, by utilizing the time scale separation assumption, we develop a recursive algorithm that produces the optimal long-run service rate vectors within the corresponding capacity regions. We also prove that the optimal operating policy applies the SRPT-FM principle, i.e., the shortest flow is served with the highest rate of the optimal rate vector, the second shortest with the second highest rate, etc. Moreover, we determine explicitly how to implement the optimal rate vectors in the actual time slot level opportunistic scheduler. In addition to the transient setting, we explore the dynamic case with randomly arriving flows under illustrative channel scenarios by simulations. Interestingly, the scheduling policy that is optimal for the transient setting can be improved in the dynamic case under high traffic load by applying a rate-based priority scheduler that breaks the ties based on the SRPT principle.     

Miniemulsion polymerization initiated by L‐ascorbic acid and sulfonate/sulfate surfactants

Styrene miniemulsions that were stabilized by common anionic surfactants (sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, and disulfonated alkyl diphenyl oxide sodium salt) polymerized at 25 °C in the presence of L ‐ascorbic acid without the addition of a free‐radical initiator. The polymerizations exhibited high rates and molecular weights, with conversions greater than 70% achieved in less than 1 h and weight‐average molecular weights greater than 1 × 10⁶ g/mol. Polymers did not form in the absence of L ‐ascorbic acid. Although the final conversion was only slightly independent on the L ‐ascorbic acid concentration, it was dependent on the surfactant concentration. The rate and final conversion were also strongly dependent on the surfactant type. Moreover, it was possible to initiate polymerizations with a monomer‐soluble derivative of L ‐ascorbic acid (L ‐ascorbic acid 6‐palmitate), although the rates were dramatically reduced compared with those when water‐soluble L ‐ascorbic acid was used. High yields and high‐molecular‐weight polymers were also produced with butyl acrylate and methyl methacrylate with L ‐ascorbic acid in the presence of sodium dodecyl benzene sulfonate. The initiation was attributed to an interaction between the surfactant and L ‐ascorbic acid, which formed a redox initiation system that generated radicals capable of adding monomer. These results are of particular significance for redox‐initiated emulsion/miniemulsion polymerizations with L ‐ascorbic acid as the reducing agent and with sulfate or sulfonate surfactants. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 69–80, 2007     

Chemical structure and curing dynamics of bisphenol S,PEEKTM-like,and resveratrol phthalonitrile thermoset resins

This effort provides a multifaceted analysis of the structural changes and material dynamics of thermally driven softening and curing of three distinct phthalonitrile (PN) resins that cross-link into thermally stable and oxidation-resistant thermosets. Although this material system has yielded a large subset of fire-retardant composites that require facile processing and low-temperature curing, to date, insufficient information had been available on the fundamental processes that drive their softening and curing stages. Our approach conducted a complementary analysis the chemistry, monomer mobility, and rheology of three PN polymers in order to correlate the curing processes with corresponding structural and behavioral transformations of thermosets. We focused on PNs with a bisphenol S backbone, a bisphenol A (PEEK^TM-like) backbone, and a resveratrol backbone. We relied on quasi-elastic neutron scattering (QENS) in order to analyze the in situ dynamics and self-diffusion properties of PN monomers, and to track changes in their mobilities during cross-linking and staging. Our analysis facilitates proper control over the staging and final curing of these resins and enables more efficient processing of these thermosets.     

Reactivity of radicals generated on irradiation of trans-[Ru(NH3)4(NO2)P(OEt)3](PF6)

The electronic absorption spectrum of trans-[Ru(NH(3))(4)(NO(2))(P(OEt)(3)](+) in aqueous solution is characterized by a strong absorption band at 334 nm (lambda(max) = 1800 mol(-1) L cm(-1)). On the basis of quantum mechanics calculations, this band has been assigned to a MLCT transition from the metal to the nitro ligand. Molecular orbital calculations also predict an LF transition at 406 nm, which is obscured by the intense MLCT transition. When trans-[Ru(NH(3))(4)(NO(2))(P(OEt)(3)](+) in acetonitrile is irradiated with a 355 nm pulsed laser light, the absorption features are gradually shifted to represent those of the solventocomplex trans-[Ru(NH(3))(4)(solv)(P(OEt)(3)](2+) (lambda(max) = 316 nm, epsilon = 650 mol(-1) L cm(-1)), which was also detected by (31)P NMR spectroscopy. The net photoreaction under these conditions is a photoaquation of trans-[Ru(NH(3))(4)(NO(2))(P(OEt)(3)](+), although, after photolysis, the presence of the nitric oxide was detected by differential pulse polarography. In phosphate buffer pH 9.0, after 15 min of photolysis, a thermal reaction resulted in the formation of a hydroxyl radical and a small amount of a paramagnetic species as detected by EPR spectroscopy. In the presence of trans-[Ru(NH(3))(4)(solv)P(OEt)(3)](2+), the hydroxyl radical initiated a chain reaction. On the basis of spectroscopic and electrochemical data, the role of the radicals produced is analyzed and a reaction sequence consistent with the experimental results is proposed. The 355 nm laser photolysis of trans-[Ru(NH(3))(4)(NO(2))(P(OEt)(3)](+) in phosphate buffer pH 7.4 also gives nitric oxide, which is readily trapped by ferrihemeproteins (myoglobin, hemoglobin, and cytochrome C), giving rise to the formation of their nitrosylhemeproteins(II), (NO)Fe(II)hem.     

A COUPLED FLUID-STRUCTURE ANALYSIS FOR 3-D INVISCID FLUTTER OF IV STANDARD CONFIGURATION

A three-dimensional non-linear time-marching method and numerical analysis for aeroelastic behaviour of an oscillating blade row is presented. The approach is based on the solution of the coupled fluid-structure problem in which the aerodynamic and structural equations are integrated simultaneously in time. In this formulation of a coupled problem, the interblade phase angle at which a stability (or instability) would occur is a part of the solution. The ideal gas flow through multiple interblade passage (with periodicity on the whole annulus) is described by the unsteady Euler equations in the form of conservative laws, which are integrated by use of the explicit monotonic second order accurate Godunov-Kolgan volume scheme and a moving hybrid H-H (or H-O) grid. The structure analysis uses the modal approach and 3-D finite element model of the blade. The blade motion is assumed to be a linear combination of modes shapes with the modal coefficients depending on time. The influence of the natural frequencies on the aerodynamic coefficient and aeroelastic coupled oscillations for the Fourth Standard Configuration is shown. The stability (instability) areas for the modes are obtained. It has been shown that interaction between modes plays an important role in the aeroelastic blade response. This interaction has an essentially non-linear character and leads to blade limit cycle oscillations.