全文获取类型
收费全文 | 207篇 |
免费 | 13篇 |
国内免费 | 6篇 |
专业分类
化学 | 122篇 |
晶体学 | 2篇 |
力学 | 1篇 |
数学 | 63篇 |
物理学 | 38篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2019年 | 8篇 |
2018年 | 3篇 |
2017年 | 7篇 |
2016年 | 7篇 |
2015年 | 5篇 |
2014年 | 12篇 |
2013年 | 8篇 |
2012年 | 8篇 |
2011年 | 13篇 |
2010年 | 8篇 |
2009年 | 8篇 |
2008年 | 17篇 |
2007年 | 3篇 |
2006年 | 6篇 |
2005年 | 12篇 |
2004年 | 1篇 |
2003年 | 12篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 11篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 1篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有226条查询结果,搜索用时 15 毫秒
1.
Oriňák Andrej Arlinghaus Heinrich Frank Vering Guido Justinová Martina Oriňáková Renáta Turčániová L’udmila Halama Maroš 《平面色谱法杂志一现代薄层色谱法》2003,16(1):23-27
JPC – Journal of Planar Chromatography – Modern TLC - Two interfaces have been tested for coupling thin-layer chromatography (TLC) with time-of-flight secondary-ion mass spectrometry... 相似文献
2.
Influence of boric acid on the electrochemical deposition of Ni 总被引:1,自引:0,他引:1
M. Šupicová R. Rozik L. Trnková R. Oriňáková M. Gálová 《Journal of Solid State Electrochemistry》2006,10(2):61-68
The electrolytic deposition of Ni onto a paraffin-impregnated graphite electrode from supporting chloride electrolyte (0.5 mol dm−3 NaCl) adjusted to the required pH using dilute HCl is investigated. The effect of electrolyte composition on the Ni electrodeposition
is studied using linear sweep voltammetry in the cathodic region. An elimination voltammetry procedure was applied to evaluate
the polarization curves. The aim of this work was to deduce the mechanism of Ni reduction in the chloride bath as well as
the influence of boric acid on this. Positively-charged NiCl+ ions were found to be the electroactive particles in the Ni reduction mechanism. The strong competition between the NiCl+, Cl− and H+ ions for active sites at the electrode is discussed. Kinetically-controlled adsorption/desorption processes of various species
were also confirmed using elimination voltammetry with a linear scan. The evolution of gaseous hydrogen, catalyzed by the
freshly-deposited Ni, accompanies the electrodeposition process. The presence of boric acid at a sufficiently high concentration
inhibits the deposition of Ni and, at the same time, improves the morphology and brightness, as well as the adhesion of the
deposited Ni.
Elimination voltammetry with a linear scan is an efficient way to evaluate current–potential curves that reflect the electrodeposition
of one-component Ni coatings. By eliminating selected currents, additional interesting and useful information can be obtained
from voltammetric data. 相似文献
3.
4.
Rachel Atzmon Ori Cheshnovsky Baruch Raz Joshua Jortner 《Chemical physics letters》1974,29(3):310-313
We report an experimental study of Xe(3P1) → Xe(3P2) electronic quenching by Ar in Xe/Ar mixtures optically excited by the 1470 Å line of Xe. The quenching process was monitored by the observation of the Xe*2 second emission continuum at low Xe pressures. 相似文献
5.
Bragg AE Verlet JR Kammrath A Cheshnovsky O Neumark DM 《The Journal of chemical physics》2005,122(5):54314
Time-resolved photoelectron imaging has been used to study the relaxation dynamics of small Hg(n) (-) clusters (n=7-13,15,18) following intraband electronic excitation at 1250 nm (1.0 eV). This study furthers our previous investigation of single electron, intraband relaxation dynamics in Hg(n) (-) clusters at 790 nm by exploring the dynamics of smaller clusters (n=7-10), as well as those of larger clusters (n=11-13,15,18) at a lower excitation energy. We measure relaxation time scales of 2-9 ps, two to three times faster than seen previously after 790 nm excitation of Hg(n) (-), n=11-18. These results, along with size-dependent trends in the absorption cross-section and photoelectron angular distribution anisotropy, suggest significant evolution of the cluster anion electronic structure in the size range studied here. Furthermore, the smallest clusters studied here exhibit 35-45 cm(-1) oscillations in pump-probe signal at earliest temporal delays that are interpreted as early coherent nuclear motion on the excited potential energy surfaces of these clusters. Evidence for evaporation of one or two Hg atoms is seen on a time scale of tens of picoseconds. 相似文献
6.
Kostko O Wrigge G Cheshnovsky O von Issendorff B 《The Journal of chemical physics》2005,123(22):221102
We present photoelectron spectroscopy studies on Zn(n) (-) in the size range of n=3-117. We show that zinc clusters exhibit a distinct transition in their electronic structure as a function of size. At small sizes (up to n=18) the clusters follow the Bloch-Wilson picture of the development of a metal from closed-shell atoms, exhibiting a gradual decrease of the gap between the fully occupied s band and the empty p band. For large sizes (n approximately or > 32) the band overlap allows the valence electrons to fully delocalize. This leads to an almost perfect free-electron density of states, as is demonstrated by discussing the spectra in the light of standard free-electron models and by comparison to the results obtained on sodium clusters. 相似文献
7.
Gil Markovich Stuart Pollack Rina Giniger Ori Cheshnovsky 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,26(1):98-100
We have measured the photoelectron-spectra of I? (H2O)n clusters in the size range n=1–60. We have found that the first six water molecules form a solvation layer with an average 0.35 eV electrostatic stabilization of the anion. At larger cluster sizes the electrostatic stabilization of water does not fit a continuous dielectric solvent. The most stable structures of the clusters consist of internally solvated anions. In the size range n=34–40 we have found evidence for existence of cluster structures with surface solvated anions. 相似文献
8.
9.
This paper is devoted to the first steps towards a systematic study of pro-p groups which are analytic over a commutative Noetherian local pro-p ring Λ, e.g. Λ=
. We restrict our attention to Λ-standard groups, which are pro-p groups arising from a formal group defined over Λ. Under some additional assumptions we show that these groups are of ‘intermediate
growth’ in various senses, strictly betweenp-adic analytic pro-p groups and free pro-p groups. This suggests a refinement of Lazard's theory which stresses the dichotomy betweenp-adic analytic pro-p groups and all the others. In the course of the discussion we answer a question posed in [LM1], and settle two conjectures
from [Bo]. 相似文献
10.
It is known that the subgroup growth of finitely generated linear groups is either polynomial or at least $n^{\frac{{\log n}}{{\log \log n}}} $ . In this paper we prove the existence of a finitely generated group whose subgroup growth is of type $n^{\frac{{\log n}}{{(\log \log n)^2 }}} $ . This is the slowest non-polynomial subgroup growth obtained so far for finitely generated groups. The subgroup growth typen logn is also realized. The proofs involve analysis of the subgroup structure of finite alternating groups and finite simple groups in general. For example, we show there is an absolute constantc such that, ifT is any finite simple group, thenT has at mostn c logn subgroups of indexn. 相似文献