全文获取类型
收费全文 | 68篇 |
免费 | 1篇 |
国内免费 | 4篇 |
专业分类
化学 | 48篇 |
数学 | 5篇 |
物理学 | 20篇 |
出版年
2023年 | 1篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2017年 | 1篇 |
2015年 | 1篇 |
2014年 | 1篇 |
2013年 | 2篇 |
2012年 | 2篇 |
2011年 | 1篇 |
2010年 | 3篇 |
2007年 | 4篇 |
2006年 | 1篇 |
2005年 | 4篇 |
2004年 | 6篇 |
2003年 | 2篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有73条查询结果,搜索用时 46 毫秒
1.
[(?) (R)-1,2-bis (Diphenylphosphino)-1-phenylethane]nickel (II) chloride was found to catalyze the asymmetric alkylation of some chiral and achiral allylic alcohols with Grignard reagents, leading to the formation of optically active olefins. Enantiomer discrimination of the substrate takes place in the alkylation of chiral allylic alcohols. 相似文献
2.
Giuliana Biagi Irene Giorgi Oreste Livi Clementina Manera Valerio Scartoni Pier Luigi Barili 《Journal of heterocyclic chemistry》1997,34(3):845-851
This paper continues the synthesis of new 1,2,3-triazolo[1,2-a]benzotriazoles or 2,3-benzo-1,3a,6,6a-tetrazapentalenes to submit to biological assays. The derivatives were obtained by deoxycyclization reactions of appropriate nitrophenyl-1,2,3-triazole derivatives and by thermal decomposition of appropriate azidophenyl-1,2,3-triazoles (Schemes 1 and 2). Some attempts to extend these synthetic routes to the preparation of 1,2,4-triazolo[1,2-a]benzotriazoles (Scheme 3) and 1,2,3-triazolo[1,2-b]-4H-1,2,3-benzo-triazines (Scheme 4) completely failed. 相似文献
3.
Giuliana Biagi Irene Giorgi Oreste Livi Federica Pacchini Valerio Scartoni 《Journal of heterocyclic chemistry》2002,39(5):885-888
The 7‐chloro‐3‐(2‐chlorobenzyl)‐ and 7‐chloro‐3‐(2‐fluorobenzyl)‐1,2,3‐triazolo[4,5‐d]pyrimidines ( 1 and 4 ), by nucleophilic replacement with some hydrazides, gave the corresponding 7‐hydrazidoderivatives ( 2a‐e and 5a‐e ). These, by heating in Dowtherm, underwent an intramolecular cyclization to form the new tricyclic 7‐substituted‐3‐(2‐chlorobenzyl)‐ and 3‐(2‐fluorobenzyl)‐1,2,3‐triazolo[4,5‐e]1,2,4‐triazolo[4,3‐c]pyrimidines ( 3a‐d and 6a‐d ). The 7‐hydrazino‐3‐(2‐chlorobenzyl)‐ and 7‐hydrazino‐3‐(2‐fluorobenzyl)‐triazolo‐pyrimidines ( 9a and 9b ) were also prepared via the corresponding mercapto ( 7a and 7b ) and thiomethyl ( 8a and 8b ) derivatives. 相似文献
4.
Antonio Da Settimo Giuliana Biagi Giampaolo Primofiore Pier Luigi Ferrarini Oreste Livi Anna Maria Marini 《Journal of heterocyclic chemistry》1980,17(6):1225-1229
The preparation of some 3,7-disubstituted-5,6-dihydroquino[3,2-c][1,8]naphthyridines ( 6 ) by the condensation of 7-substituted-2,3-dihydro-1,8-naphthyridin-4-(1H)ones ( 5 ) with o-aminoacetophenone or o-aminobenzophenone is described. All the 5,6-dihydroderivatives 6 were transformed into the fully aromatic compounds 7 by heating with nitrobenzene. Only a few quino[3,2-c][1,8]naphthyridines were previously described. 相似文献
5.
Giuliana Biagi Irene Giorgi Oreste Livi Clementina Manera Valerio Scartoni 《Journal of heterocyclic chemistry》1997,34(1):65-69
Some new 1,2,3-triazolo[4,5-d]-1,2,4-triazolo[4,3-b]pyridazines were prepared starting from the corresponding 1,2,3-triazolo[4,5-d]pyridazines via the formation of the 1,2,4-triazole ring, by condensation of an appropriate monocarbon fragment with the 4-hydrazino substituent and the nitrogen atom in the 5 position of the heterocycle. Condensation of 4-phenylhydrazino substituted derivatives with formic acid gave zwitterionic compounds. 相似文献
6.
Giuliana Biagi Irene Giorgi Oreste Livi Federica Pacchini Valerio Scartoni Oreste Leroy Salerni 《Journal of heterocyclic chemistry》2004,41(4):581-585
Title compounds bearing substituents on C(2), C(6) and C(8) were prepared from a newly synthesized pyrimidine derivative 11. The new pyrimidine 11 was generated from compound 2 through two different synthetic schemes. In one pathway, compound 2 was nitrosated, reduced and alkylated to produce com pounds 9 , 10 and 11 respectively (Scheme). In an alternate route using compound 2 as the starting material, a coupling reaction using the diazonium salt derived from p‐methylaniline afforded the azo derivative 7 , which was subsequently alkylated and reductively cleaved to form compounds 8 and 11 respectively (See Scheme). Compound 11 was annulated to the corresponding hypoxanthine derivatives 12–14 ; compounds 12 and 13 were chlorinated with phosphorus oxychloride, then reacted with amines to yield compound 17 and 20 respectively. Compounds 21 , 22 and 23 were obtained by oxidation of the corresponding sulfide as depicted in Scheme. Alkylation of the thiol function of 1 gave a mixture of 3 and 4. Compound 3 was chlo rinated to 5. Nitration of 5 resulted in electrophilic aromatic substitution of the aryl ring and concomitant oxidation of the sulfide to the sulfoxide, producing 6. 相似文献
7.
8.
Gialiana Biagi Irene Giorgi Oreste Livi Valerio Scartoni Silvia Velo Pier Luigi Barili 《Journal of heterocyclic chemistry》1996,33(6):1847-1853
A new 4-(benzotriazol-1-yl)-1,2,3-triazole structure was obtained by the diazotization reaction of either of 1-(2-aminophenyl)-4-carboxamido-5-amino-1H-1,2,3-triazole ( 1c ) or of the corresponding Dimroth isomer 1d . It underwent some common reactions to evaluate its chemical behaviour and structure. An analogous reaction sequence was carried out from the 2-nitro-4-methylphenyl azide, to assign the structure to the nitro derivatives prepared. The structure of the new compounds prepared was confirmed by chemical and spectroscopic methods. 相似文献
9.
The dynamics of small spherical neutrally buoyant particulate impurities immersed in a two-dimensional fluid flow are known to lead to particle accumulation in the regions of the flow in which vorticity dominates over strain, provided that the Stokes number of the particles is sufficiently small. If the flow is viewed as a Hamiltonian dynamical system, it can be seen that the accumulations occur in the nonchaotic parts of the phase space: the Kolmogorov-Arnold-Moser tori. This has suggested a generalization of these dynamics to Hamiltonian maps, dubbed a bailout embedding. In this paper we use a bailout embedding of the standard map to mimic the dynamics of neutrally buoyant impurities subject not only to drag but also to fluctuating forces modeled as white noise. We find that the generation of inhomogeneities associated with the separation of particle from fluid trajectories is enhanced by the presence of noise, so that they appear in much broader ranges of the Stokes number than those allowing spontaneous separation. (c) 2002 American Institute of Physics. 相似文献
10.
Algebraic Isomorphisms and Finite Distributive Subspace Lattices 总被引:1,自引:0,他引:1
Let L1 and L2 be finite distributive subspace lattices on realor complex Banach spaces. It is shown that every rank-preservingalgebraic isomorphism of AlgL1 onto AlgL2 is quasi-spatiallyinduced. If the algebraic isomorphism in question is known onlyto preserve the rank of rank one operators, then it inducesa lattice isomorphism between L1 and L2. 相似文献