Time-dependent pump-probe spectra of NeBr2

Time- and frequency-resolved pump-probe measurements on NeBr2 have been performed to better characterize its fragmentation dynamics on the B electronic state for vibrational levels in the energy region of the transition from direct vibrational predissociation to intramolecular vibrational relaxation dynamics. Above nu'=20 of the Br2 stretching mode, it was observed that the dependence of lifetime on the vibrational quantum number deviates from the energy-gap law by leveling off in the range of 10 psE transitions of the complex. These transitions are shifted 20 cm(-1) to lower energy from the free Br2 resonances, indicating an E state Ne-Br2 bond energy of 82 cm(-1). Measurements of NeBr2 vibrational predissociation via the delta nu=-2 channel were also performed for nu'=27, 28, and 29. The closing of the delta nu=-1 channel leads to an increase in the lifetimes of these vibrational levels. A new Nd:yttrium aluminum garnet pumped dual optical parametric oscillator/optical parametric amplifier system is described that allows us to conveniently record time-delayed pump-probe spectra with 2-cm(-1) spectral resolution and 15-ps time resolution.     

Analysis of Unsteady Motion with Respect to Noise Sources in a Gas Turbine Combustor: Isothermal Flow Case

In order to evaluate the direct and indirect contributions to the total combustion noise emission, a combustion chamber consisting of a swirl burner and an exit nozzle of Laval-shape, representing a gas turbine combustor, is investigated by means of experiments and large eddy simulation. Focused on the isothermal flow case first and encouraged by a good overall agreement between the LES and the experimental data for the flow field, a first characterisation of the flow with respect to noise sources is performed. To analyse acoustic properties of the flow, time and length scales are evaluated inside the combustor. Furthermore, the evidence for the existence of a precessing vortex core (PVC), typical for configurations with swirl, is revealed. Finally, the effect of the PVC on the flow inside the Laval nozzle is discussed.     

Strong flow criteria based on microstructure deformation

The dynamics of fluid systems which consist of a suspended material in a Newtonian continuous phase is investigated theoretically. Criteria are derived to predict conditions under which the strength of a flow, i.e. a measure of the form and magnitude of the velocity gradient tensor, is sufficient to induce significant deformation and/or orientation of the fluid microstructure, that is, the elements which collectively comprise the suspended phase. The development relies upon the choice of a model to describe the microstructure, and the form of the criteria reflects this choice. Once the choice is made, however, the detailed material properties of a particular fluid system enter only as parameters in the resulting equations, and thus, the results encompass a large class of systems, including particulate suspensions and macromolecular solutions. Two microstructure models are investigated here. When the microstructure is characterized by a vector, the flow strengths of all linear flows are displayed in a single figure from which the strength of a particular flow can be evaluated directly. A comparison is then made for selected flows between these results and those for the case where an irreducible second order tensor is employed to describe the microstructure. A significant difference between the two models derives from the fact that the “volume” of the microstructure must be conserved in the second-order tensor case. The criteria are finally used to predict the degree of macromolecular stretching in a model turbulent flow and the breakup of immiscible liquid drops in simple shear flow. A comparison between the flow strength predictions and experimental data yields good qualitative agreement in the latter case.     

Higher order corrections in perturbative quantum chromodynamics

We present some techniques which have been developed recently or in the recent past to compute Feynman graphs beyond one-loop order. These techniques are useful to compute the three-loop splitting functions in QCD and to obtain the complete second order QED corrections to Bhabha scattering.     

Analysis of subgrid scale mixing using a hybrid LES-Monte-Carlo PDF method

This contribution introduces a hybrid LES-Monte-Carlo method for a coupled solution of the flow and the multi-dimensional scalar joint pdf in two complex mixing devices. For this purpose an Eulerian Monte-Carlo method is used. First, a complex mixing device (jet-in-crossflow, JIC) is presented in which the stochastic convergence and the coherency between the scalar field solution obtained via finite-volume methods and that from the stochastic solution of the pdf for the hybrid method are evaluated. Results are compared to experimental data. Secondly, an extensive investigation of the micromixing on the basis of assumed shape and transported SGS-pdfs in a configuration with practical relevance is carried out. This consists of a mixing chamber with two opposite rows of jets penetrating a crossflow (multi-jet-in-crossflow, MJIC). Some numerical results are compared to available experimental data and to RANS based results. It turns out that the hybrid LES-Monte-Carlo method could achieve a detailed analysis of the mixing at the subgrid level.