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Peteris Daugulis 《Linear algebra and its applications》2012,436(3):709-721
The problem of finding a canonical form of complex matrices up to conjugacy with the set of canonical matrices being a union of affine planes in the matrix space is considered. A solution of the problem is given. 相似文献
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O. Daugulis 《Chemistry of Heterocyclic Compounds》2012,48(1):21-26
The use of non-activated aryl chloride electrophiles in the direct arylation of carbon–hydrogen bonds in five-membered ring heterocycles is described. Specifically, palladium-, ruthenium-, and nickel-catalyzed transformations, as well as reactions proceeding via benzyne intermediates, are discussed. 相似文献
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A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP(2)Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported. 相似文献
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[Structure: see text] Unsubstituted benzylamines and N-methylbenzylamine can be ortho-arylated under palladium catalysis at 130 degrees C. The reactions require the presence of trifluoroacetic acid and silver acetate. 相似文献
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Tung Thanh Nguyen Dr. Liene Grigorjeva Prof. Dr. Olafs Daugulis 《Angewandte Chemie (International ed. in English)》2018,57(6):1688-1691
A method for cobalt‐catalyzed, carboxylate‐directed functionalization of arene C?H bonds is reported. Alkynes, styrenes, and 1,3‐dienes can be coupled with benzoic acids to provide cyclic products in good yields. The reactions proceed in the presence of a cobalt(II) hexafluoroacetylacetonate catalyst, (TMS)2NH base, Ce(SO4)2 cooxidant, and oxygen oxidant. 相似文献
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Dr. Ilya Popov Dr. Teng‐Hao Chen Dr. Sergey Belyakov Prof. Olafs Daugulis Prof. Steven E. Wheeler Prof. Ognjen Š. Miljanić 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(7):2750-2754
We report structural characterization of a new member of m‐phenylene ethynylene ring family. This shape‐persistent macrocycle also co‐crystallizes with hexafluoro‐, 1,2,4,5‐tetrafluoro‐, 1,3,5‐trifluoro, and 1,4‐difluorobenzene. The four complexes are almost isostructural, and all show the fluoroarene included into the central cavity of the macrocycle. Characterized by multiple short C?H???F?C contacts, these inclusion complexes further dimerize in the solid state into a 2+2 assembly, in which the two macrocycles embrace each other by their large hydrophobic groups that are rotated by 60° relative to one another. 相似文献