The structure of poly-2,5-benzoxazole (ABPBO) and poly-2,6-benzothiazole (ABPBT) fibers by X-ray diffraction

The determination of the crystalline structure of oriented fibers of poly-2,5-benzoxazole (ABPBO) and poly-2,6-ben-zothiazole (ABPBT) is described. Both unit cells are metrically orthorhombic, with the parameters: a = 6.061 (17), b = 3.384 (13), c (fiber axis) = 11.575 (6) Å for ABPBO; and a = 6.044 (6), b = 3.417 (7), c (fiber axis) = 12.194 (18) Å for ABPBT. The fiber repeat consists in each structure of two fused ring groups arranged in a planar, zigzag conformation. The conformational torsion angle and orientation of chains within the unit cells are derived from a linked-atom least squares refinement technique. Polymer chains pack laterally through van der Waals interactions. A plausible disorder model which involves defects in chain direction is presented. Refinement of a static disorder model for ABPBO in which 50% of the chains have their chain directions reversed leads to a lower R residual and sum of constraints.     

Stereospecific Synthesis of S,S-Statine and its Congeners

Statine (STA, 8) and its cyclohexyl analog (ACHPA, 9) are obtained by a stereospecific synthesis via tetramic acid chemistry. Amides of STA and ACHPA, useful for the synthesis of antihyperten-sive renin inhibitors, are prepared directly from the intermediate activated lactams 7 by nucleophilic ring opening with amines.     

8-Methxlcorxpallihe and its O-Metbzlzzher: A Facile Sxhthesis of 8-Methxl Substituted-6, 7- Dimethoxy Tetrahsdroisoquxnolines

Abstract

The optically active B-Methy1 substituted tetrahydroisoquinoline (?)? 1 is a major reaction product in the cleavage of the bisbenzylisoquinoline alkaloid repanduline with potassium in liquid ammonia.¹ A synthesis of (±) ? 1 by a rather lengthy procedure has been reported.² In this connection we now wish to report a simple and efficient method of introducing an 8-methyl substituent into a 7-hydroxy-6- methoxy tetrahydroisoquinoline. This approach, which has probably wider applications, is exemplified by the synthesia of 8-methylcorypalline 4 and its O-methylether 5 and involves the thiomethylation reaction of poppeladorf and Holt³ followed by reductive desulfurization of the phenyl thiomethyl intermediate.     

Self-duality in Euclidean supergravity

The compatibility of Euclidean supergravity with curvature satisfying (a) self-duality and (b) a double duality Ansatz are investigated. The Minkowskian version of (b) is also considered.     

Scalar field solutions to Yang-Mills and Vierbein field theories

Covariant solutions to the Vierbein (gravitational) field equations are related to solutions of scalar field equations. New solutions to the latter are also given.     

Anomalous thermopower in the metalliclike phase of a 2D hole system

We report very low temperature ( T) thermopower and resistivity ( rho) measurements on variable-density, two-dimensional hole systems confined to GaAs quantum wells. As the hole density is lowered from 1.49x10(11) cm(-2) to 0.14x10(11) cm(-2), the system crosses from an insulating ( drho / dT less, similar0) to a metallic regime ( drho / dT>0) and finally displays insulating behavior ( drho / dT<0). Diffusion thermopower shows a striking sign reversal in a narrow range of density in the metallic regime, suggesting a qualitative change in the conduction or the scattering mechanism.     

The Alperin and Dade Conjectures for the O'Nan and Rudivalis Simple Groups

We classify the radical subgroups and chains of the O'Nan and Rudvalis simple groups O'N and Ru, and then verify the Alperin weight conjecture and the Dade final conjecture for the two groups.     

A monopole mass filter with a hyperbolic V-shaped electrode

In this article we compare the classical monopole mass filter of von Zahn and the monopole mass filter with a hyperbolic V-shaped electrode. The experimental results and those of computer simulation for both mass spectrometers are presented. We show that the replacement of a conventional 90 degrees V-shaped electrode by an electrode with a hyperbolic profile substantially improves the peak shape of any given mass, and increases the mass resolution by a factor of 3-4 and the abundance sensitivity by a factor of 100. The potential of high analytical performance combined with electroforming techniques for electrode manufacture indicate future practical uses of such instruments. Copyright 1999 John Wiley & Sons, Ltd.     

Indoor optical wireless systems–a review

This paper reviews the research effort to date into optical wireless communication systems, both in academic and industrial contexts. The idea of using the optical medium for wireless communications is not new, having been proposed as a means for indoor communications almost two decades ago. However, the last few years have seen an explosive interest in the potential for free space optical systems to provide portable data communications. One of the prime motivators for reconsidering the use of an optical carrier in the wireless context is the demand for greater transmission bandwidths. The radio frequency spectrum is already exceedingly congested and frequency allocations of sufficient bandwidths are extremely hard to obtain. Further, for the high bandwidth services envisaged, the use of microwave or mm-wave systems will be required, where device technology is currently either expensive or immature. Proponents of optical wireless systems argue that the optical medium is the only cost-effective way to provide high bit-rate mobile services to volume markets. This paper identifies the technical obstacles and limitations of indoor optical wireless delivery in addition to techniques for mitigating these effects and shows that infrared is a viable alternative to radio for certain applications. This revised version was published online in November 2006 with corrections to the Cover Date.     

Shape resonances in slow electron scattering by aromatic molecules. I. Anthraquinone derivatives

A series of anthraquinone (C(14)O(2)H(8)) derivatives has been studied by means of electron capture negative ion mass spectrometry (ECNI-MS), photoelectron spectroscopy (PES), and AM1 quantum chemical calculations. Mean lifetimes of molecular negative ions M(-.) (MNI) have been measured. The mechanism of long-lived MNI formation in the epithermal energy region of incident electrons has been investigated. A simple model of a molecule (a spherical potential well with the repulsive centrifugal term) has been applied for the analysis of the energy dependence of cross sections at the first stage of the electron capture process. It has been shown that a temporary resonance of MNI at the energy approximately 0.5 eV corresponds to a shape resonance with lifetime 1-2.10(-13) s in the f-partial wave (l = 3) of the incident electron. The next resonant state of MNI at the energy approximately 1.7 eV has been associated with the electron excited Feshbach resonance (whose parent state is a triplet npi* transition). In all cases the initial electron state of the MNI relaxes into the ground state by means of a radiationless transition, and the final state of the MNI is a nuclear excited resonance with a lifetime measurable on the mass spectrometry timescale. Copyright 1999 John Wiley & Sons, Ltd.