全文获取类型
收费全文 | 95篇 |
免费 | 3篇 |
国内免费 | 1篇 |
专业分类
化学 | 44篇 |
力学 | 5篇 |
数学 | 28篇 |
物理学 | 22篇 |
出版年
2021年 | 1篇 |
2019年 | 1篇 |
2015年 | 4篇 |
2013年 | 4篇 |
2011年 | 2篇 |
2010年 | 2篇 |
2009年 | 2篇 |
2008年 | 7篇 |
2007年 | 2篇 |
2006年 | 9篇 |
2005年 | 4篇 |
2004年 | 6篇 |
2003年 | 4篇 |
2002年 | 7篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1993年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1968年 | 3篇 |
1967年 | 1篇 |
排序方式: 共有99条查询结果,搜索用时 46 毫秒
1.
CV Tomy D Pal SS Banerjee S Ramakrishnan AK Grover S Bhattacharya MJ Higgins G Balakrishnan McK Paul 《Pramana》2002,58(5-6):925-935
The weakly pinned single crystals of the hexagonal 2H-NbSe2 compound have emerged as prototypes for determining and characterizing the phase boundaries of the possible order-disorder
transformations in the vortex matter. We present here a status report based on the ac and dc magnetization measurements of
the peak effect phenomenon in three crystals of 2H-NbSe2, in which the critical current densities vary over two orders of magnitude. We sketch the generic vortex phase diagram of
a weakly pinned superconductor, which also utilizes theoretical proposals. We also establish the connection between the metastability
effects and pinning. 相似文献
2.
3.
4.
Tandem intramolecular silylformylation-allyl(crotyl)silylation reactions have been developed that allow the highly efficient synthesis of polyketide fragments. The substrates are subjected to Rh(I)-catalyzed silylformylation to afford β-(diallyl)silyl aldehydes which undergo spontaneous uncatalyzed allylsilylation. This unusual spontaneous allylsilylation reaction is driven by strain release Lewis acidity, which arises from the ∼95° O-Si-C bond angle in the oxasilacyclopentane product of the silylformylation reaction. The methodology has been developed both for alkene and alkyne substrates, may be used to establish as many as three stereocenters, and has been shown to be amenable to use in an iterative fashion. 相似文献
5.
D. T. Clark J. Peeling J. M. O'Malley 《Journal of polymer science. Part A, Polymer chemistry》1976,14(3):543-551
The surface morphology of a number of films of AB block copolymers of polydimethylsiloxane and polystyrene was examined by ESCA and contact angle measurements. In all cases the immediate surface is shown to consist of an essentially pure polydimethylsiloxane component. By comparing the intensities of elastic peaks corresponding to photoionizations from core levels without energy loss for polydimethylsiloxane and polystyrene with those for the block copolymers and by consideration of shake-up phenomena specific to the polystyrene component, an estimate of the thickness of the polydimethylsiloxane outer layer of the latter may be obtained. This is shown to vary between ~13 and 40 Å, depending on the method of formation of copolymer film. 相似文献
6.
Wagner B. De Almeida Hélio F. Dos Santos Patrick J. O'Malley 《Structural chemistry》1995,6(6):383-389
The potential energy surface (PES) for the herbicide diuron (DCMU), a photosystem II inhibitor, has been extensively investigated using the quantum-mechanical semiempirical molecular orbital methods AM1 and PM3 and molecular mechanics method. A detailed conformational search has been carried out which revealed the occurrence of four genuine minimum energy structures. The relative stability of the conformers and rotational barriers to conformational interconversion were evaluated using distinct theoretical approaches. The results showed that thetrans form of the diuron molecule is more stable than thecis form in all methods, and so it may possibly be the biologically active isomer. 相似文献
7.
The asymptotic solution of the linear quadratic state regulator problem is obtained as the cost of the control tends to zero. Matrix Riccati gains are obtained via singular perturbations theory and are used to asymptotically calculate the optimal control and the corresponding trajectories. Several cases are distinguished and applications are discussed. 相似文献
8.
S Murray G O'Malley I K Taylor A I Mallet G W Taylor 《Journal of chromatography. A》1989,491(1):15-25
A gas chromatographic-mass spectrometric assay has been developed for the measurement of N tau-methylimidazoleacetic acid in urine and plasma. The method uses the isopropyul ester 3,5-bistrifluoromethylbenzoyl derivative of N tau-methylimidazoleacetic acid and electron capture negative ion chemical ionisation mass spectrometry. The derivative has very good chromatographic properties and a negative ion mass spectrum which contains only a molecular ion at m/z 422. When this ion is specifically monitored, an amount of derivative equivalent to 1 pg of parent compound can be detected. A deuterated analogue of N tau-methylimidazoleacetic acid was synthesised for use as an internal standard and this allowed the development of an assay for N tau-methylimidazoleacetic acid, in urine with a precision of 2.9% and in plasma with a precision of 1.5%. 相似文献
9.
With nine examples, we seek to illustrate the utility of the Renormalization Group approach as a unification of other asymptotic and perturbation methods. 相似文献
10.
A Renormalization Group Method for Nonlinear Oscillators 总被引:2,自引:0,他引:2
We present a new approach for finding the asymptotic solution of certain weakly nonlinear oscillator equations. In particular, we develop a simplified version of the renormalization group method of Chen, et al. to obtain higher-order approximations on longer time intervals than are typically provided by averaging and two-timing. The technique, which has much greater potential, is illustrated on three challenging examples from the literature for which better than usual asymptotic solutions are obtained. 相似文献