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1.
The thermally stimulated properties of PbWO4 in the temperature range 90–400 K have been investigated on undoped and terbium-doped crystals after X-ray irradiation at 90 K. Doping with terbium changes the concentration of shallow traps, which are responsible for retrapping free electrons and holes. Light illumination can change the distribution of the traps. The optically stimulated luminescence is observed. The influence of light illumination on the TSL curves and emission properties is studied. The possible mechanism of TSL phototransformation is discussed. 相似文献
2.
J. Novosad J. Jandl J. D. Woollins 《Journal of Radioanalytical and Nuclear Chemistry》1992,165(5):287-294
Samples of clinoptilolite were modified using insoluble hexacyanoferrate from aqueous solution. The modified samples were characterized by elemental analysis, powder X-ray diffraction, solid state NMR and vibrational spectroscopy. The sorption properties of modified clinoptilolite were studied, too. Higher affinity for137Cs sorption in comparison with the natural clinoptilolite has been proved. 相似文献
3.
Huizhang Liu Maria José Calhorda Michael G.B. Drew Josef Novosad Piero Zanello 《Journal of organometallic chemistry》2004,689(17):2808-2819
New Cu(I) and Ag(I) complexes were prepared by reaction of [M(NCCH3)4][X] (M = Cu or Ag; X = BF4 or PF6) with the bidentate chalcogenide ligands Ph2P(E)NHP(E)Ph2 (E = S, S2dppa; E = Se, Se2dppa), and dpspf (1,1′-bis(diphenylselenophosphoryl)ferrocene). Copper and silver behaved differently. While three molecules of either S2dppa and Se2dppa bind to a distorted tetrahedral Cu4 cluster, with deprotonation of the ligand, 1:2 complexes of the neutral ligands are formed with Ag(I), with a tetrahedral coordination of the metal. The [Cu4{Ph2P(Se)NP(Se)Ph2}3]+ clusters assemble as dimers, held together by weak Se?Se distances interactions. Another dimer was observed for the [Ag(dpspf)]+ cation, with two short Ag?Se distances. DFT and MP2 calculations indicated the presence of attracting interactions, reflected in positive Mayer indices (MI). The electrochemistry study of this species showed that both oxidation and reduction took place at silver. 相似文献
4.
5.
The influence of a gas atmosphere (O2 or air) on the transverse photovoltage (TPV) induced by X-ray irradiation in CdI2 specimens is studied. It is shown that the TPV measured at 295 K in a vacuum grows almost linearly with X-ray dose rate R. In a gas atmosphere, the TPV is of opposite sign and tends to saturation when R exceeds 200 R/min. After evacuation of the system, the TPV value increases, attains a maximum, and then abruptly drops (changing
sign) to the initial “vacuum” value. Based on the results of this study and published data, it is shown that such behavior
of the TPV in CdI2 is related to X-ray-stimulated chemisorption proceeding by the acceptor mechanism. 相似文献
6.
Reaction of sulfur dichloride with sym-EtO2CNHNHCO2Et 1 gives the title ring system which has been characterised by microanalyses, nmr, and X-Ray crystallography. The X-ray structure of S2[N(CO2Et)]4 2 reveals that the S2N4 ring adopts a chair conformation with all four ester groups in pseudo-axial positions. Bond lengths and angles are compared with 1 and S4(NR)2. 相似文献
7.
Sort J Buchanan KS Novosad V Hoffmann A Salazar-Alvarez G Bollero A Baró MD Dieny B Nogués J 《Physical review letters》2006,97(6):067201
The effect of imprinting symmetric and displaced vortex structures into an antiferromagnetic material is investigated in micron-sized disks consisting of exchange coupled ferromagnetic-antiferromagnetic bilayers. The imprint of displaced vortices manifests itself by the occurrence of a new type of asymmetric hysteresis loops characterized by curved, reversible, central sections with nonzero remanent magnetization. Such an imprint is achieved by cooling the disks through the blocking temperature of the system in small fields. Micromagnetic simulations reveal that asymmetric vortexlike loops naturally result from the competition between the different energies involved in the system. 相似文献
8.
S. S. Novosad I. M. Matviishin I. S. Novosad O. S. Novosad 《Journal of Applied Spectroscopy》2008,75(6):826-831
We have studied the effect of lead dopant on the optical absorption, photoluminescence, and x-ray luminescence spectra, and
the scintillation characteristics of CdI2 at room temperature. The crystals for the study were grown by the Stockbarger-Bridgman method. Activation of CdI2 from the melt by the compound PbI2 leads to the appearance in the absorption spectra in the near-edge region of an activator band at 395–405 nm, which is interpreted
as an A band connected with electronic transitions from the 1S0 state to the 3P1 levels in the Pb2+ ion. For x-ray excitation, CdI2:Pb2+ crystals with optimal dopant concentration (∼1.0 mol%) are characterized by a light yield with maximum in the 570–580 nm
region that is an order of magnitude higher than for CdI2 crystals in the 490–500 nm band. For α excitation, the radioluminescence kinetics for cadmium iodide is characterized by
a very short (∼0.3 nsec) rise time and fast decay of luminescence, with τ1 ≈ 4 nsec and τ2 = 10–76 nsec. Depending on the conditions under which the crystals were obtained, the fast component fraction is 95%–99%.
The crystal is characterized by a similar scintillation pulse in the case of excitation by x-ray pulses. The radioluminescence
pulse shape for CdI2:Pb in the decay stage is predominantly exponential, with luminescence decay time constants τ1 ≈ 10 nsec and τ2 = 200–250 nsec. This system is characterized by low afterglow, at the level for the Bi4G3O12 scintillator. We have demonstrated the feasibility of using CdI2:Pb as a scintillator for detecting α particles.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 6, pp. 825–830, November–December, 2008. 相似文献
9.
We consider hypercyclic composition operators on
which can be obtained from the translation operator using polynomial automorphisms of
. In particular we show that if C
S
is a hypercyclic operator for an affine automorphism S on
, then
for some polynomial automorphism Θ and vectors a and b, where I is the identity operator. Finally, we prove the hypercyclicity of “symmetric translations” on a space of symmetric analytic
functions on ℓ1.
Received: 8 June 2006 Revised: 26 September 2006 相似文献
10.
Currents of thermogradient polarization and depolarization of an electret state that arises in a photochromic crystal CdI2: Ag during one-side cooling of the sample in the dark from 325 to 90 K in the presence of a temperature gradient directed along the crystallographic axis C 6 have been found. At 90 K, the crystal polarized in the thermogradient electromotive force field is characterized by the photosensitivity in the near-edge, impurity, and infrared spectral regions. It is revealed that the electret state in the CdI2: Ag crystal is also formed at room temperature during photolysis under irradiation of the samples by integrated light from a xenon lamp. Models of photosensitive centers formed upon doping of the CdI2 crystal from the melt by the Ag+ impurity and during the occurrence of thermo- and photostimulated chemical reactions are proposed. The mechanism of the photochromic effect, including the change in the charge state of silver impurity ions, is considered. 相似文献