首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   764篇
  免费   30篇
  国内免费   17篇
化学   568篇
晶体学   4篇
力学   10篇
数学   38篇
物理学   191篇
  2023年   5篇
  2022年   3篇
  2021年   5篇
  2020年   11篇
  2019年   19篇
  2018年   16篇
  2017年   7篇
  2016年   20篇
  2015年   14篇
  2014年   23篇
  2013年   31篇
  2012年   34篇
  2011年   33篇
  2010年   29篇
  2009年   27篇
  2008年   37篇
  2007年   37篇
  2006年   39篇
  2005年   48篇
  2004年   41篇
  2003年   26篇
  2002年   26篇
  2001年   26篇
  2000年   19篇
  1999年   12篇
  1998年   4篇
  1997年   18篇
  1996年   13篇
  1995年   6篇
  1994年   23篇
  1993年   8篇
  1992年   9篇
  1991年   9篇
  1990年   7篇
  1989年   5篇
  1988年   7篇
  1987年   4篇
  1986年   11篇
  1985年   8篇
  1984年   16篇
  1983年   3篇
  1982年   8篇
  1981年   9篇
  1980年   3篇
  1979年   14篇
  1977年   8篇
  1976年   11篇
  1975年   3篇
  1973年   6篇
  1971年   2篇
排序方式: 共有811条查询结果,搜索用时 62 毫秒
1.
In this paper we are concerned with the initial boundary value problem of the micropolar fluid system in a three dimensional bounded domain. We study the resolvent problem of the linearized equations and prove the generation of analytic semigroup and its time decay estimates. In particular, LpLq type estimates are obtained. By use of the LpLq estimates for the semigroup, we prove the existence theorem of global in time solution to the original nonlinear problem for small initial data. Furthermore, we study the magneto‐micropolar fluid system in the final section. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
2.
Muon spin relaxation in zero field and longitudinal field was measured in single crystal samples of KH2PO4 (KDP) and KD2PO4 (DKDP) over a temperature range of 5 K to 300 K. At low temperatures, diamagnetic muons and muon substituted radicals with nuclear hyperfine coupling can be observed. For both KDP and DKDP, a minor change was observed in the dynamics of the muon below 140 K. Above 140 K, the mobility of the muon appears to increase and the diffusion rate becomes faster with increasing temperature. Only a small increase in the relaxation rate is observed in KDP due to the presence of theH +, suggesting that the relaxation effects probably originate from the31P.  相似文献   
3.
All kinds of high-permeability GO are manufactured using AlN as the main inhibitor. From a purely metallurgical viewpoint, three types of inhibitor preparation for high-permeability GO have been shown. They include a complete solution without nitriding, a complete precipitation with nitriding and a partial precipitation with nitriding. In this study, another possibility, i.e., a complete solution method with nitriding, was investigated to avoid the extra high-temperature slab reheating and to examine the effect of nitriding on GO bearing Al. This method can also provide the sharp Goss texture, and nitriding is shown to be very useful for changing the inhibitor intensity, depending on the primary grain size.  相似文献   
4.
Diamagnetic muon yields /PD/ in various metal acetylacetonates were measured at room temperature by the muon spin rotation technique. We have found a clear difference in PD between complexes of typical elements and those of transition elements. We suggest that partially filled inner orbitals play some important role in determining the diamagnetic yield in these complexes.  相似文献   
5.
6.
IntroductionInthepastseveralyears ,considerableprogresshasbeenachievedincontrollingtheassemblyofindividualbuildingblocksintostructureswithspecifictopologiesandinterestingpropertiessuchasmolecularrecognition ,ionexchangeandselectiveguestinclusion .1 3 Itis…  相似文献   
7.
The Ru(II)-catalyzed [2+2+2] cyclotrimerization of alkynylboronates, propargyl alcohol, and terminal alkynes proceeded chemo- and regioselectively to give rise to arylboronates, which were subjected to Suzuki-Miyaura cross-coupling with aryliodides to afford highly substituted biaryls in 53-76% yields.  相似文献   
8.
K. Nishiyama  K. Hata  T. Sato 《Tetrahedron》1975,31(3):239-244
[2.2]Metacyclophane (1) undergoes a variety of reactions according to the reagents and conditions. These include (1) substitution (path a), (2) transannular dehydrogenation (path b and c), (3) cycloisomerization (path d) and (4) transannular hydrogenation. A brief summary of these reactions is presented.The diversity of the reactions of 1 is further explored using benzoyl peroxide (BPO), cupric chloride, aluminum chloride, other metal salts, H2SO4 and FSO3H. With BPO or cupric chloride, one-electron transfer mechanism is postulated. This involves a tautomeric ion pair formed by the intramolecular arylation with an aryl cation radical. A supporting evidence in favor of the mechanism is presented from experiments using various metal salts in different solvents.On the contrary, the reaction with aluminum chloride gives decahydropyrene (8) and octahydropyrene (11) together with cycloisomerization product 5 and dehydrogenation products 2, 3 and 4. When treated with AlCl3HCl 1 gives similar products as above but the product ratios are quite different. The major product is 5 but only a trace amount of 8 is formed. The reaction with H2SO4 or FSO3H also produce 2, 4, 5 and 11. Some mechanistic evidence in favor of the disproportionation reaction is presented.  相似文献   
9.
(+) (S)- and (?) (R)-trans-1,2-cyclopropanedicarboxylic acids (C3A), (+) (S)- and (?) (R)-trans-1,2-diaminocyclopropanes (C3B), (+) (S)- and (?) (R)-trans-2-phenylcyclopropylamines (øC3B), (+) (S)- and (?) (R)-trans-1,2-bis(methylamino)-cyclopropanes (C3MB), and (+) (S)- and (?) (R)-trans-(2-phenylcyclopropyl)-methylamines (øC3MB) were prepared.  相似文献   
10.
A linearized optimal control method in combination with mixed quantum/classical molecular dynamics simulation is used for numerically investigating the possibility of controlling photodissociation wave packets of I(2)(-) in water. Optimal pulses are designed using an ensemble of photodissociation samples, aiming at the creation of localized dissociation wave packets. Numerical results clearly show the effectiveness of the control although the control achievement is reduced with an increase in the internuclear distance associated with a target region. We introduce effective optimal pulses that are designed using a statistically averaged effective dissociation potential, and show that they semiquantitatively reproduce the control achievements calculated by using optimal pulses. The control mechanisms are interpreted from the time- and frequency-resolved spectra of the effective optimal pulses.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号