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1.
Dynamic light scattering experiments in acid-catalyzed silica sols are discussed. It is shown that in spite of limited parameter accuracy and limited absolute knowledge of the particle sizes, the scattering data from various experiments are comparable with one another and give information about structural differences. Measurements at various angles indicate changes between non-spherical and nearly spherical particles and allow the estimation of gelling times before gelation. 相似文献
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Summary Electrophoretic mobility measurements in the pH 2‐10 range are described for several commercial HPLC silica microparticles
and a laboratory-produced product. The content of metal impurities for the silicas was also determined by AAS. An acidic/hydrothermal
treatment was used to generate a more homogenous surface for some of the silicas. The zero points of charge (zpc) for both
a native and a treated silica plus several commercial HPLC silicas were compared. The electrophoretic mobility method may
be useful in predicting the utility of certain types of silica supports for chromatographic separations. 相似文献
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Contrary to the informations in the literature our results of equilibrium and kinetic measurements indicate that Al(III) and Pyridine-2,6-dicarboxylic Acid in the range ofpH=(3...5) only formed the complexes AlHL
2+ (log=7.44±0.2) and AlL
+ (log=11.37±0.06). 相似文献
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O. Merwitz H. M. Nitzsche E. Hochhäuser 《Isotopes in environmental and health studies》2013,49(4):319-322
Abstract The dose-dependent isotope fractionation during decarboxylation (13C/12C) amplifies the radiation effect in the relatively low dose range. The fractionation of the nitrogen isotopes during deamination (15N/14N) at the dose of 17 Gy was found to be smaller than that of decarboxylation. 相似文献
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In Germany, geochemical modelling takes a strong position in two aspects of broader public interest. The first aspect is the safety assessment of a nuclear waste repository, the second is remediation of uranium mining areas. In both aspects, the application of geochemical modelling is stipulated by authorities. This situation results from the possibility to model highly complex situations by computers. The increase in computing power experienced in recent times now offers techniques to assess the sensitivity of modelling results to uncertain input data both in the thermodynamic data base and the site-specific field data. Both aspects are investigated by using Monte Carlo methods in combination with non-parametric statistics. A probabilistic geochemical modelling of uranium mill tailings leaching is demonstrated by application of TReaC modelling code using a simplified site model. 相似文献
7.
Ulrich Pinkernella Stefan Effkemann Frank Nitzsche Uwe Karst 《Journal of chromatography. A》1996,730(1-2):203-208
The selective oxidation of methyl p-tolyl sulfide (MTS) to the corresponding sulfoxide (MTSO) by peroxyacetic acid and the subsequent rapid separation of the sulfide and sulfoxide are the basis for a fast and reliable HPLC method for the determination of this oxidizing agent in the presence of hydrogen peroxide. The time required for chromatographic separation was reduced to less than 1 min. To improve the long-term stability of the sulfoxide solution, hydrogen peroxide was decomposed catalytically by manganese dioxide. Even in the presence of a tenfold molar excess of hydrogen peroxide, a storability of at least 20 h without a significant increase in MTSO concentration was achieved. External calibration can be performed using the stable and commercially available MTSO. Real samples from a brewery cleaning-in-place disinfection process were analysed and the results were compared with those of the classical two-step titration. 相似文献
8.
H.-M. Nitzsche W. Gläßer P. Harting 《Isotopes in environmental and health studies》2013,49(4):207-214
Abstract Gas analyses of the soil atmosphere of lignite mining dumps yielded increased contents of carbon dioxide. To get information about the potential sources and the carbon dioxide releasing capacity of the dumps, samples of dump material were investigated for their contents and isotopic compositions of organic and inorganic carbon as well as the carbon dioxide in the soil atmosphere. The contents of organic and inorganic carbon were found to vary depending on type of dump material. The isotopic composition of the organic carbon ranges between ?24.5 and ?26.5‰, which is typical for humous materials. The carbonates are found to be of marine origin (δ13C: +0.5 to ?1.1‰). By means of the isotope investigations it could be shown that the carbon dioxide in the lignite mining dump arises from these two different sources. Mixing ratios can be calculated using the isotope balance equation. Both reaction paths are associated with oxygen consumption and do not result in an increased gas pressure within the dump. 相似文献
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Effect of the Gas Phase on the Thermal Decomposition of K2[SiF6] K2SiF6 produced in usual ways is contaminated by traces of oxygen and protons. These and traces of water fed by gas atmosphere influence the thermal decomposition reaction. To study the influence of the gas phase definite amounts of H2O and HF were added. The formation of SiF4 was determined. The development of a SiO2 phase in presence of H2O and other experimental results suggest the construction of a layer on the K2SiF6 surface, which hinders further SiF4 being developped. Temperature and linear velocity of the gas influence the length of a zone of decomposition migrating through the solid. This is explained by sorption and reaction behavior of intermediately formed fluorosiloxanes. 相似文献