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1.
Nishant Peddagopu Anna L. Pellegrino Carmela Bonaccorso Patrizia Rossi Paola Paoli Graziella Malandrino 《Molecules (Basel, Switzerland)》2022,27(19)
Very few sodium complexes are available as precursors for the syntheses of sodium-based nanostructured materials. Herein, the diglyme, triglyme, and tetraglyme (CH3O(CH2CH2O)nCH3, n = 2–4) adducts of sodium hexafluoroacetylacetonate were synthesized in a single-step reaction and characterized by IR spectroscopy, 1H, and 13C NMR. Single-crystal X-ray diffraction studies provide evidence of the formation of the ionic oligomeric structure [Na4(hfa)6]2−•2[Na(diglyme2]+ when the diglyme is coordinated, while a mononuclear seven-coordinated complex Na(hfa)•tetraglyme is formed with the tetraglyme. Reaction with the monoglyme (CH3OCH2CH2OCH3) does not occur, and the unadducted polymeric structure [Na(hfa)]n forms, while the triglyme gives rise to a liquid adduct, Na(hfa)•triglyme•H2O. Thermal analysis data reveal great potentialities for their applications as precursors in metalorganic chemical vapor deposition (MOCVD) and sol-gel processes. As a proof-of-concept, the Na(hfa)•tetraglyme adduct was successfully applied to both the low-pressure MOCVD and the sol-gel/spin-coating synthesis of NaF films. 相似文献
2.
A solvent-free, eco-friendly and facile approach for the synthesis of highly functionalized tetrasubstituted pyrroles has been reported through one-pot four-component reaction of aldehyde, amine, nitroalkane and 1,3-diketone using silica gel supported polyphosphoric acid (PPA–SiO2) under microwave condition. The reaction occured through the in situ formation of β-keto enamine and nitrostyrene analog following Michael addition and finally intramolecular annulation affording the products in good yields. The key features of the present method include clean reaction, mild conditions, low catalyst loading, straightforward, high to excellent yields, short reaction time, avoiding use of harmful metal catalyst and organic solvent, environmentally friendly compared to the existing methods, recovery and reusability of catalyst and easy workup procedure. 相似文献
3.
Dr. Koji Ochiai Dr. Sankar Kuppusamy Yusuke Yasui Kenji Harada Dr. Nishant R. Gupta Dr. Yohei Takahashi Prof. Dr. Takaaki Kubota Prof. Dr. Jun'ichi Kobayashi Prof. Dr. Yujiro Hayashi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(10):3287-3291
The total synthesis of 7,10‐epimer of the proposed structure of amphidinolide N was accomplished. The requisite chiral C17–C29 subunit was assembled stereoselectively via Keck allylation, Shi epoxidation, diastereoselective 1,3‐reduction, and a later oxidative synthesis of the THF framework. The C1–C13 and C17–C29 subunits were successfully coupled using a Enders RAMP “linchpin” as the C14–C16 three carbon unit, thereby controlling the chirality at C14 and C16. The labile allyl epoxy moiety was successfully constructed by Grieco–Nishizawa olefination at a final stage of the synthesis. 相似文献
4.
5.
GPU‐accelerated direct numerical simulations of decaying compressible turbulence employing a GKM‐based solver 下载免费PDF全文
Gas Kinetic Method‐based flow solvers have become popular in recent years owing to their robustness in simulating high Mach number compressible flows. We evaluate the performance of the newly developed analytical gas kinetic method (AGKM) by Xuan et al. in performing direct numerical simulation of canonical compressible turbulent flow on graphical processing unit (GPU)s. We find that for a range of turbulent Mach numbers, AGKM results shows excellent agreement with high order accurate results obtained with traditional Navier–Stokes solvers in terms of key turbulence statistics. Further, AGKM is found to be more efficient as compared with the traditional gas kinetic method for GPU implementation. We present a brief overview of the optimizations performed on NVIDIA K20 GPU and show that GPU optimizations boost the speedup up‐to 40x as compared with single core CPU computations. Hence, AGKM can be used as an efficient method for performing fast and accurate direct numerical simulations of compressible turbulent flows on simple GPU‐based workstations. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
6.
Knowledge and understanding of the stability profile of a drug is important as it affects its safety and efficacy. In the present work, besifloxacin, a new, fourth‐generation fluoroquinolone antibiotic, was subjected to different forced‐degradation conditions as per International Conference on Harmonization (ICH) guidelines such as hydrolysis (acid, base and neutral), oxidation, thermal and photolysis. The drug degraded under acidic, basic, oxidative and photolytic conditions while it was found to be stable under dry heat and neutral hydrolytic conditions. In total, five degradation products (DPs) were formed under different conditions—DP1 and DP2 (photolysis), DP3 (oxidation), DP4 (acidic), DP3 and DP5 (basic). The chromatographic separation of besifloxacin and its degradation products was achieved on a Sunfire C18 (250 mm × 4.6 mm, 5 μm) column with 0.1% aqueous formic acid–acetonitrile as a mobile phase. The gradient RP‐HPLC method was developed and validated as per ICH guidelines. The degradation products were characterized with the help of LC–ESI–QTOF mass spectrometric studies and the most likely degradation pathway of the drug was proposed. In silico toxicity assessment of the drug and its degradation products was carried out, which indicated that DP3 and DP4 carry a mutagenicity alert. 相似文献
7.
Nishant N. Patel K. B. Joshi 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,59(1):19-23
Using empirical pseudopotential method Γ-L crossover is found for
the Ga0.74Al0.26Sb. The conduction band minimum is observed to
switch at the (0.87, 0, 0) point for Ga0.51Al0.49Sb which shifts to
the X point for Ga0.21Al0.79Sb and remains at X leading finally to
indirect band gap in AlSb. Band structure calculations for a large number of
alloys are performed and bowing parameters bX and bL are proposed
for the EX and EL respectively. Our findings may serve as
directive to select the materials in a range of composition to examine the
bowing parameters and thereby effective mass experimentally for the
GaxAl1-xSb alloys. 相似文献
8.
Ramanan Pitchumani Nishant Gupta GabrielM.H. Meesters Brian Scarlett 《Particle & Particle Systems Characterization》2003,20(5):323-326
Particle breakage can be characterised as attrition, chipping, fracture, abrasion and wear. All these types of breakage mechanisms are the effect of the damage caused to these particles. These mechanisms can be differentiated not just on the basis of magnitude and direction of the force but also by the damage caused to the particles. The damage is measured by change in the size distribution and the change in shape of the particles. In the current research, experiments were performed on the newly developed Repeated Impact Test. The unique feature of this test is that about hundred particles can be subjected simultaneously to a monitored number of impacts, without particle‐particle interactions at regulated velocities. The preliminary experiments were performed with single crystalline particles of different shapes and sizes. After fixed number of impacts, the images of the particles were taken. The volume and shape of the particles were determined by image analysis. It was observed that the rate of attrition was very high when the particles are irregular. The rate decreased as the particles became more spherical. 相似文献
9.
Charge density calculations and electronic band structures for Ga
x
Al1 − x
Sb with x = 1.0, 0.5 and 0.0 are presented in this work. The calculations are performed using the empirical pseudopotential method.
The charge density is computed for a number of planes, i.e. z = 0.0, 0.125 and 0.25 A
0 by generating the potential through a number of potential parameters available in the literature. The virtual crystal approximation
was applied for the semiconducting alloy. The characteristics of the band structure and charge density are observed to be
affected by the potential parameters. Calculated band gaps and the nature of gaps are in good agreement with the experimental
data reported. The ionicity is also reasonably in good agreement with other scales proposed in the literature; however the
formulation needs to be improved. The present work also demands indirect experimental band gap for the alloy.
相似文献
10.
Mohapatra Satyabrata Manglani Nishant Krishnan Dilmel Arumugam Ilavarasu Vijayakumar Madhavan Babu Uddagiri V. 《平面色谱法杂志一现代薄层色谱法》2014,27(4):251-254
JPC – Journal of Planar Chromatography – Modern TLC - Arnebia nobilis has gained an increasing popularity for the recently recognized various pharmacological activities. The root part... 相似文献