全文获取类型
收费全文 | 170篇 |
免费 | 8篇 |
国内免费 | 2篇 |
专业分类
化学 | 109篇 |
晶体学 | 2篇 |
力学 | 8篇 |
数学 | 25篇 |
物理学 | 36篇 |
出版年
2024年 | 2篇 |
2022年 | 4篇 |
2021年 | 6篇 |
2020年 | 3篇 |
2019年 | 6篇 |
2018年 | 15篇 |
2017年 | 3篇 |
2016年 | 7篇 |
2015年 | 6篇 |
2014年 | 8篇 |
2013年 | 12篇 |
2012年 | 15篇 |
2011年 | 18篇 |
2010年 | 4篇 |
2009年 | 8篇 |
2008年 | 11篇 |
2007年 | 4篇 |
2006年 | 4篇 |
2005年 | 13篇 |
2004年 | 5篇 |
2003年 | 6篇 |
2002年 | 2篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1997年 | 1篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1990年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1972年 | 2篇 |
排序方式: 共有180条查询结果,搜索用时 15 毫秒
1.
Multielemental characterisation of cobalt by glow discharge quadrupole mass spectrometry 总被引:5,自引:0,他引:5
Multielemental determination and the assessment of purity of cobalt metal used in the preparation of Ni-based super-alloys have been carried out by glow discharge quadrupole mass spectrometry (GD-QMS). Relative sensitivity factors (RSF) generated from certified iron matrix reference samples (NIST 663 and 664 low alloy steel pin standards) could be used for the determination of different trace element constituents of the sample. Different wet chemical procedures were also carried out for the determination of the trace constituents in the sample. The GD-QMS results are in reasonably good agreement with those obtained from wet chemical procedures, validating the use of the RSF values generated on low alloy steel standards for the computation of trace element concentrations in cobalt metal. A variety of molecular ions formed through the reaction of cobalt (matrix) with the discharge gas (argon) were also detected. 相似文献
2.
[reaction: see text] Gamma,delta-unsaturated beta-diketones have been prepared by the acylation of ketones with N-acylbenzotriazoles of various aliphatic and aromatic alpha,beta-unsaturated carboxylic acids. 相似文献
3.
Because Nitrosomonas europaea contains ammonia-oxidizing enzyme, nitrite reductase, and nitrous oxide reductase, the conversion of ammonia to dinitrogen
was tried with different reaction conditions. In aerobic reaction conditions, ammonium was converted to nitrite (NO
2
−
), while under oxygen-limiting or oxygen-free conditions, NO
2
−
-N formed from ammonia oxidation by N. europaea was reduced to N2O and dinitrogen with 22% conversion. During denitrification, optimal pH for the production of N2O and dinitrogen was found to be 7.0–8.0. Dinitrogen was not produced in acidic pH<7.0. A low partial oxygen pressure as well
as oxygen-free conditions are favorable for high production of dinitrogen. 相似文献
4.
Rishikesh Yadav Ramakanta Meher Vishnu Narayan Mishra 《Mathematical Methods in the Applied Sciences》2019,42(18):7172-7191
In this paper, we study the approximation properties of bivariate summation‐integral–type operators with two parameters . The present work deals within the polynomial weight space. The rate of convergence is obtained while the function belonging to the set of all continuous and bounded function defined on ([0],∞)(×[0],∞) and function belonging to the polynomial weight space with two parameters, also convergence properties, are studied. To know the asymptotic behavior of the proposed bivariate operators, we prove the Voronovskaya type theorem and show the graphical representation for the convergence of the bivariate operators, which is illustrated by graphics using Mathematica. Also with the help of Mathematica, we discuss the comparison by means of the convergence of the proposed bivariate summation‐integral–type operators and Szász‐Mirakjan‐Kantorovich operators for function of two variables with two parameters to the function. In the same direction, we compute the absolute numerical error for the bivariate operators by using Mathematica and is illustrated by tables and also the comparison takes place of the proposed bivariate operators with the bivariate Szász‐Mirakjan operators in the sense of absolute error, which is represented by table. At last, we study the simultaneous approximation for the first‐order partial derivative of the function. 相似文献
5.
A sharp‐interface immersed boundary framework for simulations of high‐speed inviscid compressible flows
下载免费PDF全文
![点击此处可从《国际流体数值方法杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Shuvayan Brahmachary Ganesh Natarajan Vinayak Kulkarni Niranjan Sahoo 《国际流体数值方法杂志》2018,86(12):770-791
A new finite‐volume flow solver based on the hybrid Cartesian immersed boundary (IB) framework is developed for the solution of high‐speed inviscid compressible flows. The IB method adopts a sharp‐interface approach, wherein the boundary conditions are enforced on the body geometry itself. A key component of the present solver is a novel reconstruction approach, in conjunction with inverse distance weighting, to compute the solutions in the vicinity of the solid‐fluid interface. We show that proposed reconstruction leads to second‐order spatial accuracy while also ensuring that the discrete conservation errors diminish linearly with grid refinement. Investigations of supersonic and hypersonic inviscid flows over different geometries are carried out for an extensive validation of the proposed flow solver. Studies on cylinder lift‐off and shape optimisation in supersonic flows further demonstrate the efficacy of the flow solver for computations with moving and shape‐changing geometries. These studies conclusively highlight the capability of the proposed IB methodology as a promising alternative for robust and accurate computations of compressible fluid flows on nonconformal Cartesian meshes. 相似文献
6.
7.
Haritha Rajaram N. Harshitha Shweta A. Ram Swarna M. Patra Vidya Niranjan K.A. Vishnumurthy 《印度化学会志》2022,99(6):100488
In the present study, the main protease 3CLpro and non-structural protein (NSP-12 with co-factors 7 and 8) trimer complex are used to study the protein-drug interactions with the phytochemicals from Ocimum Sanctum, Tinospora Cordifolia, Glycyrrhiza Glabra, and Azadirachta Indica. Which can give insight to be used as potent antiviral drugs against SARS-CoV-2. Twenty phytochemicals, five from each plant species, known for their wide range of biological activities were chosen from the literature. The in-silico study was carried out using virtual screening tools and the top five, which showed the least binding energies, were selected. Molecular docking tools revealed that gedunin and epoxy azadiradione proved to be excellent inhibitors for 3CLpro and so did Tinosporide for non-structural-protein complex. Further, the best-hit phytochemicals with respect to structure similarities with FDA drugs and investigatory drugs, were considered for comparative study. Molecular docking was done to check the drug-protein interactions and to check the inhibitory responses of these drugs against the viral protein. The analyses showed that the phytochemicals had similar responses on the protein complex but with exceptionally higher inhibitory responses hence which may be taken for further clinical study. 相似文献
8.
Patel Sunil V. Patel Palak R. Patel Samir G. Kanaki Niranjan S. Patel Rajendra K. Patel Archita J. 《平面色谱法杂志一现代薄层色谱法》2016,29(5):380-387
JPC – Journal of Planar Chromatography – Modern TLC - This work represents the validation of a stability-indicating thin-layer chromatographic technique for the simultaneous estimation... 相似文献
9.
A new bis-andrographolide ether from Andrographis paniculata nees and evaluation of anti-HIV activity 总被引:3,自引:0,他引:3
Reddy VL Reddy SM Ravikanth V Krishnaiah P Goud TV Rao TP Ram TS Gonnade RG Bhadbhade M Venkateswarlu Y 《Natural product research》2005,19(3):223-230
Novel bis-andrographolide ether (1) and six known compounds andrographolide, 14-deoxy-11,12-didehydroandrographolide, andrograpanin, 14-deoxyandrographolide, (+/-)-5-hydroxy-7,8-dimethoxyflavanone, and 5-hydroxy-7,8-dimethoxyflavone have been isolated from the aerial parts of Andrographis paniculata and their structures were established by spectral data. All the isolates were tested for the anti-HIV and cytotoxic activity. 相似文献
10.
[reaction: see text] 2,2,2-Trichloroethyl carboxylates undergo highly efficient dechlorinative Surzur-Tanner rearrangement with 2 equiv of a 1:1 molar mixture of CuCl and bpy in boiling DCE to give 1-chloroethenyl carboxylates in which copper appears to play an important role, probably by coordinating the initial radical or as a Lewis acid catalyst. 相似文献