全文获取类型
收费全文 | 785篇 |
免费 | 33篇 |
国内免费 | 7篇 |
专业分类
化学 | 597篇 |
晶体学 | 2篇 |
力学 | 10篇 |
数学 | 98篇 |
物理学 | 118篇 |
出版年
2023年 | 6篇 |
2022年 | 8篇 |
2021年 | 19篇 |
2020年 | 10篇 |
2019年 | 24篇 |
2018年 | 14篇 |
2017年 | 7篇 |
2016年 | 30篇 |
2015年 | 15篇 |
2014年 | 19篇 |
2013年 | 29篇 |
2012年 | 37篇 |
2011年 | 49篇 |
2010年 | 22篇 |
2009年 | 28篇 |
2008年 | 45篇 |
2007年 | 44篇 |
2006年 | 46篇 |
2005年 | 31篇 |
2004年 | 35篇 |
2003年 | 24篇 |
2002年 | 31篇 |
2001年 | 11篇 |
2000年 | 6篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 4篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 12篇 |
1992年 | 12篇 |
1991年 | 9篇 |
1990年 | 7篇 |
1989年 | 9篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1970年 | 6篇 |
1966年 | 5篇 |
1932年 | 8篇 |
1911年 | 3篇 |
1909年 | 5篇 |
1895年 | 5篇 |
1885年 | 4篇 |
排序方式: 共有825条查询结果,搜索用时 31 毫秒
1.
Jeroen J. L. M. Cornelissen W. Sander Graswinckel Alan E. Rowan Nico A. J. M. Sommerdijk Roeland J. M. Nolte 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1725-1736
The conformational properties of polymers derived from isocyanodipeptides have been investigated with a combination of model calculations, X‐ray diffraction, and circular dichroism spectroscopy. Depending on the configuration of the side chains, defined arrays of hydrogen bonds along the polymeric backbone are formed. This leads to a well‐defined conformation as, for example, expressed in the formation of lyotropic liquid‐crystalline phases and increased helical stability. Upon the disruption of the hydrogen bonds by a strong acid, a less well‐defined macromolecular conformation is observed. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1725–1736, 2003 相似文献
2.
José L. Ló pez Nico M. Temme 《Transactions of the American Mathematical Society》2004,356(11):4323-4342
Taylor expansions of analytic functions are considered with respect to several points, allowing confluence of any of them. Cauchy-type formulas are given for coefficients and remainders in the expansions, and the regions of convergence are indicated. It is explained how these expansions can be used in deriving uniform asymptotic expansions of integrals. The method is also used for obtaining Laurent expansions in several points as well as Taylor-Laurent expansions.
3.
R. Buccellato M. M. Michaelis C. A. Dempers A. Prause P. F. Cunningham 《Optics & Laser Technology》1993,25(4)
The concept of a pulsed gas lens is proposed. Potential applications are envisaged and preliminary experiments with pulsed ray refraction are reported. 相似文献
4.
5.
The ligand‐exchange mechanism of solvated Be2+ cations has been studied by means of DFT calculations (RB3LYP/6‐311+G**). Ligand exchange around [BeL4]2+, where L=H2O, NH3, CO2, formaldehyde (H2CO), HCN, N2, and CO, was found to follow an associative interchange (Ia) process in all cases. The size of the activation barrier is almost independent of the type of donor atom, and depends mainly on the hybridization undergone by the donor atom. This, in turn, suggests that steric effects play a major role in solvent‐ and ligand‐exchange reactions in Be2+ systems. 相似文献
6.
7.
R. Pepelnik H. -U. Fanger W. Michaelis B. Anders 《Journal of Radioanalytical and Nuclear Chemistry》1982,72(1-2):393-403
A new intense 14 MeV neutron generator with cylindrical acceleration structure has been put in operation at the GKSS Research
Center Geesthacht. The sealed neutron tube is combined with a fast pneumatic rabbit system with particular capabilities for
neutron activation analysis involving shortlived reaction products. The sample transfer time is less than 140 ms. The maximum
neutron flux available for activation is 5.2·1010 n/cm2s. Theoretical sensitivity predictions made in a previous study have been verified for some important trace elements. As a
first application, samples of freeze-dried suspended matter and fishes of the Elbe river were analyzed. 相似文献
8.
Floris P. J. T. Rutjes Henk Hiemstra Hendrik H. Mooiweer W. Nico Speckamp 《Tetrahedron letters》1988,29(52):6975-6978
Acid catalyzed cyclization of methoxymethyl substituted acyclic hydrazides 4 provides cyclic hydrazides 5 in moderate to good yields through the intermediacy of N,N′-di(methoxycarbonyl)hydrazinium intermediates. 相似文献
9.
Saalfrank RW Deutscher C Maid H Ako AM Sperner S Nakajima T Bauer W Hampel F Hess BA van Eikema Hommes NJ Puchta R Heinemann FW 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(8):1899-1905
In the reaction of the N-substituted diethanolamines (H(2)L(1-3)) (1-3) with calcium hydride followed by addition of iron(III) or indium(III) chloride, the iron wheels [Fe(6)Cl(6)(L(1))(6)] (4) and [Fe(6)Cl(6)(L(2))(6)] (6) or indium wheels [In(6)Cl(6)(L(1))(6)] (5), [In(6)Cl(6)(L(2))(6)] (8) and [In(6)Cl(6)(L(3))(6)] (9) were formed in excellent yields. Exchange of the chloride ions of 6 by thiocyanate ions afforded [Fe(6)(SCN)(6)(L(2))(6)] (7). Whereas the structures of 4, 5 and 7 were determined unequivocally by single-crystal X-ray analyses, complexes 8 and 9 were characterised by NMR spectroscopy. Contrary to what is normally presumed, the scaffolds of six-membered metallic wheels are not generally rigid, but rather undergo nondissociative topomerisation processes. This was shown by variable temperature (VT) (1)H NMR spectroscopy for the indium wheel [In(6)Cl(6)(L(1))(6)] (5) and is highlighted for the enantiotopomerisation of one indium centre [ 1/6[S(6)-5]<==>[1/6[S(6)-5']]. The self-assembly of metallic wheels, starting from diethanolamine dendrons, is an efficient strategy for the convergent synthesis of metallodendrimers. 相似文献
10.
Abdurashitov JN Gavrin VN Girin SV Gorbachev VV Ibragimova TV Kalikhov AV Khairnasov NG Knodel TV Kornoukhov VN Mirmov IN Shikhin AA Veretenkin EP Vermul VM Yants VE Zatsepin GT Bowles TJ Nico JS Teasdale WA Wark DL Cherry ML Karaulov VN Levitin VL Maev VI Nazarenko PI Shkol'nik VS Skorikov NV Cleveland BT Daily T Davis R Lande K Lee CK Wildenhain PW Khomyakov YS Zvonarev AV Elliott SR Wilkerson JF 《Physical review letters》1996,77(23):4708-4711