The [CH2CHOH.+, CH3CHO] solvated enol radical cation

The bimolecular reaction of the CH₂CHOH^.+ enol ion (m/z 44) with acetaldehyde gives a strongly dominant product,m/z 45, formed mainly by proton transfer from the ion to the molecule. The abundance of the product coming from a H^. abstraction reaction from the neutral, albeit more exothermic, is negligible. In order to explain this result, the long lived [CH₂CHOH^.+, CH₃CHO] solvated ion was generated by reaction of the CH₂CHOH^.+ enol ion with (CH₃CHO) _n in the cell of a Fourier transform ion cyclotron resonance mass spectrometer. The structure of this solvated ion was clearly established. Labeling indicates that [CH₂CHOH^.+, CH₃CHO], upon low energy collisions, reacts by H^. abstraction more rapidly than by H⁺ transfer to the neutral moiety. This shows that the entropic factors are determinant when the enol ion reacts directly with acetaldehyde.     

Effect of UV radiation on ion-implanted Si-SiO2 structures

The method of thermally stimulated charge release has been used to investigate the effect of UV radiation on the implantation-induced defects in the interfacial region of Si-SiO2 structures. The process of defect annealing has been observed. Defect creation is a competing process after long time UV irradiation.     

A Polynomial-Time Algorithm for Finding Regular Simple Paths in Outerplanar Graphs

Let G be a labeled directed graph with arc labels drawn from alphabet Σ, R be a regular expression over Σ, and x and y be a pair of nodes from G. The regular simple path (RSP) problem is to determine whether there is a simple path p in G from x to y, such that the concatenation of arc labels along p satisfies R. Although RSP is known to be NP-hard in general, we show that it is solvable in polynomial time when G is outerplanar. The proof proceeds by presenting an algorithm which gives a polynomial-time reduction of RSP for outerplanar graphs to RSP for directed acyclic graphs, a problem which has been shown to be solvable in polynomial time.     

Evidence for higher twist mechanisms in highp ⊥π− p events with prompt ρ0 production at 38 GeV/c

The ^– p interactions with at least one charged secondary produced at polar angle 90° in c.m.s. and having the transverse momentum above 1 GeV/c were investigated. The data were obtained using streamer chamber magnetic spectrometer RISK at 38 GeV/c beam from Serpukhov accelerator. The analyzis of associated production in reconstructed events suggests, that if the transverse momentum of a pair of oppositely charged secondaries compensates the trigger particlep practically completely, this pair is the product of the ⁰ decay in marked fraction of such events. We observed a large spin-alignment for the ⁰-mesons selected as described above: the probability of zero spin projection onto the normal to the ⁰ production plane is equal to ₀₀ ^T =0.86±0.23. The enhancement of the number of events, in which the ⁰ picks up practically full momentum transfer carrying by the exchange, and also the enlarged tensor polarization for the ⁰-mesons in these events could be qualitatively explained as manifestation of direct ⁰-production via the QCD higher twist processes in the highp ^– p collisions. At the same time, the observed effects are markedly larger than the values predicted with QCD model in which the higher twist corrections were included.     

New model potentials for sulfur-copper(I) and sulfur-mercury(II) interactions in proteins: from ab initio to molecular dynamics

We have developed new force field and parameters for copper(I) and mercury(II) to be used in molecular dynamics simulations of metalloproteins. Parameters have been derived from fitting of ab initio interaction potentials calculated at the MP2 level of theory, and results compared to experimental data when available. Nonbonded parameters for the metals have been calculated from ab initio interaction potentials with TIP3P water. Due to high charge transfer between Cu(I) or Hg(II) and their ligands, the model is restricted to a linear coordination of the metal bonded to two sulfur atoms. The experimentally observed asymmetric distribution of metal ligand bond lengths (r) is accounted for by the addition of an anharmonic (r3) term in the potential. Finally, the new parameters and potential, introduced into the CHARMM force field, are tested in short molecular dynamics simulations of two metal thiolates fragments in water. (Brooks BR et al. J Comput Chem 1983, 4, 1987.1).     

On selections and classes of spaces

Strong paracompactness, Lindelöf number and degree of compactness are characterized in terms of selections of set-valued mappings.     

Selections and selectors

The aim of the paper is to outline the known results and the main technics they are obtained with as well as the open questions about selections of set-valued mappings. More precisely the following topics will be touched: Set-valued selections of set-valued mappings, factorizations of set-valued mappings, inverse selection theorems, selections via extension of the set-valued mapping.     

AC EL STRUCTURES RED LIGHT EMISSION AND THEIR OPTOGALVANIC ANALOGUE

Some emission properties of Alternating Current Electroluminescencent (AC EL) structures containing thin chalcogenide films of the systems As-S or Ge-Sb-S are investigated by means of optogalvanic effect. The optogalvanic characteristics of red emitting structures at different conditions of their excitation are presented. Conclusions about the behaviour of the emission are drawn and some possibilities of the proposed method for the examination of the AC EL structures are analysed.     

A non-separable Christensen's theorem and set tri-quotient maps

For every space X let K(X) be the set of all compact subsets of X. Christensen [J.P.R. Christensen, Necessary and sufficient conditions for measurability of certain sets of closed subsets, Math. Ann. 200 (1973) 189-193] proved that if X,Y are separable metrizable spaces and F:K(X)→K(Y) is a monotone map such that any L∈K(Y) is covered by F(K) for some K∈K(X), then Y is complete provided X is complete. It is well known [J. Baars, J. de Groot, J. Pelant, Function spaces of completely metrizable space, Trans. Amer. Math. Soc. 340 (1993) 871-879] that this result is not true for non-separable spaces. In this paper we discuss some additional properties of F which guarantee the validity of Christensen's result for more general spaces.