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1.
Soumaya Nasri Mouhieddinne Guergueb Jihed Brahmi Youssef O. Al-Ghamdi Florian Molton Frdrique Loiseau Ilona Turowska-Tyrk Habib Nasri 《Molecules (Basel, Switzerland)》2022,27(24)
The present work describes the preparation and characterization of a new cobalt(III) porphyrin coordination compound named (chlorido)(nicotinoylchloride)[meso-tetra(para-chlorophenyl)porphyrinato]cobalt(III) dichloromethane monosolvate with the formula [CoIII(TClPP)Cl(NTC)]·CH2Cl2 (4). The single-crystal X-ray molecular structure of 4 shows very important ruffling and waving distortions of the porphyrin macrocycle. The Soret and Q absorption bands of 4 are very red-shifted as a consequence of the very distorted porphyrin core. This coordination compound was also studied by fluorescence and cyclic voltammetry. The efficiency of our four porphyrinic compounds—the H2TClPP (1) free-base porphyrin, the [CoII(TClPP)] (2) and [CoIII(TClPP)Cl] (3) starting materials, and the new Co(III) metalloporphyrin [CoIII(TClPP)Cl(NTC)]·CH2Cl2 (4)—as catalysts in the photochemical degradation was tested on malachite green (MG) dye. The current voltage of complexes 3 and 4 was also studied. Electrical parameters, including the saturation current density (Js) and barrier height (ϕb), were measured. 相似文献
2.
Molecular Diversity - This study describes the use of 3-aminotriazole, different aldehydes and N-methyl-1-(methylthio)-2-nitroethenamine as a ketene N,S-acetal in a three-component condensation for... 相似文献
3.
Molecular Diversity - 1,2,4-Triazole-containing scaffolds are unique heterocyclic compounds present in an array of pharmaceuticals and biologically important compounds used in the drug-discovery... 相似文献
4.
A new fused heterocyclic derivatives of pyrrole containing acetonitrile or cyanoacetonitrile moiety at 3-position is described by a one-pot multicomponent reaction. The reaction of dimedone, various aniline, aryl glyoxal with malononitrile/ethyl cyanoacetate/methyl cyanoacetate under mild conditions. The present method does not involve any hazardous organic solvents or catalysts. The significant features of this method are readily available starting materials, good yields, and easy purification. 相似文献
5.
Nahed Fakhfakh-Zouari Noomen Hmidet Anissa Haddar Safia Kanoun Moncef Nasri 《Applied biochemistry and biotechnology》2010,162(2):329-344
A keratinolytic enzyme (KerA1) secreted by a newly isolated Bacillus pumilus strain A1 cultivated in medium containing chicken feather meal was purified and characterized, and the gene was isolated
and sequenced. The molecular mass of the purified enzyme was estimated to be 34,000 Da by sodium dodecyl sulfate (SDS) polyacrylamide
gel electrophoresis and gel filtration. The optimum pH and temperature for the purified keratinase were 9.0 and 60 °C, respectively,
using keratin as a substrate. KerA1 showed a high stability towards nonionic surfactants. It was found to be relatively stable
toward the strong anionic surfactant (SDS). The deduced amino acid sequence of the keratinase KerA1 differs from both the
organic solvent tolerant protease of B. pumilus 115b and the dehairing protease of B. pumilus UN-31-C-42 by one and nine amino acids, respectively. These results suggest that this keratinase may be a useful alternative
and ecofriendly route for handling the abundant amount of waste feathers and for applications in detergent formulations. 相似文献
6.
Laila Manni Olfa Ghorbel-Bellaaj Kemel Jellouli Islem Younes Moncef Nasri 《Applied biochemistry and biotechnology》2010,162(2):345-357
Chitin is a polysaccharide found in abundance in the shell of crustaceans. In this study, the protease from Bacillus cereus SV1 was applied for chitin extraction from shrimp waste material of Metapenaeus monoceros. A high level of deproteinization 88.8% ± 0.4 was recorded with an E/S ratio of 20. The demineralization was completely achieved
within 6 h at room temperature in HCl 1.25 M, and the residual content of calcium in chitin was below 0.01%. 13C CP/MAS-NMR spectral analysis of chitin prepared by the enzymatic deproteinization of shrimp wastes was found to be similar
to that obtained by alkaline treatment and to the commercial α-chitin. The degree of N-acetylation, calculated from the spectrum,
was 89.5%. Chitin obtained by treatment with crude protease from B. cereus was converted to chitosan by N-deacetylation, and the antibacterial activity of chitosan solution against different bacteria
was investigated. Results showed that chitosan solution at 50 mg/mL markedly inhibited the growth of most Gram-negative and
Gram-positive bacteria tested. Furthermore, the antioxidant potential of the protein hydrolysates obtained during enzymatic
isolation of chitin was evaluated using various in vitro assays. All the samples exerted remarkable antioxidant activities. These results suggest that enzymatic deproteinization
of the shrimp shell wastes, using B. cereus SV1 protease, could be applicable to the chitin production process. 相似文献
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An efficient procedure for the synthesis of N‐alkyl‐2,5‐diaryl‐1,3‐dioxol‐4‐amines 3 via a one‐pot reaction of aromatic aldehydes 2 and alkyl isocyanides 1 at room temperature in good yields is described (Scheme 1, Table). 相似文献
9.
Javad Mashreghi Mostafa Nasri 《Nonlinear Analysis: Theory, Methods & Applications》2010,72(3-4):2086-2099
We develop a variant of Korpelevich’s method for solving variational inequality problems with pseudomonotone operators in Banach spaces. We establish the strong convergence of the sequence generated by the method under reasonable assumptions on the problem data. Finally, we justify the motivation of our theory by including compelling examples of infinite dimensional variational inequality problems for which our method is applicable. 相似文献
10.
Boumediene Abdellaoui Yasmina Nasri Ana Primo 《Mediterranean Journal of Mathematics》2013,10(1):289-311
We deal with the following parabolic problem, $$(P)\left\{\begin{array}{lll} u_t - \Delta{u} + |\nabla{u}|^q \quad=\quad \lambda{g}(x)u + f(x, t),\quad u > 0 \; {\rm in} \; \Omega \; \times \; (0, T),\\ \qquad\quad\quad\; u(x, t) \quad=\quad 0 \quad{\rm on}\; {\partial}{\Omega}\; \times ; (0, T),\\ \qquad\quad\quad\; u(x, 0) \quad=\quad u_{0}(x), \quad x \in {\Omega},\end{array}\right.$$ where is a bounded regular domain or ${\Omega = \mathbb{R}^N}$ , ${1 < q \leq 2, \lambda > 0\; {\rm and}\; f \geq 0, u_{0} \geq 0}$ are in a suitable class of functions. We give assumptions on g with respect to q for which for all λ > 0 and all ${f \in L^1(\Omega_T ), f \geq 0}$ , problem (P) has a positive solution. Under some additional conditions on the data, the Cauchy problem and the asymptotic behavior of the solution are also considered. 相似文献