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1.
Justina Grabowska Karuna Kar Nanda R.T. Rajendra Kumar J.P. Mosnier M.O. Henry Simon B. Newcomb Patrick McNally Lisa OReilly Xu Lu Enda McGlynn 《Superlattices and Microstructures》2007,42(1-6):327
Self-organized ZnAl2O4 nanostructures with the appearance (in SEM) of high aspect ratio horizontal nanowires are grown on uncatalysed c-sapphire by vapour phase transport. The nanostructures grow as three equivalent crystallographic variants on c-sapphire. Raman and cathodoluminescence spectroscopy confirm that the nanostructures are not ZnO and TEM shows that they are the cubic spinel, zinc aluminate, ZnAl2O4, formed by the reaction of Zn and O with the sapphire substrate. 相似文献
2.
B. Sahoo W. Keune E. Schuster W. Sturhahn T. S. Toellner E. E. Alp 《Hyperfine Interactions》2006,168(1-3):1185-1190
Amorphous (a-) Fe x Mg1?x alloys are interesting materials for the investigation of non-Debye-like low-energy vibrational excitations. We have prepared a-Fe x Mg1?x alloy thin films (0.3 ≤ × ≤0.7) by vapour quenching. The amorphous state was confirmed by conversion electron Mössbauer spectroscopy between 4.2–300 K, and the x- and temperature-dependence of the isomer shift and hyperfine magnetic field was measured. For x= 0.6 and 0.7, magnetic ordering occurs below ~150 K. The atomic vibrational density of states, g(E), was determined by nuclear resonant inelastic scattering, providing clear evidence for the non-Debye-like low-energy vibrational excitations. 相似文献
3.
The object of the paper is to study the absolute matrix summability problem of Fourier series, conjugate series and some associated
series under a new set of conditions on matrix methods, generalising many known results in the literature. 相似文献
4.
K. Vinay Kumar Reddy B. Sreenivasa Reddy M. Sreenath Reddy Ch. Gopal Reddy P. Yadagiri Reddy K. Rama Reddy 《Radiation measurements》2003,36(1-6):419-423
Studies conducted by Atomic Minerals Directorate of Exploration and Research (AMD) of Hyderabad, India had established the presence of higher concentrations of uranium in Lambapur and Peddagattu areas of Nalgonda district, AP, India and it was estimated that it could be a viable source for commercial extraction. The envisaged extraction process involves dispersion of radioactive particulate matter into atmosphere. Environmental radioactive studies in and around proposed mining areas at this point of time will be extremely useful for establishing base line data before a large scale uranium extraction process comes into existence. To this end, Solid State Nuclear Track Detectors were installed to evaluate indoor radon and thoron concentration levels in the dwellings of the area. The geometric means of radon and thoron concentration levels were found to be (7.1±0.2)×101 and (6.7±0.3)×101 Bq/m3, respectively. Simultaneously, natural background radiation measurements were also made and these levels are found to vary from 770 to 3995 μGy/y in the spatial distribution. 相似文献
5.
Designing an Immobilized Metal ion Affinity (IMA) chromatographic process on large scale demands a thorough understanding to be developed regarding the adsorption behaviour of proteins on metal loaded IMA (IMA-M(II)) gels and the characteristic adsorption parameters to be evaluated. This research investigation illustrates the significance of these aspects for the proposed fractionation of chicken egg-white proteins on these gels. Consequently, a systematic investigation of the adsorption characteristics of three chicken egg-white proteins viz., ovalbumin, conalbumin and lysozyme on Cu(II) and Ni(II) loaded IMA gels, iminodiacetate (IDA) and tris(2-aminoethyl)amine (TREN), has been undertaken. These gels differ in their selectivity towards the proteins of interest under the identical sets of experimental conditions. While TREN-Ni(II) was selective only for lysozyme, IDA-Cu(II), IDA-Ni(II) and TREN-Cu(II) showed varying affinities for all the three proteins. The equilibrium and kinetic data were analysed using various theoretical models and adsorption parameters were quantified. On the basis of these investigations, various strategies have been proposed for the efficient large-scale fractionation of chicken egg-white proteins on these gels. 相似文献
6.
Himansu Sekhar Sahoo S. Mahalakshmi Md. Hedayetullah Mir R. Raghunathan 《Tetrahedron letters》2007,48(5):761-765
A remarkable upfield shift of the pyα protons of complexed 2,2′-bipyridine in [cis-Pd(bpy)(NO3)2] is observed which is considered to originate from the anisotropic influence of suitably positioned coordinated nitrate anions around the Pd(II) centre of the molecule. A typical complexation-induced downfield shift is observed for the NH2 protons in [cis-Pd(en)(NO3)2] where ‘en’ stands for ethylenediamine. 相似文献
7.
The Schiff base [1,2-bis(salicylidene amino)phenylene]cobalt(II) complex, chemically bonded to a carbamate-modified silica gel catalyst, has been prepared by a four step procedure. The oxidation of cyclohexane was studied in the presence of this catalyst under relatively mild conditions (150–200 °C, 15–20 atm) using molecular oxygen. The catalyst was found to be very selective for the production of cyclohexanol, with cyclohexanone formed in only a small amount (45:1). This is in contrast to the commercially available processes in which cyclohexanol and cyclohexanone are both formed in appreciable amounts. The t.g.a. analysis shows the catalyst to be stable up to 211 °C and atomic absorption spectroscopy indicated negligible metal loss during 50 h use of the catalyst up to 180 °C. 相似文献
8.
Stols Lucy Kulkarni Gopal Harris Ben G. Donnelly Mark I. 《Applied biochemistry and biotechnology》1997,63(1):153-158
Applied Biochemistry and Biotechnology - The malic enzyme gene ofAscaris suum was cloned into the vector pTRC99a in two forms encoding alternative arnino-termini. The resulting plasmids, pMEAl and... 相似文献
9.
Ruan C Paulose M Varghese OK Mor GK Grimes CA 《The journal of physical chemistry. B》2005,109(33):15754-15759
Anodization of titanium in a fluorinated dimethyl sulfoxide (DMSO) and ethanol mixture electrolyte is investigated. The prepared anodic film has a highly ordered nanotube-array surface architecture. Using a 20 V anodization potential (vs Pt) nanotube arrays having an inner diameter of 60 nm and 40 nm wall thickness are formed. The overall length of the nanotube arrays is controlled by the duration of the anodization, with nanotubes appearing only after approximately 48 h; a 72 h anodization results in a nanotube array approximately 2.3 mum in length. The photoelectrochemical response of the nanotube-array photoelectrodes is studied using a 1 M KOH solution under both UV and visible (AM 1.5) illumination. Enhanced photocurrent density is observed for samples obtained in the organic electrolyte, with an UV photoconversion efficiency of 10.7%. 相似文献
10.
Sukumar Aditya Syamal Bandopadhyay Rebati C. Das Bata K. Nanda 《Thermochimica Acta》1981,46(3):337-340
From rehydration experiments the hydrates Ba(OH)2 · 8 H2O, Ba(OH)2 · 3 H2O β-Ba(OH)2, · 1 H2O, and γ-Ba(OH)2 · 1 H2O have been found in the system Ba(OH)2-H2O. Thermoanalytical measurements (DTA, TG, DTG, high temperature X-ray diffraction, high temperature Raman scattering) on these hydrates are reported. Thermal decomposition of Ba(OH)2 · 8 H2O and Ba(OH)2 · 3 H2O always results in the formation of β-Ba(OH)2 · 1 H2O, the stable form of the monohydrates at ambient temperature. Dehydration of β- and γ-Ba(OH)2 · 1 H2O, both of which form anhydrous β-Ba(OH)2 as the first product of decomposition, starts at 105 and 115°C, respectively. Single crystals of Ba(OH)2 · 3 H2O and γ-Ba(OH)2 · 1 H2O were prepared from Ba(OH)2 · 8 H2O meltings and from ethanolic solutions of Ba(OH)2 , respectively. The crystal data are: Ba(OH)2 · 3 H2O (orthorhombic, Pnma): a = 764.0(2), b = 1140,3(5), c = 596.5(1) pm, Z = 4; γ-Ba(OH)2 · 1 H2O (monoclinic, P21/m or P21): a = 704.9(2), b = 418.4(1), c = 633.3(1) pm, β = 111.45(2)°, Z = 2. 相似文献