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1.
Optics and Spectroscopy - Scattering of light by disordered structures is normally detrimental to their applicability in many optoelectronic devices. However, some micro and nanostructures are... 相似文献
2.
Mohan Namasivayam 《Annali di Matematica Pura ed Applicata》1986,144(1):157-172
Summary
Integral representations of junctions in the anisotropic Sobolev spaces
on unbounded domains are used in the study of the embeddings of these spaces into Lebesgue spaces. Estimates of entropy numbers of the embedding
are obtained, where k, p and q satisfy certain conditions and where is a certain type of quasibounded domain, 相似文献
3.
Mixed-ligand chelate extraction of Nd(III) into benzene with mixtures of thenoyltrifluoroacetone (HTTA) and bis-2-ethylhexyl sulphoxide (B2EHSO) or di-n-octyl sulphoxide (DOSO) or diphenyl sulphoxide (DPhSO) or trioctylphosphine oxide (TOPO) from thiocyanate solutions has been studied. A very high synergistic enhancement of the order 10(3) has been observed in these systems. Thus this mixed-ligand chelate system may be useful in the extraction and separation of Nd(III) from other metal ions. The mechanism of extraction can be explained by a simple chemically based model presented in this paper. 相似文献
4.
An attempt has been made to apply Green’s function and partitioning technique to the case of XY2Z (ClO2F) pyramidal type molecule belonging toC, point group. The isotopic rules have been formulated. The force constants, rotation distortion constants and mean amplitude
of vibration have been computed and compared with other observed and calculated values whichever is available. 相似文献
5.
S. Santhi Sudha Ch. Syama Sundar N. Bakthavatchala Reddy K. Uma Maheswara Rao S. H. Jaya Prakash C. Suresh Reddy 《Phosphorus, sulfur, and silicon and the related elements》2013,188(10):1402-1411
Abstract A simple, efficient, and environmentally benign methodology has been accomplished for the synthesis of α-aminophosphonates by one-pot three-component reaction of ethyl-2-amino-α-(methoxy-imino)-4-thiazoleacetate, aldehydes, and diethylphosphite by using Amberlyst-15 as catalyst at room temperature under solvent-free conditions. Their chemical structures were characterized by infrared (IR), NMR (1H, 13C & 31P), mass spectral, and elemental analysis. All the title compounds were screened for radical-scavenging activity by 1,1-diphenyl-2-picrylhydrazyl (DPPH), nitic oxide (NO), and hydrogen peroxide (H2O2) methods. Supplementary materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental files: Additional text and figures. 相似文献
6.
Molybdenyl(VI) acetylacetonate is an effective catalyst for the protective tetrahydropyranylation of alcohols and phenols. 相似文献
7.
The purpose of the study described in this paper was to compare removal of Zn(II) from aqueous solutions by use of two adsorbents—alkali-modified fly ash (FAN) and alkali and dye-modified fly ash (FAN-MO). The effects of four conditions (solution pH, contact time, initial metal ion concentration, and dose of adsorbent) on removal of Zn(II) at 27 ± 5 °C were studied in batch mode. Adsorption of Zn(II) was greater at pH 4.0 for FAN (76.49 %) and at pH 5.0 for FAN-MO (24.72 %). Maximum adsorption of Zn(II) by FAN and FAN-MO was achieved after 50 min. The linear forms of the Langmuir, Freundlich, Tempkin, D–R, Harkin–Jura, and Frenkel–Halsey isotherms were used for experiments with different concentrations of the metals. Adsorption of Zn(II) ions satisfied the Langmuir isotherm model only. The adsorption capacity of both adsorbents was also investigated by column studies. Adsorption of Zn(II) ions on FAN in column studies (45.33 %) was lower than in batch mode studies. For FAN-MO, adsorption was 37.88 % in column studies, again lower than in batch mode studies. Fly ash modified by alkali had a higher adsorption capacity for Zn(II) ions than fly ash modified by alkali followed by addition of dye. 相似文献
8.
Namasivayam Subhapradha Ramachandran Saravanan Pasiyappazham Ramasamy Alagiri Srinivasan Vairamani Shanmugam Annaian Shanmugam 《Applied biochemistry and biotechnology》2014,172(1):9-20
Chitosan has attracted much attention as a biomedical material, owing to its unique biological activities. In this study, hepatoprotective effect of β-chitosan obtained from the gladius of squid Sepioteuthis lessoniana was studied against carbon tetrachloride (CCl4)-induced oxidative stress and liver injury in rats. The rats that received β-chitosan along with the administration of CCl4 showed significantly decreased plasma and tissue alanine aminotransferase (ALT) and aspartate aminotransferase (AST) activities and total cholesterol, triglyceride (TG) and free fatty acid (FFA) contents, whereas the treatment with β-chitosan alone markedly increased rat hepatic and circulatory superoxide dismutase (SOD), catalase and glutathione peroxidase (GPx) and reduced glutathione (GSH) levels and decreased the malondialdehyde level. Histopathological observations recommended the marked hepatoprotective effect of β-chitosan. The CCl4-induced alterations on circulatory and hepatic antioxidant defence system were normalised by β-chitosan, and it could be concluded that the hepatoprotective effect of chitosan may be due to its antioxidant and antilipidemic property. Therefore, β-chitosan could be considered as antihepatotoxic agent. 相似文献
9.
In the present study, a series of thiodihydropyrimidine derivatives were synthesized from different substituted aromatic aldehydes, ethyl acetoacetate, and urea/thiourea using a bimetallic TUD-1 catalyst. The structures of all the synthesized compounds were characterized by melting point determination, thin layer chromatography (TLC), infrared (IR), 1HNMR, and 13C-NMR values. All the synthesized compounds were screened for their antimicrobial activities against two gram positive bacteria, two-gram negative bacteria, and two fungal strains. 相似文献
10.
Chandran Rankan Prabhakaran Santhi Marimuthu Keshri Nath Tiwari 《Journal of heterocyclic chemistry》2020,57(6):2628-2633
A greener, rapid and regioselective “on water” synthesis of spirooxindole-oxazoline by the reaction of isatin and isocyanoacetate at room temperature is described. The developed protocol has the advantage of being atom-economical, eco-friendly, and benign reaction conditions. Broader substrate scope, experimentally simple procedures, and easy purification of products with high yield further make this method attractive. The synthesized compounds have been fully characterized with spectral analysis. 相似文献