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Synthetic opportunities and mechanism of catalysis of the reaction of polyfluororalkylchlorosulfites with saturated monohydric alcohols are considered. Kinetic measurements and quantum-chemical calculations showed that polyfluoroalkylation of these compounds proceeded through the step of complex formation involving reagents and catalyst followed by liberation of hydrogen chloride and sulfur dioxide and formation of polyfluoroalkyl ethers.  相似文献   
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Russian Journal of General Chemistry -  相似文献   
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New procedures for preparing di(polyfluoroalkyl) ethers by reactions of polyfluoropropyl chlorosulfonites with polyfluorinated alcohols were tested.Translated from Zhurnal Prikladnoi Khimii, Vol. 77, No. 9, 2004, pp. 1573–1574.Original Russian Text Copyright © 2004 by Rakhimov, Nalesnaya, Vostrikova.  相似文献   
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