Preparation of Polyelectrolyte Nanotubes by a Pressure filter-template Technique Using Microporous Anodic Aluminum Oxide (AAO) as the Template

Polyelectrolyte nanotubes of poly(sodium 4‐styrene‐sulfonate) (PSS) with cationic poly(diallyl dimethyl ammonium chloride) (PDDA) (PSS/PDDA) were fabricated by a pressure‐filter‐template technique using microporous anodic aluminum oxide (AAO) as the template. UV‐Vis spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD) and infrared spectroscopy (FT‐IR) were applied to characterize the obtained PSS/PDDA nanotubes. The results have shown that the PSS/PDDA nanotubes exhibit an amorphous structure and have the outer diameter of 200 nm and length of 25 µm respectively, which are in good agreement with the dimensions of the AAO template pores. The wall thickness of the nanotubes may be controlled by the number of the self‐assembled layers. Formation of the nanotubes follows a layer‐by‐layer (LbL) mechanism due to the electrostatic interactions, where the SO^?₃ groups of PSS are first adsorbed on the Lewis acid sites of AAO template pores.     

模式匹配与积分方程在HPM模拟中的应用

针对具有电大尺寸、厚介质罩且馈源采用特定模式激励的高功率微波(HMP)传输及辐射结构研究了一种新型的电磁建模技术。将模式匹配方法与积分方程方法进行混合,构建了电磁模型的方程组,采用多层快速多极子技术、预条件器等进行求解加速,最终形成了可对电大尺寸HPM传输、辐射系统进行高效全波电磁仿真的技术。以电大变张角喇叭馈源、功率合成天线、波束波导及波束波导天线作为实例,构建了几何及电磁模型,并进行了包括远区方向图、近区功率密度分布在内的数值模拟,对该技术的正确性和通用性进行了验证。结果表明,该技术边界拟合准确,内存消耗低,且对馈电模式能予以准确反映,适用于HPM传输发射的高效高精度模拟。     

口径天线与近区厚介质体复杂系统的电磁建模

针对口径天线及其近区任意厚均匀介质体的复杂系统,应用表面积分方程（SIE）方法结合模式匹配方法（MM）建立了模式激励的新型一体化电磁模型。在馈电端口采取模式匹配方法模拟了波导中的激励情况,将金属壁处理为理想导电体,并在金属壁上利用边界条件建立电场积分方程（EFIE）;利用零场等效原理在介质体内外表面分别建立电场积分方程和磁场积分方程（MFIE）,并组合内外表面建立的电场积分方程和磁场积分方程为PMCHW方程;最后使用矩量法对所建立的EFIE-PMCHW-MM组合方程进行求解。文中结合喇叭天线设计了两个典型算例,所提混合方法EFIE-PMCHW-MM给出的数值结果与商用软件FEKO高度一致,且在求解口径天线与近区厚介质体耦合问题时由于未知量显著减少,大幅度提高了仿真效率,降低了计算机资源消耗。