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1.
This paper deals with the miscibility of polyvinyl chloride (PVC) with polymethyl methacrylate (PMMA). Blends of variable compositions from 0 to 100 wt% were prepared in the presence (15, 30 and 50 wt%) and in the absence of di ethyl- 2 hexyl phtalate as plasticizer. Their miscibility was investigated by using various analytical methods: determination of the Vicat softening temperature, a viscometry method based on the criterion of polymer–polymer miscibility, differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR). The results show that the plot of Vicat temperature against composition is a continuous curve, indicating the miscibility of the blend. The viscometry method and DSC find that the two polymers are miscible up to about 60 wt% of PMMA. This miscibility is due to a specific interaction of hydrogen bonding type between carbonyl groups (C=O) of PMMA and hydrogen from (CHCl) groups of PVC, as evidenced by FTIR spectroscopy. The two-band deconvolution shows an increase in associated groups percentage in the domain of miscibility. 相似文献
2.
Thermo-sensitive poly(2-isopropyl-2-oxazoline)s (PiPrOx) were functionalized with end groups of different polarity by living cationic ring-opening polymerization using the initiator and/or termination method as well as sequential block copolymerization with 2-methyl-2-oxazoline. As end groups, methyl, n-nonyl, piperidine, piperazine as well as oligo(ethylenglygol) and oligo(2-methyl-2-oxazoline) were introduced quantitatively. The lower critical solution temperature (LCST) of the aqueous solutions was investigated. The introduction of hydrophobic end groups decreases the LCST, while hydrophilic polymer tails raise the cloud point. In comparison to poly(N-isopropyl acrylamide), the impact of the end group polarity upon the modulation of the LCST was found to be significantly stronger. Surprisingly, terminal oligoethylenegycol units also decrease the LCST of PiPrOx, thus acting as moieties of higher hydrophobicity as compared to the poly(2-oxazoline) main chain. Together with the possible variation of the side group polarity, this allows a broad modulation of the LCST of poly(2-oxazoline)s. 相似文献
3.
A novel electrochemical sensor for ascorbic acid (AA) detection based on platinum electrode modified with polyterthiophene (P3T) and doped with metallic particles (Cu, Co, Ag, Au, Pd) was constructed. The electrocatalytic performances of the modified electrode with polyterthiophene-metallic particles related to the detection of AA, showed a better catalytic activity compared to the modified electrode with polyterthiophene film. The obtained results demonstrate also that the use of P3T–Ag nanocomposite allows a good sensitivity; which gives a high response in oxidation peak of AA. In order to have a good performance using this sensor, several parameters such as polymerization time of the film and immersion time of the film in AgNO3 solution were optimized. 相似文献
4.
Marie-France Llauro-Darricades Naima Bensemra Alain Guyot Roger Petiaud 《Macromolecular Symposia》1989,29(1):171-184
High resolution 1H and 13C NMR data were obtained on PVC and PVC reduced with Bu3SnH. The reduction is never complete and CH2Cl groups preferentially remain. It causes almost complete formation of cyclopentane structures from both internal and chain end unsaturation. 1H NMR gives total unsaturation as well as chain end unsaturation except if there are interferences with initiator residues; in that case, its combination with 13 C NMR of reduced PVC gives the chain end unsaturation. By the last method short branches and long ends are determined. Residual primary chlorine in all kinds of branches (methyl, ethyl, butyl, long ends) is taken into account. Long end contents are to be corrected (factor around 1.5), due to incomplete relaxation in standard analysis conditions. 1H NMR of reduced PVC can be used to get the total non-reduced structures, both -CH2Cl and -CHCl-. PVC was prepared by suspension or solution (trichlorobenzene) polymerization at 55° C, using dicetyl peroxydicarbonate as an initiator. The initiator residue content is higher in suspension PVC at very low conversion, and then levels off at a low value; in solution polymerization, it chiefly depends on the monomer/initiator ratio. At low conversion, more chain end and less short branches are present in suspension polymerization. Otherwise, only the butyl branch content shows a definite trend to increase with conversion. In solution polymerization, the number of defects is chiefly dependent on the initial monomer concentration; it is generally much higher than in suspension, except for the chloromethyl branches where both processes give about the same results. 相似文献
5.
Leila Hasniou Belkacem Nessark Naima Maouche 《Russian Journal of Applied Chemistry》2017,90(4):633-640
In the present work, a new composite material poly(3T + 6T + TiO2) was electrochemically synthesized. This composite material was synthesized in a solution of (CH2Cl2/TBAP) containing the monomers (terthiophene), (sexithiophene) and semiconductor (TiO2) particles. The preparedsamples were characterized electrochemically by cyclic voltamperometry (CV) and spectrometry analysis by scanning electron microscopy (SEM), ultraviolet-visible (UV-Vis) absorption spectroscopy, energy dispersive X-ray spectroscopy (EDX) and fourier transform infrared spectroscopy (FTIR), respectively. The effect of TiO2 concentration in the solution on dispersed microparticle entity and on the photocurrent response was investigated. The results showed that TiO2 particles were dispersed and codeposited into the copolymer poly(3T + 6T + TiO2) matrix, and titanium atom was confirmed by EDX spectra. From SEM images, the TiO2 has a spherical shape and micrometer size. The FTIR spectrum indicated that titanium dioxide do not show a significant modification in terms of band shape and no interaction between polymers and TiO2 particles. Furthermore, the results showed that the composite films with different amounts of TiO2 exhibit good photocurrent properties which imply that these composites films can be used in various fields, such as photoelectrochemical applications as photovoltaic cells. 相似文献
6.
A cellulose triacetate (CTA) membrane containing trioctylphosphine oxyde (TOPO) as carrier and 2-nitrophenyloctyl ether (NPOE) as a plasticizer was prepared. The membrane CTA + NPOE + TOPO was characterised using chemical techniques as well as Fourier Transform InfraRed (FTIR) spectroscopy, X-ray diffraction and Scanning Electron Microscopy (SEM). The CTA membrane is characterised by well-defined pores; these pores are completely filled with the NPOE and carrier. Surfaces of membranes with TOPO are smooth. The systems constituted by the mixture of CTA + NPOE, CTA + NPOE + TOPO do not give any diffraction. This can be due to the absence of crystallization within the membrane. On the other hand, this result should be attributable to the amorphous state of the structure, which permits us to eliminate the mechanism of transfer of the ions by electron jump. A comparative study of transport across a polymer inclusion membrane (PIM) and a supported liquid membrane (SLM) containing the same carrier in chloroform has shown that uranium or molybdenum transport efficiency was increased using PIM instead of SLM. PIM showed higher stability than SLM, the flux of transport remain constant in the former case after 2 weeks. 相似文献
7.
Naima Bouyahia Mohamed Larbi Hamlaoui Mouna Hnaien Florence Lagarde Nicole Jaffrezic-Renault 《Bioelectrochemistry (Amsterdam, Netherlands)》2011,80(2):155-161
In this work, a new biosensor was prepared through immobilization of bovine liver catalase in a photoreticulated poly (vinyl alcohol) membrane at the surface of a conductometric transducer. This biosensor was used to study the kinetics of catalase–H202 reaction and its inhibition by cyanide. Immobilized catalase exhibited a Michaelis–Menten behaviour at low H202 concentrations (< 100 mM) with apparent constant KMapp = 84 ± 3 mM and maximal initial velocity VMapp = 13.4 μS min? 1. Inhibition by cyanide was found to be non-competitive and inhibition binding constant Ki was 13.9 ± 0.3 μM. The decrease of the biosensor response by increasing cyanide concentration was linear up to 50 μM, with a cyanide detection limit of 6 μM. In parallel, electrochemical characteristics of the catalase/PVA biomembrane and its interaction with cyanide were studied by cyclic voltammetry and impedance spectroscopy. Addition of the biomembrane onto the gold electrodes induced a significant increase of the interfacial polarization resistance RP. On the contrary, cyanide binding resulted in a decrease of Rp proportional to KCN concentration in the 4 to 50 μM range. Inhibition coefficient I50 calculated by this powerful label-free and substrate-free technique (24.3 μM) was in good agreement with that determined from the substrate-dependent conductometric biosensor (24.9 μM). 相似文献
8.
Karbass N Sans V Garcia-Verdugo E Burguete MI Luis SV 《Chemical communications (Cambridge, England)》2006,(29):3095-3097
Long-term stable Pd(0) catalysts can be easily supported onto polymeric monoliths containing methyl-imidazole moieties and the corresponding reactors based on these materials can be applied for the continuous Heck reaction in near-critical EtOH. 相似文献
9.
In this paper a two-stage game that involves three container terminals located in Karachi Port in Pakistan is discussed. In the first stage, the three terminals have to decide on whether to act as a singleton or to enter into a coalition with one or both of the other terminals. The decision at this stage should presumably be based on the predicted outcome for the second stage. The second stage is here modelled as a Bertrand game with one outside competitor, the coalition and the terminal in Karachi Port (if any) that has not joined the coalition. Furthermore, three partial and one grand coalition among the three terminals at Karachi Port are investigated. The concepts of “characteristic function” and “core” are used to analyse the stability of these coalitions and this revealed that one combination does not satisfy the superadditivity property of the characteristic function and can therefore be ruled out. The resulting payoffs (profits) of these coalitions are analysed on the basis of “core”. The best payoff for all players is in the case of a “grand coalition”. However, the real winner is the outsider (the terminal at the second port) which earns a better payoff without joining the coalition, and hence will play the role of the “orthogonal free-rider”. 相似文献
10.
Sahraoui N Vian MA Bornard I Boutekedjiret C Chemat F 《Journal of chromatography. A》2008,1210(2):229-233
Steam distillation (SD) is routinely used by analysts for the isolation of essential oils from herbs, flowers and spices prior to gas chromatographic analysis. In this work, a new process design and operation for an improved microwave steam distillation (MSD) of essential oils from aromatic natural products was developed. To demonstrate its feasibility, MSD was compared with the conventional technique, SD, for the analysis of volatile compounds from dry lavender flowers (Lavandula angustifolia Mill., Lamiaceae). Essential oils isolated by MSD were quantitatively (yield) and qualitatively (aromatic profile) similar to those obtained by SD, but MSD was better than SD in terms of rapidity (6 min versus 30 min for lavender flowers), thereby allowing substantial savings of costs in terms of time and energy. Lavender flowers treated by MSD and SD were observed by scanning electron microscopy. Micrographs provide evidence of more rapid opening of essential oil glands treated by MSD, in contrast to conventional SD. 相似文献