排序方式: 共有1条查询结果,搜索用时 15 毫秒
1
1.
Zaripov R. N. Murzagulova E. I. Garifullina G. F. Safiullin R. L. Komissarov V. D. 《Kinetics and Catalysis》2002,43(3):312-315
The kinetics of the decomposition of acetyl-cyclo-hexylsulfonylperoxide (SP, RS(O2)OOC(O)CH3, R = cyclo-C6H11) was studied in a C6H4Cl2 solution in an O2 atmosphere at 323–353 K and in an Ar atmosphere at 323–343 K. The rate constants of SP monomolecular decomposition (k
1) and SP reaction with CH3
· radicals (k
3) were determined. The temperature dependences of these rate constants are described by equations log k
1 = (14.5 ± 2.9) – (115.4 ± 19.0) – (2.3RT) and log k
3= (11.6 ± 2.2) – (44.6 ± 14.2)/(2.3RT), where the activation energies are expressed in kJ/mol. 相似文献
1