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In this paper, we describe an algorithm to stably sort an array ofn elements using only a linear number of data movements and constant extra space, albeit in quadratic time. It was not known previously whether such an algorithm existed. When the input contains only a constant number of distinct values, we present a sequence ofin situ stable sorting algorithms makingO(n lg(k+1)
n+kn) comparisons (lg(K) means lg iteratedk times and lg* the number of times the logarithm must be taken to give a result 0) andO(kn) data movements for any fixed valuek, culminating in one that makesO(n lg*n) comparisons and data movements. Stable versions of quicksort follow from these algorithms.Research supported by Natural Sciences and Engineering Research Council of Canada grant No.A-8237 and the Information Technology Research Centre of Ontario.Supported in part by a Research Initiation Grant from the Virginia Engineering Foundation. 相似文献
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Non-empirical, STO-3G, and semi-empirical, MNDO, calculations have been performed to investigate the rigid rotation of the phenyl group in phenyl carbonic acid, as a model for Bisphenol A polycarbonate. The MNDO results predict a barrier to rotation of ~55 kcal mole?1, a factor of ~2 greater than that for the STO-3G computations. Analysis of the relevant orbital energies dictates that the lowest excited state of phenyl carbonic acid is . 相似文献
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The separation of bupropion enantiomers on an ovomucoid stationary phase was investigated. The mobile- and stationary-phase parameters that may influence the separation were identified. The parameters that were studied include: type and concentration of organic modifier, mobile phase pH, ionic strength, type of buffer, and column temperature, as well as the effect that the amount of sample injected had on the separation. The optimized chiral separation baseline-resolved the enantiomers in less than 10 min. Calibration curves for a standard were linear over a range of 0.27-53.0 microg/g (ppm) with a correlation coefficient of 0.999 for both enantiomers. A detection limit of 0.13 microg/g and a quantitation limit of 0.27 microg/g were also found. The system precision of the method was 0.2%. 相似文献
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Some surface aspects of the thermal and X-ray induced degradation of a cellulose nitrate have been studied by FAB/SIMS.The pristine material gives peaks at 30 and 46 amu, indicative of NO+ and NO2+ originating from the nitrate ester groups. The thermally degraded material indicates these peaks at slightly lower intensities, whereas the X-ray degraded material shows little evidence for their appearance. These data complement recent ESCA data on the same systems.1The conclusion is that electromagnetic degradation is predominantly a surface effect, whereas thermal degradation is a bulk oriented phenomenon. 13C nmr has been used to add further evidence for this last point. 相似文献
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Patricio V Poblete J.Ian Munro 《Journal of Algorithms in Cognition, Informatics and Logic》1985,6(3):336-350
A detailed analysis is presented for the behaviour of binary search trees built by using a heuristic that performs only local reorganizations at the bottom of the tree. 相似文献
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The carbon-13 NMR spectra have been recorded for representatives of three previously unexamined classes of pentacyclic triterpenes—lupanes, fernanes and arboranes. In addition to the spectra of lupeol methyl ether, cylindrin and arundoin, the spectra of a number of other triterpene methyl ethers are also recorded. The effect of methyl ether formation on the shilding values for carbons in the 3β-hydroxy-4,4-dimethyl- ring A system is defined. 相似文献
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Total luminescence yield of toluene and mesitylene, isolated in rare-gas matrices, has been measured as a function of excitation energy in the energy range covering the absorption region of both host and guest. Energy transfer from the host to the dopant is apparent. An increase in the luminescence yield is observed at the host exciton state. Luminescence excitation spectrum of pure mesitylene is presented. 相似文献