全文获取类型
收费全文 | 336篇 |
免费 | 13篇 |
国内免费 | 1篇 |
专业分类
化学 | 223篇 |
晶体学 | 4篇 |
力学 | 14篇 |
综合类 | 1篇 |
数学 | 71篇 |
物理学 | 37篇 |
出版年
2023年 | 3篇 |
2022年 | 9篇 |
2021年 | 9篇 |
2020年 | 14篇 |
2019年 | 19篇 |
2018年 | 9篇 |
2017年 | 14篇 |
2016年 | 13篇 |
2015年 | 13篇 |
2014年 | 15篇 |
2013年 | 17篇 |
2012年 | 25篇 |
2011年 | 35篇 |
2010年 | 21篇 |
2009年 | 22篇 |
2008年 | 20篇 |
2007年 | 14篇 |
2006年 | 12篇 |
2005年 | 12篇 |
2004年 | 7篇 |
2003年 | 5篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1992年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1937年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有350条查询结果,搜索用时 31 毫秒
1.
2.
Levoglucosenone reacts with α-aminoazoles to yield azolo[1,5-a]pyrimidine systems fused with a carbohydrate fragment. The reaction oocurs much more smoothly than in the case of other α,β-unsaturated
ketones. The reactions of levoglucosenone with β-dicarbonyl compounds (dimedone, barbituric acid) in the presence of a base
results in the pyran ring closure, which has never been observed earlier in reactions of β-dicarbonyl compounds with α,β-unsaturated
ketones under the conditions of basic catalysis. The structures of products were established by IR and NMR spectroscopy.
For Part 3, see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 553–558, March, 1997. 相似文献
3.
Muhammet Yürüsoy 《Applied mathematics and computation》2004,150(3):775-783
Two dimensional unsteady boundary layer equations of a general model of non-Newtonian fluids were investigated in this study. In this model, the shear stress is taken as an arbitrary function of the velocity gradient. Group classification of the equations with respect to shear stress is done using two different approaches: (1) classical theory (2) equivalence transformations. Both approaches yield identical results. It is found that the principle Lie Algebra extends only for cases of Newtonian and Power-Law flows. 相似文献
4.
Muhammad Adil Khan Shahid Khan Samet Erden Muhammad Samraiz 《Mathematical Methods in the Applied Sciences》2022,45(1):36-48
There are many useful applications of Jensen's inequality in several fields of science, and due to this reason, a lot of results are devoted to this inequality in the literature. The main theme of this article is to present a new method of finding estimates of the Jensen difference for differentiable functions. By applying definition of convex function, and integral Jensen's inequality for concave function in the identity pertaining the Jensen difference, we derive bounds for the Jensen difference. We present integral version of the bounds in Riemann sense as well. The sharpness of the proposed bounds through examples are discussed, and we conclude that the proposed bounds are better than some existing bounds even with weaker conditions. Also, we present some new variants of the Hermite–Hadamard and Hölder inequalities and some new inequalities for geometric, quasi-arithmetic, and power means. Finally, we give some applications in information theory. 相似文献
5.
Köse ME Crutchley RJ Derosa MC Ananthakrishnan N Reynolds JR Schanze KS 《Langmuir : the ACS journal of surfaces and colloids》2005,21(18):8255-8262
Polymer films consisting of a linear poly(dimethylsiloxane) end-functionalized with a luminescent Ir(III) complex (Ir-PDMS), blended with polystyrene (PS), function as optical oxygen sensors. The sensor response arises by quenching of the luminescence from the Ir(III) chromophore by oxygen that permeates into the polymer film. The morphology and luminescence oxygen sensor properties of blend films consisting of Ir-PDMS and PS have been characterized by fluorescence microscopy, atomic force microscopy, and scanning electron microscopy. The investigations demonstrate that microscale phase segregation occurs in the films. In blends that contain a relatively small amount of Ir-PDMS in PS (ca. 10 wt %), the Ir-PDMS exists as circular domains, with diameters ranging from 2 to 5 mum, surrounded by the majority PS phase. For larger weight fractions of Ir-PDMS in the blends, the film morphology becomes bicontinuous. A novel epifluorescence microscopy method is applied that allows the construction of Stern-Volmer quenching images that quantify the oxygen sensor response of the blend films with micrometer spatial resolution. These images provide a map of the oxygen permeability of the polymer blend films with a spatial resolution of ca. 1 mum. The results of this investigation show that the micrometer-sized Ir-PMDS domains display a 2-3-fold higher oxygen sensor response compared to the surrounding PS matrix. This result is consistent with the fact that PDMS is considerably more gas permeable compared to PS. The relationship of the microscale morphology of the blends to their performance as macroscale optical oxygen sensors is discussed. 相似文献
6.
Samet AV Niyazymbetov ME Semenov VV Laikhter AL Evans DH 《The Journal of organic chemistry》1996,61(25):8786-8791
Regioselective Michael addition of nitro and heterocyclic compounds to levoglucosenone, 1, is effectively catalyzed by amines and also by cathodic electrolysis. In comparison to the base-catalyzed reaction, it was found that under electrochemical conditions the reaction proceeds under milder conditions and with higher yields. Cathodically-initiated Michael addition of thiols to levoglucosenone using small currents produces the previously unknown threo addition product in several instances. The normal erythro isomer, identified as the kinetic product, tends to be formed when large currents are used. In contrast, slow, low current electrolyses promote equilibration of the two forms so that erythro can be converted to threo by the retro reaction and readdition. Addition of 2-naphthalenethiol to (R)-(+)-apoverbenone is also reported. 相似文献
7.
T. Kilic T. Dirmenci F. Satil G. Bilsel T. Kocagoz M. Altun A. C. Goren 《Chemistry of Natural Compounds》2005,41(3):276-279
The fatty acid composition of seed extracts of Salvia bracteata, S. aethiopis, and S. candidissima ssp. candidissima were analyzed by GC/MS. The main compound of S. bracteata, S. aethiopis, and S. candidissima ssp. candissima was found to be 9,12-octadecenoic acid at 64.3%, 73.4%, and 20.8%, respectively. The seed extracts of S. bracteata showed activity against S. aureus E. coli, M. smegmatis, and C. albicans with MIC values of 1.1, 0.5, 1.1, and 1.1 mg/mL, respectively, while the seeds extract of S. aethiopis showed activity against the same microorganisms with MIC values of 2.2, 2.2, 1.1, and 1.1 mg/mL, respectively. However, the seed extract of S. candidissima ssp. candidissima showed activity only against M. smegmatis with a MIC value of 0.25 mg/mL.__________Published in Khimiya Prirodnykh Soedinenii, No. 3, pp. 223–225, No. 3, May–June 2005. 相似文献
8.
9.
Chirkova Zh. V. Kabanova M. V. Filimonov S. I. Samet A. V. Stashina G. A. Sudzilovskaya T. N. 《Russian Chemical Bulletin》2018,67(6):1083-1087
Russian Chemical Bulletin - Chlorination of 1-hydroxyindole-5,6-dicarbonitriles and 1-hydroxypyrrolo[3,4-f]indole-5,7(1H,6H)-diones with N-chlorosuccinimide afforded previously unknown... 相似文献
10.
Easy and effective preparation of new 1H-pyrrolizine carboxylates was achieved with high efficiency via KHMDS-induced carbocyclization of N-alkynyl proline carboxylates under substantially mild conditions. Meanwhile, some trans-diiodoallylic N-proline carboxylates were obtained from N-propargyl proline carboxylates using molecular I2 with or without KHMDS. This method is quite feasible in terms of practical and quick access to the pyrrolizines and their derivatives over the formation of carbanions. 相似文献