Polymerization of diacetylenes by hydrogen bond templated adlayer formation

Adlayers were formed on self-assembled monolayers (SAMs) formed by alkanethiols on gold. Base SAMs exposing amide functional groups at the SAM surface were formed with 12-mercaptododecanamide. Adlayers of diacetylene-containing monomers were then formed via amide hydrogen bonding in decalin and decalin/toluene mixtures. Grazing angle FTIR, contact angle measurements, and ellipsometry suggest that these adlayer films exhibit ordering and packing similar to that of SAMs on gold. Resonance Raman spectroscopy showed that these diacetylene adlayers could be readily polymerized by exposure to UV light.     

Some Isoperimetric Inequalities in Electrochemistry and Hele Shaw Flows

Isoperimetric inequalities are applied to a moving-boundaryproblem for doubly-connected domains. This problem occurs forexample in electrochemistry, in which case the domains in questionare the electrolyte of an electrolytic cell. The two electrodessurrounding the electrolyte are assumed to grow or dissolve,at different rates in general, by electrochemical reaction.We obtain optimal estimates showing, for example, that the leastchange in volume of each electrode always occurs in sphericalsymmetry.     

Highly efficient single-pass source of pulsed single-mode twin beams of light

We report the realization of a bright ultrafast type II parametric down-conversion source of twin beams free of any spatiotemporal correlations in a periodically poled KTiOPO4 (PP-KTP) waveguide. From a robust, single-pass setup it emits pulsed two-mode squeezed vacuum states: photon-number entangled pairs of single-mode pulses or, in terms of continuous variables quantum optics, pulsed Einstein-Podolsky-Rosen states in the telecom wavelength regime. We verify the single-mode character of our source by measuring Glauber correlation functions g(2) and demonstrate with a pump energy as low as 75 pJ per pump pulse a mean photon number of 2.5.     

Experimental realization of maximum confidence quantum state discrimination for the extraction of quantum information

We present the first experimental demonstration of the maximum confidence measurement strategy for quantum state discrimination. Applying this strategy to an arbitrary set of states assigns to each input state a measurement outcome which, when realized, gives the highest possible confidence that the state was indeed present. The theoretically optimal measurement for discriminating between three equiprobable symmetric qubit states is implemented in a polarization-based free-space interferometer. The maximum confidence in the measurement result is 2/3. This is the first explicit demonstration that an improvement in the confidence over the optimal minimum error measurement is possible for linearly dependent states.     

Stepping into iSMART: Understanding Science–Mathematics Integration for Middle School Science and Mathematics Teachers

This paper is based on an online graduate program for middle school science and mathematics teachers in Texas titled Integration of Science, Mathematics and Reflective Teaching (iSMART). Launching the program for its first cohort in fall 2010, the authors attempted to answer the following two questions in this paper: (a) How do the members of the iSMART design team and the first cohort of teacher participants define science and mathematics integration with similar and different emphases? and (b) How would these definitions and concerns impact the ongoing design of the program? The iSMART design team members and the participating cohort teachers had a shared view regarding the importance of integration and its possible impact on student motivation. The findings also revealed that the two groups showed some different points of emphasis in their definitions of integration. These issues will be addressed in the ongoing design of the program in the following three areas: (a) design of the second summer meeting activities, (b) greater emphasis on teacher as researcher and action research, and (c) administrative support for teacher collaboration.     

Solid-state bonding technique for template-stripped ultraflat gold substrates

A simple procedure using gold diffusion bonding for the preparation of template-stripped gold (TSG) surfaces is described. TSG surfaces are useful for surface studies because a very consistent flat gold surface with few defects can be easily prepared. We have developed a method of producing TSG surfaces that relies only on gold diffusion bonding rather than epoxies. The resulting substrates are free from concerns of solvent compatibility, heat stability, and impurities. Bonding of centimeter-sized substrates is performed at 300 degrees C for 2 h using a vise and aluminum foil.