排序方式: 共有42条查询结果,搜索用时 11 毫秒
1.
2.
3.
A. M. Voloshchuk V. A. Gorlov T. A. Moskovskaya L. S. Reifman V. N. Chechevichkin A. A. Yurkevich 《Russian Chemical Bulletin》1990,39(6):1097-1100
The use of the method of densitometry of light passing through a layer of zeolite crystals permits determining the limiting stage of diffusion during adsorption by zeolites. Diffusion in transport pores and external heat exchange play the basic role in adsorption of benzene by NaX zeolite, while diffusion in crystals is the determining mechanism of transport in adsorption of water by NaA and NaX zeolites. The diffusion coefficients of water in NaX zeolite have an order of magnitude of 10–17 m2/sec and increase with an increase in the degree of filling. An explanation for the anomalous behavior of the kinetic adsorption curve for brief times of adsorption of water by zeolite is proposed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1224–1228, June, 1990. 相似文献
4.
A. M. Voloshchuk M. M. Dubinin T. A. Moskovskaya A. O. Larionova L. A. Shilkova 《Russian Chemical Bulletin》1988,37(10):1979-1983
1. | The adsorption isotherms of N2 at 77 K on the surface of carbonaceous adsorbents in the region of low relative pressures are satisfactorily described by the Dubinin-Radushkevich (DR) equation. However, the a0 parameter of the DR equation is not related to the monolayer capacity, and for samples with the most homogeneous surface the quantity a0 substantially exceeds the BET monolayer capacity. |
2. | The adsorption isotherms calculated per unit surface area of adsorbent can be grouped in terms of the E0 value of the DR equation; this can be regarded as a measure of the degree of energetic heterogeneity of the samples. |
3. | For samples with E0 < 15.5="" kj/mole,="" the="" specific="" surface="" areas="" calculated="" by="" the="" bet="" method="" and="" by="" the=""> and methods are similar. |
4. | The samples of carbonaceous adsorbents with E0 > 15.5 kJ/mole are characterized by surface heterogeneity associated with the presence of micropores. |
5.
A. M. Voloshchuk M. M. Dubinin T. A. Moskovskaya G. K. Ivakhnyuk N. F. Fedorov 《Russian Chemical Bulletin》1988,37(2):204-209
1. | A standard adsorption isotherm (CAI) was plotted from the isotherms of adsorption of N2 on nonporous and mesoporous carbon adsorbents for analyzing the pore structure of carbon adsorbents. |
2. | The analysis of the pore structure of active carbon with a relatively large area of mesopores and predominantly microporous active carbon shows that the CAI obtained adequately describes the adsorption of N2 on the surface of the mesopores of these samples. |
6.
Collocation Methods for Weakly Singular Second-kind Volterra Integral Equations with Non-smooth Solution 总被引:2,自引:0,他引:2
Collocation type methods are studied for the numerical solutionof the weakly singular Volterra integral equation of the secondkind:
where the solution (t) is assumedto have the form f(t) = x(t)+r?(t), x and being sufficientlysmooth. The solution is approximated near zero by a linear combinationof powers of t?, and away from zero by the usual polynomialrepresentation. Convergence is proved and many numerical experimentsare carried out with examples from the literature. A comparisonis made with a method of Brunner & Norsett (1981), originallydeveloped for (1) with a smooth solution. Special attentionis paid to the numerical approximation of the so-called momentintegrals which emerge in the collocation scheme. 相似文献
7.
8.
A. A. Maerle A. A. Karakulina L. I. Rodionova I. F. Moskovskaya I. V. Dobryakova A. V. Egorov B. V. Romanovskii 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(2):238-242
Structured mesoporous Mn, Fe, and Co oxides are synthesized using “soft” and “hard” templates; the resulting materials are characterized by XRD, SEM, TEM, BET, and TG. It is shown that in the first case, the oxides have high surface areas of up to 450 m2/g that are preserved after calcination of the material up to 300°C. Even though, the surface area of the oxides prepared by the “hard-template” method does not exceed 100 m2/g; it is, however, thermally stable up to 500°C. Catalytic activity of mesoporous oxides in methanol conversion was found to depend on both the nature of the transition metal and the type of template used in synthesis. 相似文献
9.
Feyer V Plekan O Kivimäki A Prince KC Moskovskaya TE Zaytseva IL Soshnikov DY Trofimov AB 《The journal of physical chemistry. A》2011,115(26):7722-7733
Core-level X-ray photoemission and near-edge X-ray absorption fine structure spectra of 5-methylcytosine, 5-fluorocytosine, and isocytosine are presented and discussed with the aid of high-level ab initio calculations. The effects of the methylation, halogenation, and isomerization on the relative stabilities of cytosine tautomers are clearly identified spectroscopically. The hydroxy-oxo tautomeric forms of these molecules have been identified, and their quantitative populations at the experimental temperature are calculated and compared with the experimental results and with previous calculations. The calculated values of Gibbs free energy and Boltzmann population ratios are in good agreement with the experimental results characterizing tautomer equilibrium. 相似文献
10.