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1.
N. V. Moskalev M. I. Tartynova I. Yu. Bagryanskaya Yu. V. Gatilov 《Russian Chemical Bulletin》1996,45(2):462-464
Nitrobenzene,p-bromonitrobenzene,N,N-diethyl-p-nitroaniline, and 9-methyl-3nitrocarbazole undergo condensation with two moles of acetophenone in a DMSO-KOH system to form the corresponding (Z)-1,4-diphenyl-2-arylamino-2-butene-1,4-diones.Translated from Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 480–482, February, 1996 相似文献
2.
The first evidence that α-acylnitrone is an intermediate in the base-promoted reaction of 4-nitro-N,N-diethylaniline with aceptophenome to give an enaminoketone was obtained.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1645–1647, August, 1998. 相似文献
3.
Trifluoroacetylation of 3-halo-9-methylcarbazoles at 110C proceeds at 6-position. In the case of 3-bromo- and 3-iodo-derivatives, the reaction is complicated by competing processes of dehalogenation, followed by the halogenation of the substrate, leading to 3,6-dihalo derivatives.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1492–1495, November, 1987. 相似文献
4.
Nikolai Moskalev 《Tetrahedron》2004,60(2):347-358
Enolizable ketones react with m-nitroaniline in the presence of strong base such as t-BuOK to give 4- and 6-substituted nitroindoles. The reaction proceeds via oxidative nucleophilic substitution of hydrogen in m-nitroaniline with enolate anions in positions ortho to the amino group giving anionic σH adducts that are additionally stabilized by intramolecular interaction between the amino and the carbonyl group. Spontaneous oxidation of the σH adducts followed by the Bayer type condensation of the produced ortho-aminonitrobenzyl ketones gives 4- and 6-substituted nitroindoles. The scope of this reaction and its basic mechanistic features are discussed. 相似文献
5.
E. E. Sirotkina N. V. Moskalev I. G. Shabotkin 《Chemistry of Heterocyclic Compounds》1984,20(5):512-514
It is shown that the trifluoroacetylation of 9-methylcarbazole proceeds regio-specifically in the 3 position of the ring. 1,1,1-Tris(9-methyl-3-carbazolyl)-2,2,2-trifluoroethane and 1,1,1,1-tetrakis(9-methyl-3-carbazolyl)-2,2,2,2,2,-2-hexafluorodiethyl ether were also isolated from the reaction mixture. Bis(trifluoroacetyl) derivatives were not detected. Only a 3-trifluoroacetyl derivative is formed when the reaction is carried out by heating in the presence of pyridine.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 640–642, May, 1984. 相似文献
6.
A. M. Yakub M. V. Moskalev N. L. Bazyakina I. L. Fedushkin 《Russian Chemical Bulletin》2018,67(3):473-478
A mixture of allylbromide and diphenylacetonitrile is reduced to afford 2,2-diphenylpentene-4-nitrile as a major product in the presence of catalytic amounts of the magnesium complex (dpp-bian)Mg(thf)3 (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene dianion). The overall conversion of nitrile is 71% within 3 h at 85 °С. 4,4-Diphenylbutene-1 and diphenylmethane are by-products in this process. Complexes (dpp-bian)Mg(thf)3 and (dpp-bian)Ca(thf)4 (in an amount of 0.5—5 mol.%) catalyze the intramolecular hydroamination of some aminopentenes and aminohexenes with the conversion from 67 to 99%. 相似文献
7.
8.
9.
We presume that extending lifespan and particularly its healthy period is absolutely beneficial for human being. However,
the existing views and approaches did not result in a significant extension of human lifespan. 相似文献
10.
M. V. Moskalev A. A. Skatova V. A. Chudakova N. M. Khvoinova N. L. Bazyakina A. G. Morozov O. V. Kazarina A. V. Cherkasov G. A. Abakumov I. L. Fedushkin 《Russian Chemical Bulletin》2015,64(12):2830-2840
Digallane (dpp-bian)Ga—Ga(dpp-bian) (1) (dpp-bian is the 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) catalyzes the addition of 4-chloroaniline to some terminal alkynes RC≡CH (R = Bun, Ph, 4-MeC6H4). The reaction orders in each of the substrates were found for the reaction of phenylacetylene with 4-chloroaniline catalyzed by compound 1. The reaction of compound 1 with phenylacetylene in a molar ratio of 1: 10 led to 1-[N-(2,6-diisopropylphenyl)imino]-2-(1-phenylethylidene)acenaphthene (5) and the compound [C12H6(NC6H3Pr2 i)(PhC=CH2)(PhC=CH)]Ga(C≡CPh)2 (6). The reaction of digallane 1 with phenylacetylene and aniline in a stoichiometric ratio of 1: 2: 2 gave bis-anilide (dpp-bian)-Ga[N(H)Ph]2 (7) in 40% yield. The compound (PhC≡C)3Ga·THF (9) was obtained by the reaction of three equivalents of sodium phenylacetylide (prepared in situ from phenylacetylene and sodium) with one equivalent of GaCl3 in tetrahydrofuran. Compounds 5—7 and 9 were characterized by IR spectroscopy, 1H NMR spectroscopy was used to characterize products 5, 6, and 9, whereas EPR spectroscopy was used for amide 7. The structures of compounds 5—7 and 9 were determined by single crystal X-ray diffraction analysis. 相似文献