Optical detection of NO3 and NO2 in “pure” HNO3 vapor,the liquid-phase decomposition of HNO3

Flowing and static gas-phase samples of HNO₃ in O₂ and N₂ were analyzed by long-path ultraviolet/visible (UV/VIS) spectroscopy to reveal the presence of both NO₂ and NO₃, the concentrations of which were calculated using differential absorption cross sections. NO₂ is produced predominantly by the heterogeneous decomposition of HNO₃, whereas NO₃ is generated in the gas phase by the thermal decomposition of N₂O₅, a product of the self-disproportionation of liquid HNO₃. © 1993 John Wiley & Sons, Inc.     

Formation of secondary ozonides in the gas-phase ozonolysis of simple alkenes

Secondary propene ozonide and isobutene ozonide were formed in the gas-phase ozonolysis of ethene with added acetaldehyde and acetone, respectively. Combined with the formation of hydroperoxymethyl formate and methoxymethyl hydroperoxide in the ethene-ozone reaction system in the presence of HCOOH and CH₃OH, respectively, formation of the secondary ozonides reveals a close similarity between the gas-phase and the liquid-phase ozonolysis of alkenes.     

A study of the UV—visible absorption spectrum of molecular chlorine

The UV—visible absorption spectrum of molecular chlorine at 298 K was investigated in the wavelength range 200–550 nm with a spectral resolution of 0.2 nm. Except for minor discrepancies, the absorption cross-sections are in agreement with those found in the literature. In the region 250λ-550 nm, the Cl₂ spectrum can be adequately described by a semi-empirical function of the wavelength A (in vacuum) and temperature T

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where TANH=tanh(hcx559.751 cm⁻¹/2kT). The absorption of solar radiation by the weak continuum around λ_max=406.5 nm contributes 9% or more of the photodissociation of molecular chlorine in the atmosphere, but the banded Cl₂ features (λ 479 nm) are of negligible atmospheric significance.     

Summary of the CMS potential for the Higgs boson discovery

The European Physical Journal C - This work summarizes the studies for the Higgs boson searches in CMS at the LHC collider. The main discovery channels are presented and the potential is given for...     

Molar extinction coefficients of some carbohydrates in aqueous solutions

Molar extinction coefficients of some carbohydrates viz. l-arabinose (C₅H₁₀O₅), d-glucose (C₆H₁₂O₆), d-mannose (C₆H₁₂O₆), d-galactose (C₆H₁₂O₆), d(-) fructose (C₆H₁₂O₆) and maltose (C₁₂H₂₄O₁₂) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by gamma ray transmission method in a narrow beam good geometry set-up. These coefficients have been found to depend upon the photon energy following a 4-parameter polynomial. These extinction coefficients for different sugars having the same molecular formula have same values varying within experimental uncertainty. Within concentration ranges studied, Beer-Lambert law is obeyed very well.     

Pair-produced heavy particle topologies: MSSM neutralino properties at the LHC from gluino/squark cascade decays

Processes of the form pp → anything → X_iX_j → + + notE are studied via a technique that may be viewed as an adaptation of time-honoured Dalitz plot analyses. X_i and X_j are new heavy states (with i, j =1, . . .,n), which may be identical or distinct; and and are necessarily distinct standard model (SM) fermion pairs whose invariant masses can be measured. A Dalitz-like plot of said invariant masses, versus , exhibits a topology connected to the masses and specific decay chains of X_i and X_j. Aside from relatively minor details, observed patterns consist of a collection of box and wedge shapes. This collection is model-dependent: comparison of the observed pattern to the possibilities for a specific model yields information on which new particle pair combinations are actually being produced, information beyond that extractable from conventional one-dimensional invariant mass distributions. The technique is illustrated via application to the minimal supersymmetric standard model (MSSM) process pp → → e⁺e^- + μ⁺μ^- notE. Here the heavy states are neutralinos (i = 2,3,4) - note that is excluded - which are produced in gluino/squark ( / ) cascade decay chains. Even with fairly modest expectations for the LHC performance during the first few years, this method still provides substantial insight into the neutralino mass spectrum and couplings if gluino/squark masses are relatively low (≃ 400 GeV). Arrival of the final proofs: 29 November 2005     

The reactions of the Criegee intermediate CH3 CHOO in the gas-phase ozonolysis of 2-butene isomers

Ozonolysis of cis- and trans-2-butene isomers were carried out in a 570 l spherical glass vessel in 730 torr synthetic air at 295 ± 3 K. The initial concentrations were 5 to 10 ppmv for the isomers and 2 to 5 ppmv for ozone. Quantitative yields were determined by FTIR spectroscopy for CH₃CHO, HCHO, CH₄, CH₃OH, CO, and CO₂. By means of computational subtraction of the spectral contribution of the identified products from the product spectra, residual spectra have been obtained. Formation of 2-butene ozonide, propene ozonide, and l-hydroperoxyethyl formate CH₃CH(OOH)(SINGLE BOND)O(SINGLE BOND)CH(O) have been identified in the residual spectra. These products have been shown to be formed in the reactions of the Criegee intermediate CH₃CHOO with CH₃CHO, HCHO, and HCOOH, respectively. Mechanistic implications and atmospheric relevance of these observations are discussed. © 1997 John Wiley & Sons, Inc. Int J Chem Kinet 29: 461–468, 1997.     

Measurement of CP violation in stop cascade decays at the LHC

We study the potential observation at the LHC of CP-violating effects in stop production and subsequent cascade decays, , , , within the Minimal Supersymmetric Standard Model. We study T-odd asymmetries based on triple products between the different decay products. There may be a large CP asymmetry at the parton level, but there is a significant dilution at the hadronic level after integrating over the parton distribution functions. Consequently, even for scenarios where large CP intrinsic asymmetries are expected, the measurable asymmetry is rather small. High luminosity and precise measurements of masses, branching ratios and CP asymmetries may enable measurements of the CP-violating parameters in cascade decays at the LHC.     

Matrix-isolation spectra of chlorine nitrate

High-resolution FTIR-isolation spectra of chlorine nitrate in nitrogen and argon matrices have been studied and a full analysis based on planar ClONO₂ and known impurities carried out. No evidence for isomers of ClONO₂ has been found; if present, their concentrations must be less than 1% of parent ClONO₂.     

Homoconjugation in the adamantane cage: DFT/IGLO studies of the 1, 3-dehydro-5-adamantyl cation, its isoelectronic boron analogue 1, 3-dehydro-5-boraadamantane, and related systems(1)(,)

The structure of 1,3-dehydro-5-adamantyl cation and its isoelectronic boron analogue 1,3-dehydro-5-boraadamantane as well as some related adamantane systems, hitherto unknown as persistent long-lived species, were investigated by using the density functional theory (DFT) method. (13)C and (11)B NMR chemical shifts of the compounds were also calculated using the IGLO method. Stabilization of the systems due to homoconjugation is discussed.